Tag: M.W=100-150

Piras, Carmen C. published the artcileFacile Method to Obtain Low DS β-ketoesters and Esters of Microfibrillated Cellulose, Category: esters-buliding-blocks, the main research area is microfibrillated cellulose acetoacetate beta ketoester.

Herein we report a facile approach to prepare low DS microfibrillated cellulose acetoacetates and esters. All the reactions were performed directly in cellulose slurries without the need of solvent evaporation, which can cause hornification, and without damaging the fibers. The products obtained display the inserted functionalities while retaining the main features and morphol. of the unmodified cellulose fibers. In comparison to previously reported synthetic routes, this method is cost-effective, more environmentally friendly through omission of extra solvents and the possibility of reusing the dispersing agents, which can be recovered by distillation

Fibers and Polymers published new progress about Transesterification. 5405-41-4 belongs to class esters-buliding-blocks, name is Ethyl 3-hydroxybutanoate, and the molecular formula is C6H12O3, Category: esters-buliding-blocks.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Tabanelli, Tommaso published the artcileTransfer Hydrogenation of Methyl and Ethyl Levulinate Promoted by a ZrO2 Catalyst: Comparison of Batch vs. Continuous Gas-Flow Conditions, SDS of cas: 539-88-8, the main research area is transfer hydrogenation methyl ethyl levulinate Zirconia catalyst.

The catalytic conversion of Me and Et levulinates into γ-valerolactone (GVL) by using methanol, ethanol, and 2-propanol as the H-donor/solvent, promoted by the ZrO2 catalyst, is described as carried out under both batch and gas-flow conditions. Under batch conditions, 2-propanol was found to be the best H-donor mol., with Et levulinate giving the highest yield in GVL. The reactions occurring under continuous gas-flow conditions were found to be much more efficient, also showing excellent yields in GVL when EtOH was used as the reducing agent. These experiments clearly show that the ability to release hydrogen from the alc. H-donor/solvent is the main factor driving CTH processes, while the tendency to attack the esteric group is the key step in the formation of transesterification products.

ACS Sustainable Chemistry & Engineering published new progress about Transesterification. 539-88-8 belongs to class esters-buliding-blocks, name is Ethyl 4-oxopentanoate, and the molecular formula is C7H12O3, SDS of cas: 539-88-8.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Hernandez-Ruiz, Raquel published the artcileMo-Catalyzed One-Pot Synthesis of N-Polyheterocycles from Nitroarenes and Glycols with Recycling of the Waste Reduction Byproduct. Substituent-Tuned Photophysical Properties, Related Products of esters-buliding-blocks, the main research area is polyheterocycle preparation green chem; nitroarene glycol tandem reduction imine formation intramol cyclization oxidation; dioxomolybdenum complex catalyst waste reuse; N-heterocycles; dioxomolybdenum; nitroaromatics; photophysical properties; reuse of waste.

A catalytic domino reduction-imine formation-intramol. cyclization-oxidation for the general synthesis of a wide variety of biol. relevant N-polyheterocycles, such as quinoxaline- and quinoline-fused derivatives, and phenanthridines, is reported. A simple, easily available, and environmentally friendly dioxomolybdenum(VI) complex has proven to be a highly efficient and versatile catalyst for transforming a broad range of starting nitroarenes involving several redox processes. Not only is this a sustainable, step-economical as well as air- and moisture-tolerant method, but also it is worth highlighting that the waste byproduct generated in the first step of the sequence is recycled and incorporated in the final target mol., improving the overall synthetic efficiency. Moreover, selected indoloquinoxalines have been photophys. characterized in cyclohexane and toluene with exceptional fluorescence quantum yields above 0.7 for the alkyl derivatives

Chemistry – A European Journal published new progress about Absorption spectra. 623-50-7 belongs to class esters-buliding-blocks, name is Ethyl 2-hydroxyacetate, and the molecular formula is C4H8O3, Related Products of esters-buliding-blocks.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Santamaria, Pilar published the artcileNitrogen sources added to must: effect on the fermentations and on the tempranillo red wine quality, Safety of Ethyl 3-hydroxybutanoate, the main research area is nitrogen supplementation alc malolactic fermentation Tempranillo red wine quality.

Nitrogen supplementation in musts or during the alc. fermentation is a common practice to promote fermentations In this study, the impact of the supplementation of two different sources of nitrogen during Tempranillo red wine elaboration was studied. Mineral and organic nitrogen was added after the exponential yeast growth phase and during winemaking, examining its impact on the alc. and malolactic fermentation development, on the aromatic wine composition and on the nitrogenous wine composition The nitrogen supplementation did not provide neither significant advantages in kinetics and fermentations time, nor differences in the chem. wine composition The aromatic composition of the wines improved with the addition of inorganic nitrogen, although its organoleptic evaluation was not favored. Moreover, the concentration of amino acids in wines increased slightly after the malolactic fermentation and significantly during the stabilization time, especially with organic nitrogen addition However, the synthesis of biogenic amines did not increase in wines neither after the malolactic fermentation, nor after the storage period.

Fermentation published new progress about Acidity (volatile). 5405-41-4 belongs to class esters-buliding-blocks, name is Ethyl 3-hydroxybutanoate, and the molecular formula is C6H12O3, Safety of Ethyl 3-hydroxybutanoate.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Zhao, Xuelai published the artcileSynthesis of long chain alkanes via aldol condensation over modified chitosan catalyst and subsequent hydrodeoxygenation, COA of Formula: C7H12O3, the main research area is furfural levulinic acid aldol condensation hydrodeoxygenation.

In this paper, jet fuel range alkanes were produced by aldol condensation of furfural and levulinic acid over modified chitosan catalyst and subsequent hydrodeoxygenation. NaOH modified chitosan was developed and used as a solid catalyst in the aldol condensation of furfural and levulinic acid to produce long carbon chain compounds At room temperature, the total yield of condensation products reached 94.4% over NaOH/CT-4 catalyst. The amine of chitosan plays an important role in the aldol condensation, which reacted with the aldehyde group of the furfural, producing an intermediate Schiff base and promoting the formation of condensation products. This new route avoided the occurrence of side reactions caused by NaOH. Therefore, the yield of the products was greatly increased. Moreover, kinetic anal. of the condensation reaction and the test of catalyst repeatability were also conducted with NaOH/CT-4. The condensation products were further converted to long-chain branched alkanes by hydrodeoxygenation over the 5 wt% Pd/NbOPO4 catalyst. As a potential application, these alkanes could be mixed with and used as the components of jet fuels.

Chemical Engineering Journal (Amsterdam, Netherlands) published new progress about Aldol condensation. 539-88-8 belongs to class esters-buliding-blocks, name is Ethyl 4-oxopentanoate, and the molecular formula is C7H12O3, COA of Formula: C7H12O3.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Cho, Hong Je published the artcileSelectivity Control in Tandem Catalytic Furfural Upgrading on Zeolite-Encapsulated Pt Nanoparticles through Site and Solvent Engineering, Name: Ethyl 4-oxopentanoate, the main research area is selectivity tandem catalytic furfural upgrading zeolite encapsulated platinum nanoparticle.

Selectivity control is a pressing challenge in developing selective tandem catalytic processes. In this work, we demonstrate that tailoring types of acid sites of zeolite-encapsulated Pt nanoparticles (NPs) and solvents provide a compelling strategy to manipulate product distribution in tandem catalysis. Model tandem furfural conversion with acetone and ethanol (EtOH) is investigated in cyclohexane and EtOH solvents. Pt NPs encapsulated in ZSM-5 with Bronsted acid sites (BAS) only located in intracrystalline mesopores selectively mediate the tandem Aldol condensation and subsequent hydrogenation of furfural and acetone by limiting the access of furfural to Pt sites and promoting the Aldol condensation. A combined yield of 69% toward hydrogenated Aldol adducts is achieved. In contrast, furfural hydrogenation to valeric acid (VA) and Et valerate (EV) dominates with a combined yield of 80% on Pt NPs encapsulated in ZSM-5 with Lewis acid sites (LAS) and BAS in both zeolitic micropores and intracrystalline mesopores. Concentration of EtOH in the reaction system is identified as another key parameter in selectivity control: (1) Low EtOH concentrations (EtOH to furfural ratio of <5) suppress the catalytic transfer hydrogenation pathway and favor the formation of 2-methylfuran (MF) from furfural as most hydrogenation and hydrogenolysis steps occur on Pt NPs; (2) Modest EtOH concentrations (EtOH to furfural ratio of 5-10) favor VA/EV by enabling the catalytic transfer hydrogenation pathway in zeolitic micropores and exposing intermediates to BAS prior to Pt NPs; and (3) High EtOH concentrations (EtOH to furfural ratio of >10) suppress the production of VA/EV by excessive water formation via acid catalyzed etherification of EtOH. Therefore, tailoring the nature of active sites and solvent composition are both effective strategies in manipulating the product distribution in tandem catalysis.

ACS Catalysis published new progress about Aldol condensation. 539-88-8 belongs to class esters-buliding-blocks, name is Ethyl 4-oxopentanoate, and the molecular formula is C7H12O3, Name: Ethyl 4-oxopentanoate.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Chen, Xiao published the artcileFree and glycosidic volatiles in tamarillo (Solanum betaceum Cav. syn. Cyphomandra betacea Sendt.) juices prepared from three cultivars grown in New Zealand, HPLC of Formula: 5405-41-4, the main research area is glycosidic volatile tamarillo juice cultivar; PCA; PLS-DA; glycosides; ripening; tamarillo; volatile.

This study investigated the free and glycosidic-bound volatiles in the juice samples of three tamarillo cultivars (i.e. Amber, Mulligan, and Laird’s Large) that are widely grown in New Zealand. Juice samples were prepared from fruits at different ripening stages (green, middle, and ripe). Headspace solid-phase microextraction combined with gas chromatog.-mass spectrometry was applied to analyze the free volatiles in the samples. A total of 20 free volatiles were detected. Among the samples, the ripe Mulligan juice gave the highest contents of free terpenoids (424μg/L) and esters (691μg/L). The glycosidic-bound volatiles were prepared by solid-phase extraction The matrix effect was evaluated based on the recovery rate of analytes containing multiple aglycon classes. From the results, Ph β-D-glucopyranoside was selected to compensate the matrix effect caused by insufficient acquisition of glycosidic volatiles during analyte preparation In all the ripe-fruit juice samples, the aglycons 4-hydroxy-2,5-dimethyl-3(2H)-furanone and trans-2, cis-6-nonadienal were found to give high odor activity values. According to multivariate statistical anal., 11 free volatiles and 22 glycosidic volatiles could be potentially applied as volatile makers to distinguish the juice samples. This study has provided a comprehensive understanding of the flavor chem. of tamarillo juices, with a focus on the potential role of glycosidic aglycons as aroma contributors to tamarillo products.

Journal of Agricultural and Food Chemistry published new progress about Cyphomandra betacea. 5405-41-4 belongs to class esters-buliding-blocks, name is Ethyl 3-hydroxybutanoate, and the molecular formula is C6H12O3, HPLC of Formula: 5405-41-4.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Montevecchi, G. published the artcileEffect of Kaolin/Defoliation combined with dry ice on Lambrusco red wine production to constrain the effects of climate change, Recommanded Product: Ethyl 3-hydroxybutanoate, the main research area is Lambrusco red wine kaolin defoliation dry ice climate change.

Since viticulture is affected considerably by climate change, it is imperative to encourage research on new strategies in order to constrain these critical effects on the composition of berries and the quality of wines. A multi-strategy approach composed of (i) kaolin application on foliage, (ii) late tree defoliation and (iii) cryomaceration of grapes with dry ice was evaluated in the production of Lambrusco Salamino wines. Phys., chem. and sensory analyses were carried out on the sample set, including the control wines. In general, cryomaceration with dry ice proved to be a winning choice to lower alc. strength (roughly 5%). In addition, the wines showed an increase in anthocyanin content by approx. 17%, while the content of catechins, flavanols and hydroxycinnamic acids decreased. Consistent with the increase in the anthocyanin content, an increase in color indexes and sensory color intensity scores was observed As for the aromatic profile, 2-phenylethanol showed an increase of approx. 18% in the treated wines while, in parallel, a lower content of C6 alcs. and volatile fatty acids was observed The multiple adaptation strategies put in place in the present study show an alternative way to mitigate the severe effects of climate change on wine production, and to face changing consumer demands.

South African Journal of Enology and Viticulture published new progress about Acetates Role: FFD (Food or Feed Use), BIOL (Biological Study), USES (Uses). 5405-41-4 belongs to class esters-buliding-blocks, name is Ethyl 3-hydroxybutanoate, and the molecular formula is C6H12O3, Recommanded Product: Ethyl 3-hydroxybutanoate.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Ntsoane, Makgafele Lucia published the artcileImpact of low oxygen storage on quality attributes including pigments and volatile compounds in ‘Shelly’ mango, Computed Properties of 5405-41-4, the main research area is Shelly mango low oxygen storage quality.

Optimal oxygen conditions in controlled atm. storage play an important role in maintaining quality and extending shelf life of mangoes, especially for long distance markets. The aim of the study was to investigate the low O2 tolerance limit of ‘Shelly’ mango fruit based on quality attributes including pigments and accumulation of O2 restricted volatile organic compounds (VOCs). Spectroscopy in the visible wavelength range was applied in diffuse reflectance mode as a non-destructive method for monitoring the pigment contents. Furthermore, the relationship between non-destructively measured pigment indexes and pigment content was investigated. The spectral reflectance measurements predicted the pigment content in mango fruit (R2 ≥ 0.70). However, exptl. results showed that low O2 had no impact on pigment contents. Soluble solids and individual sugars (sucrose, fructose, and glucose) increased in all storage conditions. Significant differences were found in VOCs, 1% O2 resulted in significant accumulation of anaerobic metabolites: ethanol, Et acetate, 3-hydroxy-2-butanone, Et butanoate, 1-butanol, 2, 3-butanediol, Et propanoate, 2, 3-butanediol, undecane. Sensory anal. indicated that the panelists rejected fruit stored at 1% O2 due to unfavorable odor and taste. The results showed that 5% is the low O2 limit for ‘Shelly’ mango, below which anaerobic metabolites accumulated compromising the acceptability of the fruit due to ‘off-flavor’. However, storage conditions of 10% O2 can already result in reduced fruit mass loss and respiration rate; maintained the fruit flesh firmness, soluble solids content, and individual sugars in ‘Shelly’ mango after 21 d of storage.

Scientia Horticulturae (Amsterdam, Netherlands) published new progress about Alcohols Role: FFD (Food or Feed Use), BIOL (Biological Study), USES (Uses). 5405-41-4 belongs to class esters-buliding-blocks, name is Ethyl 3-hydroxybutanoate, and the molecular formula is C6H12O3, Computed Properties of 5405-41-4.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Su, Yingyu published the artcileEffects of Broussonetia papyrifera-fermented feed on the growth performfermentedance and muscle quality of Hu sheep, Product Details of C6H12O3, the main research area is Broussonetia papyrifera fermentation feed muscle quality Hu sheep.

This study aims to determine the effect of adding different proportions of Broussonetia papyrifera (BP)-fermented feed on Hu sheep. A total of 40 male Hu sheep (weighting 20.6 ± 2.20 kg) were collected and then divided into group I, II, III, and IV, with 0%, 5%, 10%, and 15% of BP-fermented feed to based diet, resp. After the trial period of 10 and 50 d, the sheep were slaughtered by conventional methods for the chem. analyses. It showed that adding 10% fermented feed could significantly increase the growth performance of the Hu sheep. Adding the fermented feed can improve the protein level, main flavor amino acid content, and fatty acid in the muscle. Based on the headspace solid-phase microextraction and gas chromatog. – mass spectrometry methods, a total of 125, 120, 119, and 117 kinds of volatile compounds were identified in group I, II, III, and IV, among which the relative content of the acid compound, ester compound, ketone compound, and aldehydes in group II, III, and IV were higher than that in control group, resp. Addition of BP-fermented feed could significantly improve growth performance and meat quality of Hu sheep.

Canadian Journal of Animal Science published new progress about Aldehydes Role: FFD (Food or Feed Use), BIOL (Biological Study), USES (Uses). 5405-41-4 belongs to class esters-buliding-blocks, name is Ethyl 3-hydroxybutanoate, and the molecular formula is C6H12O3, Product Details of C6H12O3.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics