Month: December 2022

Rong, Hao published the artcileTranscriptional profiling between yellow- and black-seeded Brassica napus reveals molecular modulations on flavonoid and fatty acid content, Recommanded Product: Methyl docosanoate, the main research area is Brassica transcription flavonoid fatty acid phenylpropanoid AIM1 KAT2.

Brassica napus is an important cash crop broadly grown for the vegetable and oil values. Yellow-seeded B. napus is preferred by breeders due to its improved oil and protein quality, less pigments and lignin compared with the black-seeded counterpart. This study compared the differences in flavonoid and fatty acid contents between yellow rapeseed from the progenies of B. napus-Sinapis alba somatic hybrids and the black-seeded counterpart using RNA-seq anal. Through HPLC-PDA-ESI(-)/MS2 anal., it was found that phenylpropanoids and flavonoids (i.e., isorhamnetin, epicatechin, kaempferol, and other derivatives) in yellow seed were significantly lower than those in black seed. The fatty acid (FA) content in yellow rapeseed was higher than that in black rapeseed due to the variation of C16:0, C18:0, C18:1, C18:2, and C18:3 contents. RNA-seq anal. of seeds at four and five weeks after flowering (WAF) indicated that differentially expressed genes (DEGs) between black and yellow rapeseeds were enriched in flavonoid and FA biosynthesis, including BnTT3, BnTT4, BnTT18, and BnFAD2. Also, genes related to FA biosynthesis, desaturation and elongation (FAD3, LEC1, FUS3, and LPAT2) in yellow seed were up-regulated compared to those in black seed, while genes involved in beta-oxidation cycle (AIM1 and KAT2) of yellow seed were down-regulated compared to those in black seed. The DEGs related to the variation of flavonoids, phenylpropanoids, and FAs would help improve the knowledge of yellow seed character in B. napus and promote rapeseed improvement.

Journal of Integrative Agriculture published new progress about Brassica napus (black seed). 929-77-1 belongs to class esters-buliding-blocks, name is Methyl docosanoate, and the molecular formula is C23H46O2, Recommanded Product: Methyl docosanoate.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Al-layla, Neam m. t. published the artcileLiquid bio-fuels and carbon adsorbents production via pyrolysis of non-edible feedstock, Computed Properties of 929-77-1, the main research area is biofuel adsorbent pyrolysis activated carbon morphol.

The slow pyrolysis of milk thistle (Silybum marianum L.) seeds (MTS) in a lab-scale batch reactor to investigate the influence of heating rate, temperature, contact period, and particle size on the yields of bio-oil (BO) and bio-char (BC) was presented for the first time. The maximum yield of BO (49.55 ± 2.50%) was obtained at a pyrolysis temperature of 475°C for 60 min using a 0.25 mm MTS particle size at 20°C/min heating rate. The chem. composition of BO from MTS was identified by FTIR, 1H NMR, and GC-MS techniques. Following the FTIR outcomes, aldehydes, alcs., phenols, acids, and alkanes are present in the BO . Also, results from 1HNMR spectrum indicated that the percentage of the aliphatic compounds in the as-synthesized BO was greater than that of the aromatic compounds The GC-MS anal. exhibited that the MTS derived BO is rich in higher acids (38.64%), higher esters (21.30%), and hydrocarbons (11.39%). The elemental anal. consequences revealed that the attained BO possessed a higher carbon content and a lower oxygen content than its resp. MTS with a chem. formula of CH1.67 N0.025O0.10. Addnl., the BO owned a calorific value of 39.47 MJ/kg, close to that established for petro based liquid fuels and comparable to those of BOsamples declared in the literature. Besides, the physic-chem. properties of the MTS derived BO were close to those specified for conventional fossil fuels. Proximate anal., elemental composition, higher heating value, iodine number, surface area, and morphol. of the attained biochar were determined The ZnCl2 activation method was employed to synthesize activated carbon from the produced BC via the optimized procedure. An impregnation ratio of 1.5:1 ZnCl2:BC, 500°C, 60 min activation period, and 0.21 mm particle size were the best conditions to yield an activated carbon with 638.66 mg/g iodine number and 677.22 m2/g surface area. The FESEM results affirmed the mesoporosity of the attained activated carbon compared to the macroporosity of the pristineBC .

Journal of Analytical and Applied Pyrolysis published new progress about Adsorbents. 929-77-1 belongs to class esters-buliding-blocks, name is Methyl docosanoate, and the molecular formula is C23H46O2, Computed Properties of 929-77-1.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Mulik, Nagesh published the artcileSynergetic combination of H2Zr1PW12O40 and Sn-Beta as potential solid acid catalyst for direct one-step transformation of glucose to ethyl levulinate, a biofuel additive, SDS of cas: 539-88-8, the main research area is Bronsted Lewis acid catalyst glucose ethyl levulinate biofuel additive.

Et levulinate (EL) has found wide applications as chems. and biofuel additives. Efficient catalytic conversion of abundantly available glucose to ELs over solid acid catalyst having optimum Bronsted (B) and Lewis (L) acidity is highly appreciated. Present work demonstrated, direct one-step synthesis of EL from glucose over synergized Bronsted (H2Zr1PW12O40) and Lewis (Sn-Beta) acid catalyst. H2Zr1PW12O40 is prepared by exchanging H+ of tungstophosphoric acid (H3PW12O40-heteropolyacid) with Zr, improves the heterogeneity in polar medium by 50%. The combination of a phys. mixture of H2Zr1PW12O40 + Sn-Beta with 80:20 weight ratio was found to be optimum for the maximum EL yield formation of 54% from glucose at 180°C for 3 h, which is probably the highest than reported over the heterogeneous catalyst in ethanol medium. An optimal combination of B and L catalyst and its ratio is found to be crucial for the direct transformation of glucose to EL in one step. The present study also explored that this combined phys. mixture of H2Zr1PW12O40 + Sn-Beta can tolerate glucose concentration up to 30 g/L, which is probably the higher than reported. © 2019 American Institute of Chem. Engineers Environ Prog, 2019

Environmental Progress & Sustainable Energy published new progress about Phase composition Role: PRP (Properties), TEM (Technical or Engineered Material Use), USES (Uses). 539-88-8 belongs to class esters-buliding-blocks, name is Ethyl 4-oxopentanoate, and the molecular formula is C7H12O3, SDS of cas: 539-88-8.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Wang, Bin published the artcileProtein disulfide isomerases (PDIs) negatively regulate ebolavirus structural glycoprotein expression in the endoplasmic reticulum (ER) via the autophagy-lysosomal pathway, Formula: C12H9N3O5S, the main research area is protein disulfide isomerase glycoprotein ebolavirus ER autophagy lysosomal pathway; Autophagy; ER-phagy; ERAD; ERp57; EVD; ebola; filoviruses; glycoproteins; lysosomes; reticulophagy.

Zaire ebolavirus (EBOV) causes a severe hemorrhagic fever in humans and non-human primates with high morbidity and mortality. EBOV infection is dependent on its structural glycoprotein (GP), but high levels of GP expression also trigger cell rounding, detachment, and downregulation of many surface mols. that is thought to contribute to its high pathogenicity. Thus, EBOV has evolved an RNA editing mechanism to reduce its GP expression and increase its fitness. We now report that the GP expression is also suppressed at the protein level in cells by protein disulfide isomerases (PDIs). Although PDIs promote oxidative protein folding by catalyzing correct disulfide formation in the endoplasmic reticulum (ER), PDIA3/ERp57 adversely triggered the GP misfolding by targeting GP cysteine residues and activated the unfolded protein response (UPR). Abnormally folded GP was targeted by ER-associated protein degradation (ERAD) machinery and, unexpectedly, was degraded via the macroautophagy/autophagylysosomal pathway, but not the proteasomal pathway. PDIA3 also decreased the GP expression from other ebolavirus species but increased the GP expression from Marburg virus (MARV), which is consistent with the observation that MARV-GP does not cause cell rounding and detachment, and MARV does not regulate its GP expression via RNA editing during infection. Furthermore, five other PDIs also had a similar inhibitory activity to EBOV-GP. Thus, PDIs neg. regulate ebolavirus glycoprotein expression, which balances the viral life cycle by maximizing their infection but minimizing their cellular effect. We suggest that ebolaviruses hijack the host protein folding and ERAD machinery to increase their fitness via reticulophagy during infection.

Autophagy published new progress about Ebolavirus. 55981-09-4 belongs to class esters-buliding-blocks, name is 2-((5-Nitrothiazol-2-yl)carbamoyl)phenyl acetate, and the molecular formula is C12H9N3O5S, Formula: C12H9N3O5S.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Cecchi, Lorenzo published the artcileExploitation of virgin olive oil by-products (Olea europaea L .): phenolic and volatile compounds transformations phenomena in fresh two-phase olive pomace (′alperujo′) under different storage conditions, Quality Control of 123-29-5, the main research area is olive oil Olea europaea phenolic volatile compound storage condition; HS-SPME-GC-MS; nutraceuticals; olive mill by-products; olive pomace storage; polyphenols; secoiridoids.

Much effort has recently been spent for re-using virgin olive oil byproducts as nutraceutical ingredients for human diet thanks to their richness in bioactive phenols, but their management is not easy for producers. We aimed to provide useful information for a better management of fresh olive pomace before drying, by studying the phenolic and volatile compounds transformations phenomena of fresh olive pomace stored under different conditions planned to simulate controlled and uncontrolled temperature conditions in olive oil mills. The evolution of the phenolic and volatile compounds was studied by high-performance liquid chromatog.-diode array detector mass spectrometry (HPLC-DAD-MS) and headspace solid-phase microextraction gas chromatog.-mass spectrometry (HS-SPME-GC-MS). The phenolic profile varied rapidly during storage: the verbascoside content decreased about 70% after 17 days even at 4 °C, while the content of simple phenols such as hydroxytyrosol and caffeic acid increased over time. The low temperature was able to slow down these phenomena. A total of 94 volatile organic compounds (VOCs) were detected in the fresh olive pomace, with a prevalence of lipoxygenase (LOX) VOCs (78%), mainly aldehydes (19 490.9μg kg-1) despite the higher number of alcs. A decrease in LOX volatiles and a quick development of the ones linked to off-flavors (carboxylic acids, alcs., acetates) were observed, in particular after 4 days of storage at room temperature Only storage at 4 °C allowed these phenomena to be slowed down. To preserve the natural phenolic phytocomplex of fresh olive pomace before drying and to avoid off-flavors development, storage in open containers must be avoided and a short storage in cold rooms (7-10 days) is to be preferred. 2021 The Authors. Journal of The Science of Food and Agriculture published by John Wiley & Sons Ltd on behalf of Society of Chem. Industry.

Journal of the Science of Food and Agriculture published new progress about Alcohols Role: BSU (Biological Study, Unclassified), PRP (Properties), BIOL (Biological Study). 123-29-5 belongs to class esters-buliding-blocks, name is Ethyl nonanoate, and the molecular formula is C11H22O2, Quality Control of 123-29-5.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Cecchi, Lorenzo published the artcileExploitation of virgin olive oil by-products (Olea europaea L .): phenolic and volatile compounds transformations phenomena in fresh two-phase olive pomace (′alperujo′) under different storage conditions, Category: esters-buliding-blocks, the main research area is olive oil Olea europaea phenolic volatile compound storage condition; HS-SPME-GC-MS; nutraceuticals; olive mill by-products; olive pomace storage; polyphenols; secoiridoids.

Much effort has recently been spent for re-using virgin olive oil byproducts as nutraceutical ingredients for human diet thanks to their richness in bioactive phenols, but their management is not easy for producers. We aimed to provide useful information for a better management of fresh olive pomace before drying, by studying the phenolic and volatile compounds transformations phenomena of fresh olive pomace stored under different conditions planned to simulate controlled and uncontrolled temperature conditions in olive oil mills. The evolution of the phenolic and volatile compounds was studied by high-performance liquid chromatog.-diode array detector mass spectrometry (HPLC-DAD-MS) and headspace solid-phase microextraction gas chromatog.-mass spectrometry (HS-SPME-GC-MS). The phenolic profile varied rapidly during storage: the verbascoside content decreased about 70% after 17 days even at 4 °C, while the content of simple phenols such as hydroxytyrosol and caffeic acid increased over time. The low temperature was able to slow down these phenomena. A total of 94 volatile organic compounds (VOCs) were detected in the fresh olive pomace, with a prevalence of lipoxygenase (LOX) VOCs (78%), mainly aldehydes (19 490.9μg kg-1) despite the higher number of alcs. A decrease in LOX volatiles and a quick development of the ones linked to off-flavors (carboxylic acids, alcs., acetates) were observed, in particular after 4 days of storage at room temperature Only storage at 4 °C allowed these phenomena to be slowed down. To preserve the natural phenolic phytocomplex of fresh olive pomace before drying and to avoid off-flavors development, storage in open containers must be avoided and a short storage in cold rooms (7-10 days) is to be preferred. 2021 The Authors. Journal of The Science of Food and Agriculture published by John Wiley & Sons Ltd on behalf of Society of Chem. Industry.

Journal of the Science of Food and Agriculture published new progress about Alcohols Role: BSU (Biological Study, Unclassified), PRP (Properties), BIOL (Biological Study). 111-11-5 belongs to class esters-buliding-blocks, name is Methyl octanoate, and the molecular formula is C9H18O2, Category: esters-buliding-blocks.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Cecchi, Lorenzo published the artcileExploitation of virgin olive oil by-products (Olea europaea L .): phenolic and volatile compounds transformations phenomena in fresh two-phase olive pomace (′alperujo′) under different storage conditions, Formula: C11H22O2, the main research area is olive oil Olea europaea phenolic volatile compound storage condition; HS-SPME-GC-MS; nutraceuticals; olive mill by-products; olive pomace storage; polyphenols; secoiridoids.

Much effort has recently been spent for re-using virgin olive oil byproducts as nutraceutical ingredients for human diet thanks to their richness in bioactive phenols, but their management is not easy for producers. We aimed to provide useful information for a better management of fresh olive pomace before drying, by studying the phenolic and volatile compounds transformations phenomena of fresh olive pomace stored under different conditions planned to simulate controlled and uncontrolled temperature conditions in olive oil mills. The evolution of the phenolic and volatile compounds was studied by high-performance liquid chromatog.-diode array detector mass spectrometry (HPLC-DAD-MS) and headspace solid-phase microextraction gas chromatog.-mass spectrometry (HS-SPME-GC-MS). The phenolic profile varied rapidly during storage: the verbascoside content decreased about 70% after 17 days even at 4 °C, while the content of simple phenols such as hydroxytyrosol and caffeic acid increased over time. The low temperature was able to slow down these phenomena. A total of 94 volatile organic compounds (VOCs) were detected in the fresh olive pomace, with a prevalence of lipoxygenase (LOX) VOCs (78%), mainly aldehydes (19 490.9μg kg-1) despite the higher number of alcs. A decrease in LOX volatiles and a quick development of the ones linked to off-flavors (carboxylic acids, alcs., acetates) were observed, in particular after 4 days of storage at room temperature Only storage at 4 °C allowed these phenomena to be slowed down. To preserve the natural phenolic phytocomplex of fresh olive pomace before drying and to avoid off-flavors development, storage in open containers must be avoided and a short storage in cold rooms (7-10 days) is to be preferred. 2021 The Authors. Journal of The Science of Food and Agriculture published by John Wiley & Sons Ltd on behalf of Society of Chem. Industry.

Journal of the Science of Food and Agriculture published new progress about Alcohols Role: BSU (Biological Study, Unclassified), PRP (Properties), BIOL (Biological Study). 110-42-9 belongs to class esters-buliding-blocks, name is Methyl decanoate, and the molecular formula is C11H22O2, Formula: C11H22O2.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Wang, Delong published the artcileGuaiacol as a natural melanin biosynthesis inhibitor to control northern corn leaf blight, Recommanded Product: Benzyl acetate, the main research area is guaiacol natural melanin essential oil corn leaf blight; DHN melanin biosynthesis inhibitor; guaiacol; northern corn leaf blight; plant essential oil compounds.

BACKGROUND : The natural 1,8-dihydroxynaphthalene (DHN) melanin biosynthesis inhibitors (MBIs) are one of the promising approaches to the integrated management of plant diseases but have received scarce attention until now. Herein, to explore the natural DHN MBIs used in the control of northern corn leaf blight (NCLB), a library of 53 essential oil compounds was used to screen the MBIs against Exserohilum turcicum, the causal pathogen of NCLB, using tricyclazole as a reference compound RESULTS : The results of morphol. change in the colony, thermogravimetric anal., UV-visible spectroscopy, and transmission electron microscopy confirmed that guaiacol could effectively inhibit the melanin production at 50 μg/mL under in vitro conditions. The in vitro bioassay results indicated that this inhibition effect was concentration-dependent and the min. inhibition concentration of guaiacol was 50 μg/mL. The in vivo exptl. results demonstrated that guaiacol significantly inhibited appressorium formation and penetration on corn leaf sheaths at the concentration of 500 μg/mL. The pot experiment results revealed that there were no differences between guaiacol (500 μg/mL) and tricyclazole (100 μg/mL) in control efficacy. The enzymic assay suggested that guaiacol might exert the activity through inhibiting DHN polymerization to form melanins, which was distinct from tricyclazole. CONCLUSIONS : Taken together, this study screened out guaiacol as a natural MBI from 53 essential oil compounds and verified its effectiveness in the control of NCLB at 500 μg/mL. Above all, this research opened an avenue for exploring natural DHN MBIs in the integrated management of plant diseases. 2022 Society of Chem. Industry.

Pest Management Science published new progress about Color. 140-11-4 belongs to class esters-buliding-blocks, name is Benzyl acetate, and the molecular formula is C9H10O2, Recommanded Product: Benzyl acetate.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Zhao, Yuechao published the artcileEffect of chemical component characteristics of waste cooking oil on physicochemical properties of aging asphalt, Category: esters-buliding-blocks, the main research area is waste cooking oil aging asphalt pavement physicochem property.

The combined utilization of waste cooking oil (WCO) and reclaimed asphalt pavement (RAP) is attractive for economic, environmental, and energy benefits. However, the quality stability of WCO is poor due to its wide sources, which limits the further development of WCO recycled RAP. In this study, the classification method of WCO was proposed according to the mol. weight difference of its chem. components, and WCO was classified into three categories including light components (LC), intermediate components (IC), and heavy components (HC). Meanwhile, the characteristics of these three WCO components and their effects on the physicochem. properties of aging asphalt were investigated comprehensively. The exptl. results show that the softening ability of different components of WCO on aging asphalt is mainly determined by their mol. weight and thermal stability. Furthermore, LC rich in Me palmitate is easy solidification and volume expansion at the low temperature, which is not conducive to the repair of low-temperature ductility of aged asphalt. The chem. property analyses of recycled asphalt indicate that there is no chem. reaction between the components of WCO and the aging asphalt. The phys. dilution ability of WCO components on carbonyl index, sulfoxide index, and high mol. weight substances of aging asphalt is pos. correlated with their mol. weight In addition, HC contains chem. substances similar in composition to asphalt, which has the most obvious effect on the colloidal structure of aging asphalt. Overall, the classification method for WCO and related findings found in this study provides a reference for ensuring the quality stability of WCO and its industrial application in the recycling of aged asphalt.

Construction and Building Materials published new progress about Asphaltenes Role: PEP (Physical, Engineering or Chemical Process), PRP (Properties), PROC (Process). 929-77-1 belongs to class esters-buliding-blocks, name is Methyl docosanoate, and the molecular formula is C23H46O2, Category: esters-buliding-blocks.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Rodriguez-Solana, Raquel published the artcileInfluence of elaboration process on chemical, biological, and sensory characteristics of European pennyroyal liqueurs, Category: esters-buliding-blocks, the main research area is pennyroyal liqueur chem biol sensory property; antioxidant capacity; enzyme inhibition; napping; pennyroyal liqueur processing; pulegone; total phenolic content.

Mentha pulegium is an aromatic and medicinal plant used in different Mediterranean herb-based liqueurs, whose phytochem. composition depends on the elaboration technique used. The aim of this work was to investigate differences in the sensory, chem., and biol. characteristics of pennyroyal liqueurs elaborated by hydro-alc. (HI) and aqueous (AI) infusions, percolation (P), maceration (M), and distillation (D) techniques, and by the mixture of spirit with pennyroyal essential oil (EO). The volatile composition determined by gas chromatog.-mass spectrometry (GC-MS) and gas chromatog. coupled to flame ionization detection (GC-FID), the total phenolic (TPC) and flavonoid (TFC) contents, the antioxidant (AC), and enzyme (α-glucosidase, tyrosinase, and acetylcholinesterase) inhibitory capacities, and the sensory anal. by napping, were evaluated in the liqueurs obtained. Monoterpenes and sesquiterpenes were the main volatiles present in liqueurs. The M, P, HI, and AI liqueurs showed the highest TPC, TFC, and AC values; and pulegone, the main hepatotoxic chemotype, was found in concentrations that gave rise to concern. The D and EO liqueurs stand out for their acceptable pulegone content and greater tyrosinase inhibition. Similar liqueur classifications were achieved by sensory analyses, and physico-chem. and biol. analyses using multiple factor and principal component analyses, resp. These results are an important contribution to the identification of the most appropriate elaboration conditions for herbal liqueurs with the healthiest chem. composition and functional properties.

Journal of the Science of Food and Agriculture published new progress about Antioxidants. 123-29-5 belongs to class esters-buliding-blocks, name is Ethyl nonanoate, and the molecular formula is C11H22O2, Category: esters-buliding-blocks.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics