On June 30, 2019, Lafuente, Leticia; Rochetti, Maria Florencia; Bravo, Rodolfo; Sasiambarrena, Leandro; Santiago, Cintia C.; Ponzinibbio, Agustin published an article.SDS of cas: 2873-29-2 The title of the article was Cu-Fe Spinels: First Heterogeneous and Magnetically Recoverable Catalyst for the Ferrier Rearrangement of 2-Nitroglycals. And the article contained the following:
Cu-Fe spinels promoted the Ferrier rearrangement of 2-nitroglycals with several O-nucleophiles. 2,3-Unsaturated carbohydrate derivatives were prepared by the reaction of 3,4,6-tri-Oacetyl- 2-nitroglucal and alcs. in the presence of 5% of CuFe2O4. After separation of the catalyst with an external magnet, the reaction products were obtained in good yields and high stereo and regioselectivity. Also, S- and heterocyclic C-3 substituted 2-nitro-endo-glycals could be prepared by this method. The experimental process involved the reaction of (2R,3S,4R)-2-(Acetoxymethyl)-3,4-dihydro-2H-pyran-3,4-diyl diacetate(cas: 2873-29-2).SDS of cas: 2873-29-2
The Article related to nitroglycal ferrier rearrangement structural morphol catalytic property, Catalysis, Reaction Kinetics, and Inorganic Reaction Mechanisms: Catalysts and other aspects.SDS of cas: 2873-29-2
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