Tag: M.W=150-200

Recently I am researching about C BOND-CLEAVAGE; PHOTOREDOX CATALYSTS; CARBOXYLIC-ACIDS; DIBENZOPYRANONES; RADICALS; FUNCTIONALIZATION; C(SP(2))-H; COMPLEXES; LACTONES, Saw an article supported by the SERB, New Delhi [SB/S2/RJN-138/2018]. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Wadekar, K; Aswale, S; Yatham, VR. The CAS is 2005-10-9. Through research, I have a further understanding and discovery of 6H-Benzo[c]chromen-6-one. HPLC of Formula: C13H8O2

The first cerium photocatalyzed dehydrogenative lactonization of 2-arylbenzoic acids has been developed. This operationally simple protocol allows rapid access to synthetically useful coumarins on gram scale by employing CeCl3 as a photocatalyst and O-2 as a terminal oxidant. Overall, this delivers an economical and environmentally amiable entry to diversely substituted coumarins, important structural motifs in bioactive molecules.

HPLC of Formula: C13H8O2. Welcome to talk about 2005-10-9, If you have any questions, you can contact Wadekar, K; Aswale, S; Yatham, VR or send Email.

Reference:
Article; Zhang, Jian; Shi, Dongdong; Zhang, Haifeng; Xu, Zheng; Bao, Hanyang; Jin, Hongwei; Liu, Yunkui; Tetrahedron; vol. 73; 2; (2017); p. 154 – 163;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Recommanded Product: 2005-10-9. In 2019.0 CHEM-EUR J published article about ELECTRON-TRANSFER PROCESS; Z ISOMERIZATION; PHOTOOXIDATIVE DECARBOXYLATION; PHOTOCATALYTIC E; PI INTERACTIONS; ACTIVATION; OXIDATION; CLEAVAGE in [Hauptmann, Richy; Petrosyan, Andranik; Cordero, Miguel A. Argueello; Surkus, Annette-E; Pospech, Jola] Univ Rostock, Leibniz Inst Catalysis, Albert Einstein Str 29a, D-18059 Rostock, Germany; [Fennel, Franziska; Cordero, Miguel A. Argueello] Univ Rostock, Inst Phys, Dynam Mol Syst, Albert Einstein Str 23-24, D-18059 Rostock, Germany in 2019.0, Cited 33.0. The Name is 6H-Benzo[c]chromen-6-one. Through research, I have a further understanding and discovery of 2005-10-9.

Herein we report the photo- and electrochemical characterization of pyrimidopteridine N-oxide-based heterocycles. The potential of their application as organic photoredox catalysts is showcased in the photomediated contra-thermodynamic E -> Z isomerization of cinnamic acid derivatives and oxidative cyclization of 2-phenyl benzoic acid to benzocoumarin using molecular oxygen as a mild oxidant. Furthermore, unprecedented intermolecular non-covalent n-pi-hole interactions in solid state are discussed based on crystallographic and theoretical data.

About 6H-Benzo[c]chromen-6-one, If you have any questions, you can contact Hauptmann, R; Petrosyan, A; Fennel, F; Cordero, MAA; Surkus, AE; Pospech, J or concate me.. Recommanded Product: 2005-10-9

Reference:
Article; Zhang, Jian; Shi, Dongdong; Zhang, Haifeng; Xu, Zheng; Bao, Hanyang; Jin, Hongwei; Liu, Yunkui; Tetrahedron; vol. 73; 2; (2017); p. 154 – 163;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Safety of 6H-Benzo[c]chromen-6-one. In 2019.0 CHEMISTRYSELECT published article about BAEYER-VILLIGER OXIDATION; SELECTIVE OXIDATION; AROMATIC-ALDEHYDES; CATALYTIC THIOCYANATION; EFFICIENT BROMINATION; SODIUM PERCARBONATE; BENZYLIC ALCOHOLS; HYDROGEN-PEROXIDE; AMIDATION; EPOXIDATION in [Khosravi, Kaveh; Naserifar, Shirin] Arak Univ, Dept Chem, Fac Sci, Arak 3815688349, Iran in 2019.0, Cited 61.0. The Name is 6H-Benzo[c]chromen-6-one. Through research, I have a further understanding and discovery of 2005-10-9.

Urea-2,2-dihydroperoxypropane (UDHPP)- a white crystalline solid oxidant which is formed when urea is recrystallized from dihydroperoxypropane- was applied as the terminal oxidant in several oxidative procedures namely epoxidation of alpha, beta-unsaturated ketones and alkenes, oxidation of sulfides to sulfoxides and sulfones, bayer-villeger reaction, bromination and iodation of aniline and phenol derivatives, oxidative esterification, oxidative amidation of aromatic aldehydes, thiocyanation of aromatic compounds, and oxidation of pyridines, oxidation of secondary, allylic and benzylic alcohols. All the approaches were carried out under mild conditions and short reaction times and afforded the corresponding products in high yields.

Welcome to talk about 2005-10-9, If you have any questions, you can contact Khosravi, K; Naserifar, S or send Email.. Safety of 6H-Benzo[c]chromen-6-one

Reference:
Article; Zhang, Jian; Shi, Dongdong; Zhang, Haifeng; Xu, Zheng; Bao, Hanyang; Jin, Hongwei; Liu, Yunkui; Tetrahedron; vol. 73; 2; (2017); p. 154 – 163;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

An article Methyl Trifluoroacetate as a Methylation Reagent for N-H, O-H, and S-H Functionalities under Mild Conditions WOS:000477363700001 published article about CATALYZED METHYLATION; DIMETHYL CARBONATE; IONIC LIQUIDS; AMINES; DERIVATIVES; METHANOL; ACID; TRIFLUOROMETHYLATION; GENERATION; DIOXIDE in [Zheng, Xin; Zeng, Jiechun; Xiong, Mindong; Huang, Jiawei; Li, Cuiyan; Zhou, Rujin; Xiao, Duoduo] Guangdong Univ Petrochem Technol, Coll Chem, Maoming 525000, Peoples R China in 2019.0, Cited 60.0. SDS of cas: 103-25-3. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3

A methylation reagent for compounds bearing N-H, O-H, and S-H functionalities was developed. Methyl trifluoroacetate (MTFA) was commonly considered as trifluoroacetylating reagent or trifluoromethylating reagent. In this work, we report the methylation behavior of MTFA under mild conditions with good functional group tolerance, allowing the transformation of a wide range of substrates, including N,H-heteroaromatic compounds, phenolic compounds, carboxylic acids, thiophenols, secondary amides and imides, in high yields. This method was preliminarily applied to the chemoselective methylation of bifunctionalized secondary amide.

About Methyl 3-phenylpropionate, If you have any questions, you can contact Zheng, X; Zeng, JC; Xiong, MD; Huang, JW; Li, CY; Zhou, RJ; Xiao, DD or concate me.. SDS of cas: 103-25-3

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

In 2019.0 CHINESE J CHEM published article about C-H TRIFLUOROMETHYLATION; OXIDATIVE TRIFLUOROMETHYLATION; ALKENES; BONDS; DIFUNCTIONALIZATION; FUNCTIONALIZATION; ALKYNES; OXYTRIFLUOROMETHYLATION; PERFLUOROALKYLATION; AMINOACETOXYLATION in [Wang, Yin] Lanzhou Univ, Sch Nucl Sci & Technol, Radiochem Lab, Lanzhou 730000, Gansu, Peoples R China; [Wang, Yin; Yang, Yunhui; Wang, Congyang] Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Mol Recognit & Funct, CAS Res Educ Ctr Excellence Mol Sci,Inst Chem, Beijing 100190, Peoples R China; [Wang, Yin; Yang, Yunhui; Wang, Congyang] Univ Chinese Acad Sci, Beijing 100049, Peoples R China; [Yang, Yunhui; Wang, Congyang] Huairou Natl Comprehens Sci Ctr, Phys Sci Lab, Beijing 101400, Peoples R China in 2019.0, Cited 110.0. The Name is Methyl 3-phenyl-2-propenoate. Through research, I have a further understanding and discovery of 103-26-4. COA of Formula: C10H10O2

of main observation and conclusion Herein, unprecedented rhenium-catalyzed decarboxylative oxytri-/difluoromethylation and Heck-type trifluoromethylation of styrenes have been developed by using hypervalent iodine(III) reagents derived from cheap, stable, and easy-handling fluorinated carboxylic acids. Mechanistic studies revealed a radical decarboxylative trifluoromethylation pathway occurring in these reactions.

COA of Formula: C10H10O2. Bye, fridends, I hope you can learn more about C10H10O2, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Article; Weng, Shiue-Shien; Ke, Chih-Shueh; Chen, Fong-Kuang; Lyu, You-Fu; Lin, Guan-Ying; Tetrahedron; vol. 67; 9; (2011); p. 1640 – 1648;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

In 2020.0 CHINESE J CATAL published article about METAL-SUPPORT INTERACTIONS; ISOMERIZING ALKOXYCARBONYLATION; OXIDATIVE DEHYDROGENATION; RU/CEO2 CATALYSTS; ALCOHOLS; EFFICIENT; CERIA; CO; NANOPARTICLES; CEO2 in [An, Jinghua; Wang, Yehong; Zhang, Zhixin; Zhang, Jian; Wang, Feng] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China; [An, Jinghua] Univ Chinese Acad Sci, Beijing 100049, Peoples R China; [Gocyla, Martin; Dunin-Borkowski, Rafal E.] Forschungszentrum Julich, Ernst Ruska Ctr Microscopy & Spect Electron, D-52425 Julich, Germany; [Gocyla, Martin; Dunin-Borkowski, Rafal E.] Forschungszentrum Julich, Peter Grunberg Inst, D-52425 Julich, Germany in 2020.0, Cited 45.0. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3. COA of Formula: C10H12O2

Hydroalkoxycarbonylation of olefins has been considered to be one of the most attractive methods to synthesize esters. Controlling the regioselectivities of linear esters (L) and branched esters (B) is a challenging project for researchers working in this reaction. Although most of the attention has been paid to control the regioselectivity through ligand design in homogeneous catalytic systems, study in the area is still limited. Herein, Ru-clusters/CeO2 is employed as a heterogeneous catalyst for the hydromethoxycarbonylation of styrene without any additives. After optimization of the reaction conditions, the conversion of styrene is > 99% with 83% and 12% regioselectivity of linear and branched ester, respectively. By using different supports (CeO2 (nanoparticle), CeO2-rod, and CeO2-cube), three catalysts including Ru-clusters/CeO2, Ru/CeO2-rod, and Ru/CeO2-cube are prepared and applied in the reaction. Structural characterizations demonstrate that the L/B ratio is related to the Ru size of supported Ru catalysts. Further Raman characterization and NH3-TPD demonstrate that the metal-support interaction and the concentration of oxygen vacancy of the catalyst have a great influence on the Ru size. The mechanism and kinetic analysis for this reaction are also investigated in this work. (C) 2020, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.

COA of Formula: C10H12O2. Bye, fridends, I hope you can learn more about C10H12O2, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Formula: C10H10O2. In 2019.0 BIOCHEM PHARMACOL published article about ENDOTHELIAL-CELLS; IMPROVES SURVIVAL; ANGELICA-GIGAS; SEPSIS; LIPOPOLYSACCHARIDE; DAMAGE in [Lee, Wonhwa] KRIBB, Aging Res Ctr, Daejeon 34141, South Korea; [Yuseok, O.; Song, Gyu-Yong] Chungnam Natl Univ, Coll Pharm, 99 Daehak Ro, Daejon 34134, South Korea; [Lee, Changhun; Jeong, So Yeon; Bae, Jong-Sup] Kyungpook Natl Univ, BK21 Plus KNU Multiomits Based Creat Drug Res Tea, Pharmaceut Sci Res Inst, Coll Pharm,CMRI, Daegu 41566, South Korea; [Lee, Jee-Hyun; Song, Gyu-Yong] AREZ Co Ltd, 197 Songam Ro, Sejong 30066, South Korea; [Baek, Moon-Chang] Kyungpook Natl Univ, Sch Med, CMRI, Dept Mol Med, Daegu 700422, South Korea in 2019.0, Cited 36.0. The Name is Methyl 3-phenyl-2-propenoate. Through research, I have a further understanding and discovery of 103-26-4.

In the present study, several decursin analogues (KC1-3) were synthesized and evaluated in terms of their antiseptic activities on high mobility group box 1 (HMGB1)-mediated septic responses and survival rate in a mouse model of sepsis. KC1 and KC3, but not KC2, significantly reduced HMGB1 release in lipopolysaccharide (LPS)-activated human umbilical vein endothelial cells (HUVECs) and attenuated the cecal ligation and puncture (CLP)-induced release of HMGB1. Additionally, in vitro analyses revealed that KC1 and KC3 both alleviated HMGB1-mediated vascular disruptions and inhibited hyperpermeability in mice, and in vivo analyses revealed that KC1 and KC3 reduced sepsis-related mortality and tissue injury. Taken together, the present results suggest that KC1 and KC3 both reduced HMGB1 release and septic mortality and, thus, may be useful for the treatment of sepsis.

Bye, fridends, I hope you can learn more about C10H10O2, If you have any questions, you can browse other blog as well. See you lster.. Formula: C10H10O2

Reference:
Article; Weng, Shiue-Shien; Ke, Chih-Shueh; Chen, Fong-Kuang; Lyu, You-Fu; Lin, Guan-Ying; Tetrahedron; vol. 67; 9; (2011); p. 1640 – 1648;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Computed Properties of C10H10O2. Authors Adnan, M; Siddiqui, AJ; Hamadou, WS; Patel, M; Ashraf, SA; Jamal, A; Awadelkareem, AM; Sachidanandan, M; Snoussi, M; De Feo, V in MDPI published article about in [Adnan, Mohd; Siddiqui, Arif Jamal; Hamadou, Walid Sabri; Jamal, Arshad; Snoussi, Mejdi] Univ Hail, Dept Biol, Coll Sci, Hail 2440, Saudi Arabia; [Patel, Mitesh] Veer Narmad South Gujarat Univ, Dept Biosci, Bapalal Vaidya Bot Res Ctr, Surat 395007, India; [Ashraf, Syed Amir; Awadelkareem, Amir Mahgoub] Univ Hail, Dept Clin Nutr, Coll Appl Medial Sci, Hail 2440, Saudi Arabia; [Sachidanandan, Manojkumar] Univ Hail, Dept Oral Radiol, Coll Dent, Hail 2440, Saudi Arabia; [Snoussi, Mejdi] Univ Monastir, High Inst Biotechnol, Lab Genet Biodivers & Valorisat Bioresources, Monastir 5000, Tunisia; [De Feo, Vincenzo] Univ Salerno, Dept Pharm, Via Giovanni Paolo II,132, I-84084 Salerno, Italy in 2021.0, Cited 89.0. The Name is Methyl 3-phenyl-2-propenoate. Through research, I have a further understanding and discovery of 103-26-4

In this study, we investigated the bioactive potential (antibacterial and antioxidant), anticancer activity and detailed phytochemical analysis of Selaginella repanda (S. repanda) ethanolic crude extract for the very first time using different in vitro approaches. Furthermore, computer-aided prediction of pharmacokinetic properties and safety profile of the identified phytoconstituents were also employed in order to provide some useful insights for drug discovery. S. repanda, which is a rich source of potent natural bioactive compounds, showed promising antibacterial activity against the tested pathogenic bacteria (S. aureus, P. aeruginosa, E. coli and S. flexneri). The crude extract displayed favorable antioxidant activity against both 2,2-diphenyl-1-picrylhydrazyl (DPPH) (IC50 = 231.6 mu g/mL) and H2O2 (IC50 = 288.3 mu g/mL) molecules. S. repanda also showed favorable and effective anticancer activity against all three malignant cancer cells in a dose/time dependent manner. Higher activity was found against lung (A549) (IC50 = 341.1 mu g/mL), followed by colon (HCT-116) (IC50 = 378.8 mu g/mL) and breast (MCF-7) (IC50 = 428.3 mu g/mL) cancer cells. High resolution-liquid chromatography-mass spectrometry (HR-LC-MS) data of S. repanda crude extract revealed the presence of diverse bioactive/chemical components, including fatty acids, alcohol, sugar, flavonoids, alkaloids, terpenoids, coumarins and phenolics, which can be the basis and major cause for its bioactive potential. Therefore, achieved results from this study confirmed the efficacy of S. repanda and a prospective source of naturally active biomolecules with antibacterial, antioxidant and anticancer potential. These phytocompounds alone with their favorable pharmacokinetics profile suggests good lead and efficiency of S. repanda with no toxicity risks. Finally, further in vivo experimental investigations can be promoted as probable candidates for various therapeutic functions, drug discovery and development.

Computed Properties of C10H10O2. Welcome to talk about 103-26-4, If you have any questions, you can contact Adnan, M; Siddiqui, AJ; Hamadou, WS; Patel, M; Ashraf, SA; Jamal, A; Awadelkareem, AM; Sachidanandan, M; Snoussi, M; De Feo, V or send Email.

Reference:
Article; Weng, Shiue-Shien; Ke, Chih-Shueh; Chen, Fong-Kuang; Lyu, You-Fu; Lin, Guan-Ying; Tetrahedron; vol. 67; 9; (2011); p. 1640 – 1648;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Recently I am researching about CHARGE-TRANSFER; ORGANIC COCRYSTALS; MOLECULAR-COMPLEX; DESIGN; ANTHRACENE; PYRENE; WILL, Saw an article supported by the Engineering and Physical Sciences Research Council (EPSRC)UK Research & Innovation (UKRI)Engineering & Physical Sciences Research Council (EPSRC) [EP/S026339/1]; EPSRCUK Research & Innovation (UKRI)Engineering & Physical Sciences Research Council (EPSRC) [EP/R018472/1]; Leverhulme TrustLeverhulme Trust; Leverhulme Research Centre for Functional Materials Design via the Leverhulme Research Centre for Functional Materials Design [RC-2015-036]; Cambridge Crystallographic Data Centre. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Vriza, A; Canaj, AB; Vismara, R; Cook, LJK; Manning, TD; Gaultois, MW; Wood, PA; Kurlin, V; Berry, N; Dyer, MS; Rosseinsky, MJ. The CAS is 2005-10-9. Through research, I have a further understanding and discovery of 6H-Benzo[c]chromen-6-one. COA of Formula: C13H8O2

The implementation of machine learning models has brought major changes in the decision-making process for materials design. One matter of concern for the data-driven approaches is the lack of negative data from unsuccessful synthetic attempts, which might generate inherently imbalanced datasets. We propose the application of the one-class classification methodology as an effective tool for tackling these limitations on the materials design problems. This is a concept of learning based only on a well-defined class without counter examples. An extensive study on the different one-class classification algorithms is performed until the most appropriate workflow is identified for guiding the discovery of emerging materials belonging to a relatively small class, that being the weakly bound polyaromatic hydrocarbon co-crystals. The two-step approach presented in this study first trains the model using all the known molecular combinations that form this class of co-crystals extracted from the Cambridge Structural Database (1722 molecular combinations), followed by scoring possible yet unknown pairs from the ZINC15 database (21 736 possible molecular combinations). Focusing on the highest-ranking pairs predicted to have higher probability of forming co-crystals, materials discovery can be accelerated by reducing the vast molecular space and directing the synthetic efforts of chemists. Further on, using interpretability techniques a more detailed understanding of the molecular properties causing co-crystallization is sought after. The applicability of the current methodology is demonstrated with the discovery of two novel co-crystals, namely pyrene-6H-benzo[c]chromen-6-one (1) and pyrene-9,10-dicyanoanthracene (2).

COA of Formula: C13H8O2. Bye, fridends, I hope you can learn more about C13H8O2, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Article; Zhang, Jian; Shi, Dongdong; Zhang, Haifeng; Xu, Zheng; Bao, Hanyang; Jin, Hongwei; Liu, Yunkui; Tetrahedron; vol. 73; 2; (2017); p. 154 – 163;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

An article Carboxylation of Aryl Triflates with CO2 Merging Palladium and Visible-Light-Photoredox Catalysts WOS:000473116000050 published article about C-H FUNCTIONALIZATION; CARBON-DIOXIDE; DUAL CATALYSIS; DRIVEN CARBOXYLATION; UNACTIVATED PRIMARY; BUILDING-BLOCK; BONDS; HALIDES; ACIDS; HYDROCARBOXYLATION in [Bhunia, Samir Kumar; Das, Pritha; Nandi, Shantanu; Jana, Ranjan] CSIR Indian Inst Chem Biol, Organ & Med Chem Div, 4 Raja SC Mullick Rd, Kolkata 700032, W Bengal, India; [Bhunia, Samir Kumar; Jana, Ranjan] Acad Sci & Innovat Res AcSIR, Kolkata 700032, W Bengal, India in 2019.0, Cited 88.0. The Name is 6H-Benzo[c]chromen-6-one. Through research, I have a further understanding and discovery of 2005-10-9. Computed Properties of C13H8O2

We report herein a visible-light-promoted, highly practical carboxylation of readily accessible aryl triflates at ambient temperature and a balloon pressure of CO2 by the combined use of palladium and photoredox Ir(III) catalysts. Strikingly, the stoichiometric metallic reductant is replaced by a nonmetallic amine reductant providing an environmentally benign carboxylation process. In addition, one-pot synthesis of a carboxylic acid directly from phenol and modification of estrone and concise synthesis of pharmaceutical drugs adapalene and bexarotene have been accomplished via late-stage carboxylation reaction. Furthermore, a parallel decarboxylation-carboxylation reaction has been demonstrated in an H-type closed vessel that is an interesting concept for the strategic sector. Spectroscopic and spectroelectrochemical studies indicated electron transfer from the Ir(III)/DIPEA combination to generate aryl carboxylate and Pd(0) for catalytic turnover.

Computed Properties of C13H8O2. Bye, fridends, I hope you can learn more about C13H8O2, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Article; Zhang, Jian; Shi, Dongdong; Zhang, Haifeng; Xu, Zheng; Bao, Hanyang; Jin, Hongwei; Liu, Yunkui; Tetrahedron; vol. 73; 2; (2017); p. 154 – 163;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics