On January 5, 1986, Iwasaki, Genji; Saeki, Seitaro; Hamana, Masatomo published an article.Safety of tert-Butyl 2-(4-nitrophenyl)acetate The title of the article was Nucleophilic substitution of p-dinitrobenzene with some carbanions. Formation of p-substituted nitrobenzenes. And the article contained the following:
Treatment of p-O2NC6H4NO2 with RH (R = CH2COMe, CHMeCOEt, CHEtCOMe, CMe2COCHMe2, CH2CO2Et, CH2CO2CMe3, CH2CN, CHPhCN, CMePhCN, PhNH 2-oxocyclopentyl, 2-oxocyclohexyl, cyano-1-naphthylmethyl, 2-pyridylamino) in the presence of Me3COK in liq NH3 at -70° gave p-O2NC6H4R in 18-97.6% yields. The experimental process involved the reaction of tert-Butyl 2-(4-nitrophenyl)acetate(cas: 29704-38-9).Safety of tert-Butyl 2-(4-nitrophenyl)acetate
The Article related to nitrobenzene nucleophile substitution, carbanion substitution dinitrobenzene, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Nitro and Nitroso Compounds and other aspects.Safety of tert-Butyl 2-(4-nitrophenyl)acetate
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