Tag: M.W=150-200

Jindapon, Wayu published the artcileContinuous production of fatty acid methyl esters and high-purity glycerol over a dolomite-derived extrudate catalyst in a countercurrent-flow trickle-bed reactor, Name: Methyl decanoate, the main research area is biodiesel fatty acid methyl ester palm oil transesterification catalyst; calcium magnesium oxide catalyst countercurrent flow trickle bed reactor.

In this work, fatty acid Me esters (FAME), as biodiesel components, were continuously produced via the heterogeneously catalyzed transesterification of palm oil with methanol vapor in a countercurrent-flow trickle-bed reactor. Dolomitic rock was used as natural calcium source in the preparation of the calcium oxide-based extrudate catalyst via a phys. mixing method. Effects of operating parameters on the FAME yield and the two-phase flow behavior were investigated. The reaction system was characterized by a high mass diffusion resistance at gas-liquid-solid interfaces due to the low solubility of methanol in triglycerides and the high viscosity of oil. Mixing palm oil with com. grade Me decanoate, a C10 Me ester (C10 CME), at a 1:1 mass ratio during the start-up period promoted FAME production The FAME yield was enhanced by increasing the operating temperature and the methanol flow rate, while operation at a high oil flow rate severely decreased the FAME yield. The concentration of C10 CME, which acted as an emulsifier, in the catalyst bed was crucial to maintain the FAME production stability. In addition to a high FAME yield (ca. 92.3 wt%), the system provided glycerol, obtained without any washing, at a high purity of 93.6 wt%.

Renewable Energy published new progress about Biodiesel fuel. 110-42-9 belongs to class esters-buliding-blocks, name is Methyl decanoate, and the molecular formula is C11H22O2, Name: Methyl decanoate.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Pandiangan, Kamisah D. published the artcileProduction of magnesium oxides from raw salt solution using electrochemical precipitation method as a heterogeneous catalyst for transesterification of coconut oil, Application In Synthesis of 110-42-9, the main research area is coconut oil magnesium oxide electrochem precipitation transesterification.

This study was conducted to explore the production of magnesium oxide from raw salt solution using electrochem. precipitation, followed by calcination. Electrochem. precipitation was conducted by electrolysis of the salt solution using nickel rods as cathodes and graphite as anodes. Two sets of salt solutions were prepared: one set without pretreatment and another with BaCl2 pretreatment. The solutions were used to study the effect of salt concentration, potential, and electrolysis time. The representatives of the MgO produced were tested as catalysts for transesterification of coconut oil. The results indicate that optimum mass of precipitate was produced from 400 mg/L salt solution electrolyzed using 8 V for 60 min. Elemental anal. using X-Ray Fluorescence (XRF) revealed the presence of Mg as the main component of the precipitate, confirming the electrochem. conversion of Mg2+ into solid Mg(OH)2. The MgO with the purity of 74.23% and 88.87% was produced from non-pretreated and pretreated salt solution, resp. The transesterification experiments indicate that the yield of 90% and 98% was achieved using the MgO produced from non-pretreated and pretreated salt solution, resp.

Revista de Chimie (Bucharest, Romania) published new progress about Biodiesel fuel. 110-42-9 belongs to class esters-buliding-blocks, name is Methyl decanoate, and the molecular formula is C11H22O2, Application In Synthesis of 110-42-9.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Pandiangan, Kamisah D. published the artcileProduction of magnesium oxides from raw salt solution using electrochemical precipitation method as a heterogeneous catalyst for transesterification of coconut oil, Safety of Methyl octanoate, the main research area is coconut oil magnesium oxide electrochem precipitation transesterification.

This study was conducted to explore the production of magnesium oxide from raw salt solution using electrochem. precipitation, followed by calcination. Electrochem. precipitation was conducted by electrolysis of the salt solution using nickel rods as cathodes and graphite as anodes. Two sets of salt solutions were prepared: one set without pretreatment and another with BaCl2 pretreatment. The solutions were used to study the effect of salt concentration, potential, and electrolysis time. The representatives of the MgO produced were tested as catalysts for transesterification of coconut oil. The results indicate that optimum mass of precipitate was produced from 400 mg/L salt solution electrolyzed using 8 V for 60 min. Elemental anal. using X-Ray Fluorescence (XRF) revealed the presence of Mg as the main component of the precipitate, confirming the electrochem. conversion of Mg2+ into solid Mg(OH)2. The MgO with the purity of 74.23% and 88.87% was produced from non-pretreated and pretreated salt solution, resp. The transesterification experiments indicate that the yield of 90% and 98% was achieved using the MgO produced from non-pretreated and pretreated salt solution, resp.

Revista de Chimie (Bucharest, Romania) published new progress about Biodiesel fuel. 111-11-5 belongs to class esters-buliding-blocks, name is Methyl octanoate, and the molecular formula is C9H18O2, Safety of Methyl octanoate.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Niju, S. published the artcileFish-Bone-Doped Sea Shell for Biodiesel Production from Waste Cooking Oil, Product Details of C9H18O2, the main research area is Tellina shell waste fish bone cooking oil biodiesel production.

Transesterification of waste cooking oil with methanol using calcined waste fish bone and sea shell catalyst was studied. An inexpensive and environmentally benign catalyst was prepared from waste fish bones (WFB) and Tellina tenuis shells (TTS), and the catalyst was characterized by Fourier transform IR spectroscopy (FTIR), SEM (SEM), Brunauer-Emmett-Teller, X-ray diffraction (XRD) and energy-dispersive X-ray spectroscopy (EDS) techniques. From XRD, it was confirmed that the major phase of WFB was hydroxyapatite and calcium oxide was found to be the dominant fraction of calcined TTS. FTIR and SEM-EDS anal. of WFB confirmed the presence of hydroxyapatite exhibiting hexagonal structure. Different combinations of WFB and TTS have been developed to obtain novel catalyst composition Above 94% conversion was reported with various combinations of WFB and TTS using 3 wt% catalyst, 12:1 molar ratio, 65°C and 1.5 h.

Journal of the Institution of Engineers (India): Series E published new progress about Biodiesel fuel. 111-11-5 belongs to class esters-buliding-blocks, name is Methyl octanoate, and the molecular formula is C9H18O2, Product Details of C9H18O2.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Balakrishnan, A. published the artcileExperimental correlation of laminar flame pollutant emission indices with methyl ester fuel degree of unsaturation and equivalence ratio, SDS of cas: 110-42-9, the main research area is methyl ester fuel unsaturation equivalence laminar fame pollutant emission.

Fuel unsaturation has been widely cited as a reason for the increased nitric oxide emissions from compression ignition engines when fueled with Me esters (biodiesels) and their blends with petroleum counterparts. In an earlier study, a parameter called degree of unsaturation (DOU) was established to serve as a common platform across different fuel families (esters/alkanes/aromatics) to quantify the effects of fuel unsaturation, particularly with petroleum/biodiesel blends. DOU can be evaluated based on the average mol. formula of the fuel alone without involving complex and expensive exptl. procedures such as those involved in the measurement of iodine number and bromine number In this article, the fuel unsaturation effects on the emission characteristics from the laminar flames of blends of various pre-vaporized Me esters, such as Me oleate, neat biodiesels (from Me esters of soy, canola, palm and rapeseed feedstock) and biodiesel blends were investigated at four burner-exit equivalence ratios of 0.9, 1.0, 1.2 and 1.5. The selection of these fuels for this study was an attempt to isolate the fuel unsaturation effect of biodiesels, and their blending effect with petroleum fuels. Exptl. correlations were developed between DOU (over a range of 1.7-2.5) and global NO and CO emission indexes as a function of equivalence ratio. The effects of DOU on EINO were significantly influenced by the equivalence ratio, with the maximum influence at an equivalence ratio of 1.2.

Fuel published new progress about Biodiesel fuel. 110-42-9 belongs to class esters-buliding-blocks, name is Methyl decanoate, and the molecular formula is C11H22O2, SDS of cas: 110-42-9.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Balakrishnan, A. published the artcileExperimental correlation of laminar flame pollutant emission indices with methyl ester fuel degree of unsaturation and equivalence ratio, Category: esters-buliding-blocks, the main research area is methyl ester fuel unsaturation equivalence laminar fame pollutant emission.

Fuel unsaturation has been widely cited as a reason for the increased nitric oxide emissions from compression ignition engines when fueled with Me esters (biodiesels) and their blends with petroleum counterparts. In an earlier study, a parameter called degree of unsaturation (DOU) was established to serve as a common platform across different fuel families (esters/alkanes/aromatics) to quantify the effects of fuel unsaturation, particularly with petroleum/biodiesel blends. DOU can be evaluated based on the average mol. formula of the fuel alone without involving complex and expensive exptl. procedures such as those involved in the measurement of iodine number and bromine number In this article, the fuel unsaturation effects on the emission characteristics from the laminar flames of blends of various pre-vaporized Me esters, such as Me oleate, neat biodiesels (from Me esters of soy, canola, palm and rapeseed feedstock) and biodiesel blends were investigated at four burner-exit equivalence ratios of 0.9, 1.0, 1.2 and 1.5. The selection of these fuels for this study was an attempt to isolate the fuel unsaturation effect of biodiesels, and their blending effect with petroleum fuels. Exptl. correlations were developed between DOU (over a range of 1.7-2.5) and global NO and CO emission indexes as a function of equivalence ratio. The effects of DOU on EINO were significantly influenced by the equivalence ratio, with the maximum influence at an equivalence ratio of 1.2.

Fuel published new progress about Biodiesel fuel. 111-11-5 belongs to class esters-buliding-blocks, name is Methyl octanoate, and the molecular formula is C9H18O2, Category: esters-buliding-blocks.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Zharova, P. A. published the artcileOriginal Pt-Sn/Al2O3 catalyst for selective hydrodeoxygenation of vegetable oils, Name: Benzyl acetate, the main research area is platinum aluminum oxide catalyst hydrodeoxygenation vegetable oil.

The preparation of biodiesel from fatty materials HDO provides a very constructive idea to solve the global clean energy problem. The application of catalytic technol. to convert oils into green liquid hydrocarbon fuel has great potential for industrial application. The main problem with the development of green diesel technol. is the limited number of available non-food sources of fatty acid triglycerides. Also the researchers have made remarkable achievements in the field of catalyst, the stability of the catalyst is insufficient and the selectivity of large mols. of direct alkanes is low. These defects hinder the large-scale resource development of biodiesel. In current paper the potential of hydrodeoxygenation (HDO) of fatty materials and model esters was explored by enhancing the synergy of platinum and tin by using heterometallic (PPh4)3 [Pt (SnCl3)5 complex. Heterometallic (PPh4)3 [Pt (SnCl3)5] complex provides in its structure platinum and tin atoms linked by a metal-metal bond that causes the originality of catalytic performance. The performance of bimetallic Pt-Sn/Al2O3 catalyst, which is characterized by the Sn/Pt molar ratio of 5/1, has been studied at hydrogen pressure 50 atm and temperature 400-480°C. HDO reaction of a number of fatty materials has been shown to proceed with the highest ever yield of direct hydrocarbons derived from alkoxy and acyl groups of the initial ester. Also it was investigated a performance in HDO reaction of mixture containing rapeseed oil oleic acid and water that simulate cooked oil that may be a prospective soure for green hydrocarbons in megalopolises. A structural studies of the catalyst showed that its high selectivity in HDO reaction of fatty materials provided by two important factors: impregnated particles size and formation of intermettallic species of PtSn3±σ. Finally, catalysts sustained activity and stability were tested during five turns of 24 h each.

Energy (Oxford, United Kingdom) published new progress about Binding energy. 140-11-4 belongs to class esters-buliding-blocks, name is Benzyl acetate, and the molecular formula is C9H10O2, Name: Benzyl acetate.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Yao, Yaqi published the artcileRoles of Cu+ and Cu0 sites in liquid-phase hydrogenation of esters on core-shell CuZnx@C catalysts, Category: esters-buliding-blocks, the main research area is liquid hydrogenation ester core shell CuZnx catalyst.

Liquid-phase hydrogenolytic reduction of esters on Cu-based catalysts is a promising approach for synthesis of alcs. Here, core-shell CuZnx@C materials synthesized via pyrolysis of a Zn(NO3)2-loaded metal-organic framework (MOF) were proposed, in which well-defined spacing between Cu species in the parent MOF and the homogeneous loading of a Zn salt leads to an ideal distribution and strong interaction of Cu and Zn after pyrolysis of the precursor. The as-synthesized CuZnx@C showed a much higher catalytic activity than Cu@C. This higher activity is tentatively attributed to the simultaneous presence of Cu0 and Cu+ sites at ZnO crystal domains. The resulting Cu-O-Zn sites have a high tendency to adsorb the ester in the form of a surface bound species that greatly improves the hydrogenolysis, which is the rate controlling step in the reductive pathway. A theor. study confirms the ability of this site to bind and catalytically convert fatty acid esters.

Applied Catalysis, B: Environmental published new progress about Binding energy. 111-11-5 belongs to class esters-buliding-blocks, name is Methyl octanoate, and the molecular formula is C9H18O2, Category: esters-buliding-blocks.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

He, Zhiwei published the artcileEncapsulation of heteropolyacids within hollow microporous polymer nanospheres for sustainable esterification reaction, Product Details of C9H10O2, the main research area is heteropolyacid microporous polymer nanosphere catalyst esterification reaction.

Herein, the Keggin structural phosphotungstic acid (HPW) has been successfully encapsulated within hollow microporous polymer nanospheres (H-MPNs) by a “”ship-in-bottle”” approach. The H-MPNs are formed by self-assembly induced by hyper-crosslinking of polylactide-b-polystyrene (PLA-b-PS). The obtained catalysts (HPW@H-MPNs) exhibit more sustainable availability than the previously reported HPW-supported catalysts in esterification reaction. This excellent sustainability can be attributed to the stable microporous channels in H-MPNs which are smaller than the mol. size of HPW, thereby effectively preventing the HPW from leaking out. Moreover, such catalysts also perform well in terms of catalytic activity and universality because of the combination of a hollow structure in the interior and permeable pore channels in the shells. This type of polymer carrier and general encapsulation method may provide a new strategy for developing more sustainable catalysts for various chem. reactions.

Reactive & Functional Polymers published new progress about Binding energy. 140-11-4 belongs to class esters-buliding-blocks, name is Benzyl acetate, and the molecular formula is C9H10O2, Product Details of C9H10O2.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Fiorio, Jhonatan Luiz published the artcileReusable Heterogeneous Tungstophosphoric Acid-Derived Catalyst for Green Esterification of Carboxylic Acids, HPLC of Formula: 111-11-5, the main research area is tungstophosphoric catalyst green esterification carboxylic acid ester.

Solid acid catalysts are environmentally friendly alternatives to the use of mineral acids in a range of applications, including the esterification of carboxylic acids. Here, a phosphorus- and nitrogen-doped, carbon-modified, fully heterogeneous solid acid catalyst was prepared by pyrolysis of a mixture of melamine and tungstophosphoric acid at 250, 500, and 750 °C under a nitrogen atm. provided. The structure of the different catalysts was evaluated by surface area measurements, XRD, XPS, Raman spectroscopy, elemental anal., and electron microscopies. Pyrolysis at 500 °C created complex solid materials with larger surface area and significantly higher acidity, which can be attributed to WO3 formation on a heteroat. (N,P)-carbon structure. The 500 °C-treated heterogeneous catalysts showed remarkably better activity for esterification of palmitic acid and were thus applied in the esterification of a broad range of carboxylic acids with good overall yields. Furthermore, the solid acid catalyst can be easily recovered and recycled up to eight times without significant loss of activity with no leaching of species to the reaction mixture

ACS Sustainable Chemistry & Engineering published new progress about Binding energy. 111-11-5 belongs to class esters-buliding-blocks, name is Methyl octanoate, and the molecular formula is C9H18O2, HPLC of Formula: 111-11-5.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics