Tag: M.W=150-200

Quality Control of Methyl 3-phenylpropionate. I found the field of Chemistry; Engineering very interesting. Saw the article Linear-regioselective hydromethoxycarbonylation of styrene using Ru-clusters/CeO2 catalyst published in 2020.0, Reprint Addresses Wang, F (corresponding author), Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China.. The CAS is 103-25-3. Through research, I have a further understanding and discovery of Methyl 3-phenylpropionate.

Hydroalkoxycarbonylation of olefins has been considered to be one of the most attractive methods to synthesize esters. Controlling the regioselectivities of linear esters (L) and branched esters (B) is a challenging project for researchers working in this reaction. Although most of the attention has been paid to control the regioselectivity through ligand design in homogeneous catalytic systems, study in the area is still limited. Herein, Ru-clusters/CeO2 is employed as a heterogeneous catalyst for the hydromethoxycarbonylation of styrene without any additives. After optimization of the reaction conditions, the conversion of styrene is > 99% with 83% and 12% regioselectivity of linear and branched ester, respectively. By using different supports (CeO2 (nanoparticle), CeO2-rod, and CeO2-cube), three catalysts including Ru-clusters/CeO2, Ru/CeO2-rod, and Ru/CeO2-cube are prepared and applied in the reaction. Structural characterizations demonstrate that the L/B ratio is related to the Ru size of supported Ru catalysts. Further Raman characterization and NH3-TPD demonstrate that the metal-support interaction and the concentration of oxygen vacancy of the catalyst have a great influence on the Ru size. The mechanism and kinetic analysis for this reaction are also investigated in this work. (C) 2020, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.

Quality Control of Methyl 3-phenylpropionate. Bye, fridends, I hope you can learn more about C10H12O2, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Authors An, JH; Wang, YH; Zhang, ZX; Zhang, J; Gocyla, M; Dunin-Borkowski, RE; Wang, F in SCIENCE PRESS published article about METAL-SUPPORT INTERACTIONS; ISOMERIZING ALKOXYCARBONYLATION; OXIDATIVE DEHYDROGENATION; RU/CEO2 CATALYSTS; ALCOHOLS; EFFICIENT; CERIA; CO; NANOPARTICLES; CEO2 in [An, Jinghua; Wang, Yehong; Zhang, Zhixin; Zhang, Jian; Wang, Feng] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China; [An, Jinghua] Univ Chinese Acad Sci, Beijing 100049, Peoples R China; [Gocyla, Martin; Dunin-Borkowski, Rafal E.] Forschungszentrum Julich, Ernst Ruska Ctr Microscopy & Spect Electron, D-52425 Julich, Germany; [Gocyla, Martin; Dunin-Borkowski, Rafal E.] Forschungszentrum Julich, Peter Grunberg Inst, D-52425 Julich, Germany in 2020.0, Cited 45.0. Formula: C10H12O2. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3

Hydroalkoxycarbonylation of olefins has been considered to be one of the most attractive methods to synthesize esters. Controlling the regioselectivities of linear esters (L) and branched esters (B) is a challenging project for researchers working in this reaction. Although most of the attention has been paid to control the regioselectivity through ligand design in homogeneous catalytic systems, study in the area is still limited. Herein, Ru-clusters/CeO2 is employed as a heterogeneous catalyst for the hydromethoxycarbonylation of styrene without any additives. After optimization of the reaction conditions, the conversion of styrene is > 99% with 83% and 12% regioselectivity of linear and branched ester, respectively. By using different supports (CeO2 (nanoparticle), CeO2-rod, and CeO2-cube), three catalysts including Ru-clusters/CeO2, Ru/CeO2-rod, and Ru/CeO2-cube are prepared and applied in the reaction. Structural characterizations demonstrate that the L/B ratio is related to the Ru size of supported Ru catalysts. Further Raman characterization and NH3-TPD demonstrate that the metal-support interaction and the concentration of oxygen vacancy of the catalyst have a great influence on the Ru size. The mechanism and kinetic analysis for this reaction are also investigated in this work. (C) 2020, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.

Bye, fridends, I hope you can learn more about C10H12O2, If you have any questions, you can browse other blog as well. See you lster.. Formula: C10H12O2

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

In 2020.0 J ORG CHEM published article about COUPLING REACTION; HYDROCARBONS; HALOGENATION; ACID; HALIDES; MILD; 9-MESITYL-10-METHYLACRIDINIUM; SUCCINIMIDYL; COMPLEXES; OXIDATION in [Xiang, Ming; Zhou, Chao; Yang, Xiu-Long; Chen, Bin; Tung, Chen-Ho; Wu, Li-Zhu] Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Photochem Convers & Optoelect Mat, Beijing 100190, Peoples R China; [Xiang, Ming; Zhou, Chao; Yang, Xiu-Long; Chen, Bin; Tung, Chen-Ho; Wu, Li-Zhu] Chinese Acad Sci, Univ Chinese Acad Sci, Beijing 100190, Peoples R China; [Xiang, Ming; Zhou, Chao; Yang, Xiu-Long; Chen, Bin; Tung, Chen-Ho; Wu, Li-Zhu] Univ Chinese Acad Sci, Sch Future Technol, Beijing 100049, Peoples R China in 2020.0, Cited 48.0. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3. Name: Methyl 3-phenylpropionate

By combining N-chlorosuccinimide (NCS)” as the safe chlorine source with Acr(+)-Mes as the photocatalyst, we successfully achieved benzylic C-H bond chlorination under visible light irradiation. Furthermore, benzylic chlorides could be converted to benzylic ethers smoothly in a one-pot manner by adding sodium methoxide. This mild and scalable chlorination method worked effectively for diverse toluene derivatives, especially for electron-deficient substrates. Careful mechanistic studies supported that NCS provided a hydrogen abstractor N-centered succinimidyl radical, which was responsible for the cleavage of the benzylic C-H bond, relying on the reducing ability of Acr(center dot)-Mes.

Bye, fridends, I hope you can learn more about C10H12O2, If you have any questions, you can browse other blog as well. See you lster.. Name: Methyl 3-phenylpropionate

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

SDS of cas: 103-26-4. Labulo, AH; Omondi, B; Nyamori, VO in [Labulo, Ayomide H.; Omondi, Bernard; Nyamori, Vincent O.] Univ KwaZulu Natal, Sch Chem & Phys, Westville Campus,Private Bag X54001, Durban, South Africa published Graphene/pyrrolic-structured nitrogen-doped CNT nanocomposite supports for Pd-catalysed Heck coupling and chemoselective hydrogenation of nitroarenes in 2019.0, Cited 110.0. The Name is Methyl 3-phenyl-2-propenoate. Through research, I have a further understanding and discovery of 103-26-4.

This work focused on the synthesis of 3D Pd-based nanocomposites which were tested in Heck coupling reactions and for the hydrogenation of nitroarenes. This was achieved by fabrication of graphene oxide/nitrogen-doped carbon nanotubes (G/N-CNTs) by mechanical grinding of 2D graphene oxide (GO) and 1D oxygen-treated nitrogen-doped CNTs (N-CNTs-OT) in a 3:1 ratio, respectively. The fabrication of G/N-CNTs is to overcome the habitual aggregation and restacking of graphene sheets. Palladium nanoparticles (Pd NPs) were deposited on the 3D G/N-CNTs nanocomposites via metal organic chemical vapour deposition method. The 3D Pd-based nanocomposites were characterized by TEM, SEM, HRTEM, XRD, TGA, XPS, ICP-OES, elemental analysis, BET analysis and Raman spectroscopy. For the Heck coupling reactions, aryl halides, olefins and 3D Pd-based nanocomposites were mixed in a suitable solvent and the reaction carried under microwave irradiation.The chemoselective hydrogenation of nitroarenes was done with dry ethanol in a Paar reactor, purged with H-2 gas. These catalysts demonstrate excellent activity and selectivity in both reactions. The remarkable activity of the 3D Pd-based nanocomposites in Heck reactions and hydrogenation of nitroarenes may be attributed to the small particle size (3-10 nm) and a high degree of dispersion of Pd NPs. A comparative experiment was conducted with Pd/AC, Pd/CNTs, Pd/G/CNTs and Pd/rGO. Pd/G/N-CNTs-OT showed higher activity and selectivity than Pd/G/CNTs, Pd/G/N-CNTs, Pd/rGO and Pd/N-CNTs counterpart.

SDS of cas: 103-26-4. About Methyl 3-phenyl-2-propenoate, If you have any questions, you can contact Labulo, AH; Omondi, B; Nyamori, VO or concate me.

Reference:
Article; Weng, Shiue-Shien; Ke, Chih-Shueh; Chen, Fong-Kuang; Lyu, You-Fu; Lin, Guan-Ying; Tetrahedron; vol. 67; 9; (2011); p. 1640 – 1648;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

An article Larvicidal Activity of Cinnamic Acid Derivatives: Investigating Alternative Products for Aedes aegypti L. Control WOS:000606118200001 published article about ESSENTIAL OILS; ACETYLCHOLINESTERASE 1; ESTERS; INHIBITION; QSAR; GUI in [Araujo, Marianna O.; Sousa, Damiao P. de] Univ Fed Paraiba, Post Grad Program Nat & Synthet Bioact Prod, BR-58051900 Joao Pessoa, Paraiba, Brazil; [Perez-Castillo, Yunierkis] Univ Las Amer, Biocheminformat Res Grp, Quito 170125, Ecuador; [Perez-Castillo, Yunierkis] Univ Las Amer, Escuela Ciencias Fis & Matemat, Quito 170125, Ecuador; [Oliveira, Louise H. G.; Nunes, Fabiola C.] Univ Fed Paraiba, Biotechnol Ctr, BR-58051900 Joao Pessoa, Paraiba, Brazil; [Sousa, Damiao P. de] Univ Fed Paraiba, Dept Pharmaceut Sci, BR-58051970 Joao Pessoa, Paraiba, Brazil in 2021.0, Cited 67.0. The Name is Methyl 3-phenyl-2-propenoate. Through research, I have a further understanding and discovery of 103-26-4. Recommanded Product: Methyl 3-phenyl-2-propenoate

The mosquito Aedes aegypti transmits the virus that causes dengue, yellow fever, Zika and Chikungunya viruses, and in several regions of the planet represents a vector of great clinical importance. In terms of mortality and morbidity, infections caused by Ae. aegypti are among the most serious arthropod transmitted viral diseases. The present study investigated the larvicidal potential of seventeen cinnamic acid derivatives against fourth stage Ae. aegypti larvae. The larvicide assays were performed using larval mortality rates to determine lethal concentration (LC50). Compounds containing the medium alkyl chains butyl cinnamate (7) and pentyl cinnamate (8) presented excellent larvicidal activity with LC50 values of around 0.21-0.17 mM, respectively. While among the derivatives with aryl substituents, the best LC50 result was 0.55 mM for benzyl cinnamate (13). The tested derivatives were natural compounds and in pharmacology and antiparasitic studies, many have been evaluated using biological models for environmental and toxicological safety. Molecular modeling analyses suggest that the larvicidal activity of these compounds might be due to a multi-target mechanism of action involving inhibition of a carbonic anhydrase (CA), a histone deacetylase (HDAC2), and two sodium-dependent cation-chloride co-transporters (CCC2 e CCC3).

Welcome to talk about 103-26-4, If you have any questions, you can contact Araujo, MO; Perez-Castillo, Y; Oliveira, LHG; Nunes, FC; de Sousa, DP or send Email.. Recommanded Product: Methyl 3-phenyl-2-propenoate

Reference:
Article; Weng, Shiue-Shien; Ke, Chih-Shueh; Chen, Fong-Kuang; Lyu, You-Fu; Lin, Guan-Ying; Tetrahedron; vol. 67; 9; (2011); p. 1640 – 1648;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

I found the field of Chemistry very interesting. Saw the article Pd-catalyzed alkoxycarbonylation of alkenes promoted by H2O free of auxiliary acid additive published in 2020.0. SDS of cas: 103-25-3, Reprint Addresses Liu, Y (corresponding author), East China Normal Univ, Sch Chem & Mol Engn, Shanghai Key Lab Green Chem & Chem Proc, 3663 North Zhongshan Rd, Shanghai 200062, Peoples R China.. The CAS is 103-25-3. Through research, I have a further understanding and discovery of Methyl 3-phenylpropionate

The Pd-catalyzed alkoxycarbonylation of alkenes using water as a promoter has been scarcely reported before. Herein, water instead of Bronsted/Lewis acid was found to effectively improve the catalytic performance of Pd (MeCN)(2)Cl-2-Xantphos system for alkoxycarbonylation of alkenes. Under the optimal conditions, the best yield of 97% was obtained for the target products (methyl 3-phenylpropanoate and methyl 2-phenylpropanoate) with L/B of 4.3 and TON of 192. With the involvement of water, Pd(MeCN)(2)Cl-2-Xantphos system also exhibited the moderate to good generality to alkoxycarbonylation of different kinds of alkenes with alcohols. The in situ high pressure FT-IR analysis verified that water played an important role in promoting formation and stability of Pd-H active species which was responsible for the efficient alkoxycarbonylation of alkenes. In addition, the ligand effect of Xantphos on this reaction was discussed.

Bye, fridends, I hope you can learn more about C10H12O2, If you have any questions, you can browse other blog as well. See you lster.. SDS of cas: 103-25-3

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

An article Palladium-catalysed alkyne alkoxycarbonylation with P,N-chelating ligands revisited: a density functional theory study WOS:000465603200031 published article about GENERALIZED GRADIENT APPROXIMATION; METHYL PROPANOATE; CARBON-MONOXIDE; COMPLEXES; CARBONYLATION; MECHANISM; METHOXYCARBONYLATION; CHEMISTRY; EXCHANGE; METHANOL in [Ahmad, Shahbaz; Lockett, Ashley; Buhl, Michael] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland; [Shuttleworth, Timothy A.; Miles-Hobbs, Alexandra M.; Pringle, Paul G.] Univ Bristol, Bristol BS8 1TS, Avon, England in 2019.0, Cited 70.0. Product Details of 103-26-4. The Name is Methyl 3-phenyl-2-propenoate. Through research, I have a further understanding and discovery of 103-26-4

A revised in situ base mechanism of alkyne alkoxycarbonylation via a Pd catalyst with hemilabile P,N-ligands (PyPPh2, Py = 2-pyridyl) has been fully characterised at the B3PW91-D3/PCM level of density functional theory. Key intermediates on this route are acryloyl and (3)-propen-1-oyl complexes that readily undergo methanolysis. With two hemilabile P,N-ligands and one or both of them protonated, the overall computed barrier is 16.8 kcal mol(-1). This new mechanism is consistent with all of the experimental data relating to substituent effects on relative reaction rates and branched/linear selectivities, including new results on the methoxycarbonylation of phenylacetylene using (4-Me2N-Py)PPh2 and (6-Cl-Py)PPh2 ligands. This ligand is found to decrease catalytic activity over PyPPh2, thus invalidating a formerly characterised in situ base mechanism.

Product Details of 103-26-4. Welcome to talk about 103-26-4, If you have any questions, you can contact Ahmad, S; Lockett, A; Shuttleworth, TA; Miles-Hobbs, AM; Pringle, PG; Buhl, M or send Email.

Reference:
Article; Weng, Shiue-Shien; Ke, Chih-Shueh; Chen, Fong-Kuang; Lyu, You-Fu; Lin, Guan-Ying; Tetrahedron; vol. 67; 9; (2011); p. 1640 – 1648;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Quality Control of Methyl 3-phenyl-2-propenoate. Recently I am researching about CATALYZED BORYLATION; BENZYLIC PHOSPHATES; AROMATIC ALCOHOLS; 2-PYRIDYL ETHERS; ORTHO-ARYLATION; BOND FORMATION; ACTIVATION; ARENES; ACIDS; ARYL, Saw an article supported by the National Natural Science Foundation of China (NNSFC)National Natural Science Foundation of China (NSFC) [21172111, 21672116, 21873051]. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Chen, JJ; Xu, JC; Zhou, Y; Xie, SG; Gao, F; Xu, XF; Xu, XH; Jin, Z. The CAS is 103-26-4. Through research, I have a further understanding and discovery of Methyl 3-phenyl-2-propenoate

Design of C-H activation directing groups that can serve as electrophiles for subsequent cross-coupling significantly improves the step economy of synthetic applications of directed C-H functionalization. Through using a well-defined bifunctional template, palladium-catalyzed ortho-C-H alkenylation and arylation of benzylic alcohols was achieved via an end-on nitrile-embedded 12-membered macrocyclic transition state. Thereafter, the directing template is used as a handle for palladium-catalyzed ipso-C-O cross-coupling to provide functionalized diarylmethanes.

Quality Control of Methyl 3-phenyl-2-propenoate. Welcome to talk about 103-26-4, If you have any questions, you can contact Chen, JJ; Xu, JC; Zhou, Y; Xie, SG; Gao, F; Xu, XF; Xu, XH; Jin, Z or send Email.

Reference:
Article; Weng, Shiue-Shien; Ke, Chih-Shueh; Chen, Fong-Kuang; Lyu, You-Fu; Lin, Guan-Ying; Tetrahedron; vol. 67; 9; (2011); p. 1640 – 1648;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

I found the field of Chemistry very interesting. Saw the article Synergetic Catalysis for One-pot Bis-alkoxycarbonylation of Terminal Alkynes over Pd/Xantphos-Al(OTf)(3) Bi-functional Catalytic System published in 2020.0. Name: Methyl 3-phenyl-2-propenoate, Reprint Addresses Liu, Y (corresponding author), East China Normal Univ, Sch Chem & Mol Engn, Shanghai Key Lab Green Chem & Chem Proc, 3663 North Zhongshan Rd, Shanghai 200062, Peoples R China.; Giang, VT (corresponding author), Univ Paris Sud, Inst Chim Mol & Mat dOrsay, F-91405 Orsay, France.. The CAS is 103-26-4. Through research, I have a further understanding and discovery of Methyl 3-phenyl-2-propenoate

Tandem bis-alkoxycarbonylation of alkynes allows for the preparation of 2-substituted succinates from alkynes and nucleophile alcohol via two successive alkoxycarbonylation with advantages of 100 % atomic economy and simplified one-pot operation. Herein, the one-pot tandem bis-alkoxycarbonylation of alkynes was accomplished over the bi-functional catalytic system containing Xantphos-modified Pd-complex and Lewis super-acid of Al(OTf)(3). It was found that, via the synergetic catalysis, the involved Xantphos-modified Pd-complex was responsible for the activation of CO and the alkynes through coordination to Pd-center while Al(OTf)(3) was in charge of the activation of the alcohol to facilitate the formation of [Pd-H](+) active species. The in situ high-pressure FT-IR analysis, coupled with H-1/C-13 NMR spectral characterizations, confirmed that the introduced Al(OTf)(3) with intensive oxophilicity (via acid-base pair interaction) was able to activate nucleophilic MeOH to be a reliable proton-donor (i. e. hydride-source) to warrant the formation and stability of [Pd-H](+) species upon the oxidation of Pd-0 by H+ (Pd-0+H+->[Pd-II-H](+)). Over the developed bi-functional catalytic system, the yields of the target diesters were obtained in the range of 36 similar to 86 % in this sequence with the wide substrate scope.

Welcome to talk about 103-26-4, If you have any questions, you can contact Guo, WD; Liu, L; Yang, SQ; Chen, XC; Lu, Y; Giang, VT; Liu, Y or send Email.. Name: Methyl 3-phenyl-2-propenoate

Reference:
Article; Weng, Shiue-Shien; Ke, Chih-Shueh; Chen, Fong-Kuang; Lyu, You-Fu; Lin, Guan-Ying; Tetrahedron; vol. 67; 9; (2011); p. 1640 – 1648;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Product Details of 2005-10-9. In 2021.0 CHEM COMMUN published article about REDIRECTING SECONDARY BONDS; DIARYLIODONIUM SALTS; ALPHA-TOSYLOXYLATION; HYPERVALENT; IODINE(III); REACTIVITY; REAGENTS; OXO in [Boelke, Andreas; Sadat, Soleicha; Nachtsheim, Boris J.] Univ Bremen, Inst Organ & Analyt Chem, D-28359 Bremen, Germany; [Lork, Enno] Univ Bremen, Inst Inorgan Chem & Crystallog, D-28359 Bremen, Germany in 2021.0, Cited 47.0. The Name is 6H-Benzo[c]chromen-6-one. Through research, I have a further understanding and discovery of 2005-10-9.

Bis-N-heterocycle-stabilized lambda(3)-iodanes (BNHIs) based on azoles are introduced as novel structural motifs in hypervalent iodine chemistry. A performance test in a variety of benchmark reactions including sulfoxidations and phenol dearomatizations revealed a bis-N-bound pyrazole substituted BNHI as the most reactive derivative. Its solid-state structure was characterized via X-ray analysis implying strong intramolecular interactions between the pyrazole nitrogen atoms and the hypervalent iodine centre.

Welcome to talk about 2005-10-9, If you have any questions, you can contact Boelke, A; Sadat, S; Lork, E; Nachtsheim, BJ or send Email.. Product Details of 2005-10-9

Reference:
Article; Zhang, Jian; Shi, Dongdong; Zhang, Haifeng; Xu, Zheng; Bao, Hanyang; Jin, Hongwei; Liu, Yunkui; Tetrahedron; vol. 73; 2; (2017); p. 154 – 163;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics