Tag: 1100-1200

Migration of Irganox 1010, Irganox 1076, and Titanium dioxide into Doogh and corresponding food simulant from laminated packaging was written by Forooghi, Elaheh;Ahmadi, Shervin;Farhoodi, Mehdi;Mortazavian, Amir M.. And the article was included in Journal of Environmental Health Science and Engineering in 2022.Synthetic Route of C73H108O12 This article mentions the following:

Doogh is a famous Iranian drink based on fermented milk. Laminated film is one of the most common packaging for this beverage in Iran. So, chem. substances of the packaging may migrate to the Doogh and endanger human health. In this research, High-Performance Liquid Chromatog. (HPLC) was used to determine the migration of Irganox 1010 and Irganox 1076 from the contact layer and inductively coupled plasma for Titanium dioxide (TiO₂) from the second layer of three-layer laminate films into Doogh and acetic acid 3% (w/v). The influence of different storage temperatures and times was investigated by evaluating the samples stored in various conditions. The morphol., thermal and mech. properties of the film, before and after contact with food simulant were further studied. The highest amount of Irganox 1010 concentration of the tested samples were 0.8 ± 0.04 mg/l in acetic acid 3% (w/v), and 0.62 ± 0.04 mg/l in Doogh. The highest amount of TiO₂ concentration were 0.25 ± 0.04 mg/l in acetic acid 3% (w/v), and 0.12 ± 0.02 mg/l in Doogh. The migration of Irganox 1076 was determined, but it was not detected. The results indicated that the food simulant had no significant effect on the microstructure and thermal properties of the polymer, but it reduced the mech. properties. The results indicate the possible migrating of Irganox 1010 and TiO₂ through laminate packaging into Doogh in some storage conditions. Since the migration value was low, the mentioned film was proven safe for Doogh packaging, imposing no hazards on human health. In the experiment, the researchers used many compounds, for example, 2,2-Bis(((3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoyl)oxy)methyl)propane-1,3-diyl bis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoate) (cas: 6683-19-8Synthetic Route of C73H108O12).

2,2-Bis(((3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoyl)oxy)methyl)propane-1,3-diyl bis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoate) (cas: 6683-19-8) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Polyesters are important plastics, with monomers linked by ester moieties. Esters are more polar than ethers but less polar than alcohols. They participate in hydrogen bonds as hydrogen-bond acceptors, but cannot act as hydrogen-bond donors, unlike their parent alcohols. This ability to participate in hydrogen bonding confers some water-solubility.Synthetic Route of C73H108O12

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Crystallinity enhancement of extruded polypropylene containing poly(vinyl alcohol) fibers prepared in situ was written by Nishikawa, Riho;Eno, Ayaka;Janchai, Khunanya;Han, Ruiqi;Kida, Takumitsu;Mori, Toyoichiro;Aridome, Norifumi;Miyamoto, Akira;Yamaguchi, Masayuki. And the article was included in Polymer in 2022.Application In Synthesis of 2,2-Bis(((3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoyl)oxy)methyl)propane-1,3-diyl bis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoate) This article mentions the following:

The present paper describes a novel method for reinforcing isotactic polypropylene (PP) by adding poly(vinyl alc.) (PVA) fibers prepared by melt-stretching. Low-viscosity PVA droplets were deformed into fibers in the molten PP by melt-stretching them beyond the m.p. of PVA. When the obtained composite was extruded below the m.p. of PVA, the fibers became oriented toward the flow direction. The PVA demonstrated marked nucleating activity with regard to PP crystallization, which was further promoted by enlargement of the surface area by fibrillization. As a result, there was virtually no orientation relaxation of the PP chains with an increase in crystallinity, which explains the improvement in rigidity of the reinforced composite. In the experiment, the researchers used many compounds, for example, 2,2-Bis(((3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoyl)oxy)methyl)propane-1,3-diyl bis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoate) (cas: 6683-19-8Application In Synthesis of 2,2-Bis(((3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoyl)oxy)methyl)propane-1,3-diyl bis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoate)).

2,2-Bis(((3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoyl)oxy)methyl)propane-1,3-diyl bis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoate) (cas: 6683-19-8) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Polyesters are important plastics, with monomers linked by ester moieties. Esterification is the general name for a chemical reaction in which two reactants (typically an alcohol and an acid) form an ester as the reaction product. Esters are common in organic chemistry and biological materials.Application In Synthesis of 2,2-Bis(((3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoyl)oxy)methyl)propane-1,3-diyl bis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoate)

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Non-Arrhenius behavior: Influence of antioxidants on lifetime predictions for materials used in the cable and wire industries was written by Blivet, Camille;Larche, Jean-Francois;Israeli, Yael;Bussiere, Pierre-Olivier. And the article was included in Polymer Degradation and Stability in 2022.Product Details of 6683-19-8 This article mentions the following:

Thermo-oxidation (70-160°) of peroxide crosslinked polyethylene (XLPE) formulations stabilized with different antioxidants were studied. In order to sep. study the influence of three commonly used antioxidants, three formulations were prepared with only one antioxidant each (0.3% weight/weight): a sterically hindered phenolic antioxidant (Irganox 1010), an organosulfur antioxidant (Hostanox SE4) and an oligomeric, sterically hindered amine light stabilizer (HALS 94). The materials were characterized by IR spectroscopy measurements and tensile testing. Results proved that the addition of antioxidants causes in each case an Arrhenius break, occurring at a different temperature depending on the nature of the added antioxidant. Interestingly, the study of the thermo-oxidation (50-105°) of a certified antioxidant-free polyethylene (non-cross-linked) revealed no Arrhenius deviation. In a previous paper, the authors reported an Arrhenius deviation at low temperature (50°) for two crosslinked PE and EPR, containing residual process antioxidants. These results strengthen our hypothesis that several Arrhenius deviations could be explained by the presence of antioxidants (residual process antioxidants or formulation antioxidants), which “activity” is extremely dependent on the temperature In the experiment, the researchers used many compounds, for example, 2,2-Bis(((3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoyl)oxy)methyl)propane-1,3-diyl bis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoate) (cas: 6683-19-8Product Details of 6683-19-8).

2,2-Bis(((3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoyl)oxy)methyl)propane-1,3-diyl bis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoate) (cas: 6683-19-8) belongs to esters. Esters are also usually derived from carboxylic acids. It may also be obtained by reaction of acid anhydride or acid halides with alcohols or by the reaction of salts of carboxylic acids with alkyl halides. Because of their lack of hydrogen-bond-donating ability, esters do not self-associate. Consequently, esters are more volatile than carboxylic acids of similar molecular weight.Product Details of 6683-19-8

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Degradation and Stabilization of Poly(Butylene Adipate-co-Terephthalate)/Polyhydroxyalkanoate Biodegradable Mulch Films Under Different Aging Tests was written by Wang, James H.;Tian, Yuchuan;Zhou, Bing. And the article was included in Journal of Polymers and the Environment in 2022.Recommanded Product: 6683-19-8 This article mentions the following:

The degradation and stability of biodegradable films determine the service length of mulch films in actual use. Most biodegradable polymers degrade too fast to meet the required durability of mulch films. The objective of this work is to investigate the degradation behaviors of poly(butylene adipate-co-terephthalate) (PBAT)/polyhydroxyalkanoate (PHA) blend mulch films. Several different types of stabilizers were incorporated in the biodegradable blends to provide protection for the PHA/PBAT films during thermal processing and aging on agricultural fields. The degradation process of the films was systematically studied under an Accelerated aging test (AAT) and a Soil aging test (SAT). Adding a UV stabilizer, or antioxidant to the mulch films led to significant improvement in the retention of mech. properties of the films under both AAT and SAT. Morphol. evolution of the films with or without a UV stabilizer as a function of aging times was studied by SEM. The results of thermal properties and crystallinity revealed damage of crystalline structure of the films during AAT. Spectrocopic results indicated that the films underwent both hydrolysis and photodegradative chain scissions (Norrish Type I/II reactions and photo-oxidation). Two degradation mechanisms of the PBAT/PHA biodegradable mulch films were proposed. In the experiment, the researchers used many compounds, for example, 2,2-Bis(((3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoyl)oxy)methyl)propane-1,3-diyl bis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoate) (cas: 6683-19-8Recommanded Product: 6683-19-8).

2,2-Bis(((3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoyl)oxy)methyl)propane-1,3-diyl bis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoate) (cas: 6683-19-8) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Esters are more polar than ethers but less polar than alcohols. They participate in hydrogen bonds as hydrogen-bond acceptors, but cannot act as hydrogen-bond donors, unlike their parent alcohols. This ability to participate in hydrogen bonding confers some water-solubility.Recommanded Product: 6683-19-8

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Organogelators with dual β- and α-nucleating ability in isotactic polypropylene was written by Horvath, Flora;Bodrogi, Dominika;Hilt, Bendeguz;Pregi, Emese;Menyhard, Alfred. And the article was included in Journal of Thermal Analysis and Calorimetry in 2022.Recommanded Product: 6683-19-8 This article mentions the following:

Nucleation efficiency and the special supermol. structure formed in the presence of novel nucleating agents, N,N’-dicyclohexylsuberoylamide and N,N’-dicyclohexylsebacoylamide are presented in this work. The nucleation effect is studied in isotactic polypropylene (iPP). The melting and crystallization processes as well as the polymorphic composition are studied using calorimetric and thermo-optical techniques, while the solubility of the nucleating agents is studied by rheol. The properties of the iPP products nucleated by the novel compounds are characterized by conventional tensile and impact tests and the optical properties are measured by standardized haze measurements. The results indicated clearly that the studied nucleating agents are partially soluble in the iPP melt and possess dual nucleating ability. The formation of β-phase is evidenced by the calorimetric and thermo-optical measurements. The morphol. of the nucleated samples shows similarity to iPP nucleated by well-known soluble “organogelators”; however, the nucleating agents introduced in this work are the first “organogelators” with β-nucleating efficiency. In the experiment, the researchers used many compounds, for example, 2,2-Bis(((3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoyl)oxy)methyl)propane-1,3-diyl bis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoate) (cas: 6683-19-8Recommanded Product: 6683-19-8).

2,2-Bis(((3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoyl)oxy)methyl)propane-1,3-diyl bis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoate) (cas: 6683-19-8) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Esterification is the general name for a chemical reaction in which two reactants (typically an alcohol and an acid) form an ester as the reaction product. Esters are common in organic chemistry and biological materials.Recommanded Product: 6683-19-8

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Mechanical and Processing Enhancement of a Recycled HDPE/PPR-Based Double-Wall Corrugated Pipe via a POE-g-MAH/CaCO₃/HDPE Polymer Composite was written by Wang, Yutong;Lu, Lichang;Hao, Yu;Wu, Yujie;Li, Yuanzhe. And the article was included in ACS Omega in 2021.Electric Literature of C73H108O12 This article mentions the following:

With the people’s awareness of the “3Rs” in recent years, using recycled high-d. polyethylene (HDPE) and random copolymer polypropylene (PPR) as the base materials for piping fabrication has become a mainstream in scholastic path and industrial engineering. In this study, the modified maleic anhydride-grafted polyethylene (POE-g-MAH) compatibilizer was fabricated to increase the interfacial adhesion and dispersion. With the surface modification of calcium carbonate, a POE-g-MAH/CaCO₃/HDPE polymer composite has been prepared Such modified polymer composites can further reinforce the processing performance and mech. properties of recycled HDPE and PPR materials. The results indicated that with the introduction of the polymer composite, significant enhancement of the recycled materials in the aspects of processability, tensile strength, flexural performance, and impact force could be obtained, and the POE-g-MAH/CaCO₃/HDPE polymer composite would contribute to the impressive balance between high rigidity and toughness. In addition, the feasibility and mech. properties of the recycled HDPE-PPR-POE-g-MAH/CaCO₃/HDPE blended system were also studied: with the help of a composite microcapsule, the gap of mech. capacity between recycled and non-recycled materials was further reduced, and such a blended system was capable of being commercialized in the piping industry. In the experiment, the researchers used many compounds, for example, 2,2-Bis(((3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoyl)oxy)methyl)propane-1,3-diyl bis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoate) (cas: 6683-19-8Electric Literature of C73H108O12).

2,2-Bis(((3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoyl)oxy)methyl)propane-1,3-diyl bis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoate) (cas: 6683-19-8) belongs to esters. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Many esters have the potential for conformational isomerism, but they tend to adopt an s-cis (or Z) conformation rather than the s-trans (or E) alternative, due to a combination of hyperconjugation and dipole minimization effects. The preference for the Z conformation is influenced by the nature of the substituents and solvent, if present. Lactones with small rings are restricted to the s-trans (i.e. E) conformation due to their cyclic structure.Electric Literature of C73H108O12

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Organic Chemical Contaminants in Water System Infrastructure Following Wildfire was written by Draper, William M.;Li, Na;Solomon, Gina M.;Heaney, Yvonne C.;Crenshaw, Reese B.;Hinrichs, Richard L.;Chandrasena, R. Esala P.. And the article was included in ACS ES&T Water in 2022.Computed Properties of C73H108O12 This article mentions the following:

Wildfires have destroyed multiple residential communities in California in recent years. After fires in 2017 and 2018, high concentrations of benzene and other volatile organic compounds (VOCs) were found in public drinking water systems in fire-affected areas. The sources of the contamination and appropriate remediation have been urgent matter of investigation. This study characterizes target and nontarget VOCs and semivolatile organic compounds in water from a highly contaminated service line after the 2018 Camp Fire (Paradise, CA). Ninety-five organic compounds were identified or tentatively identified in the service line. Laboratory combustion experiments with drinking water pipes made of polyvinyl chloride (PVC), cross-linked polyethylene, and high-d. polyethylene and a review of the literature were used to evaluate potential sources of the detected chems. Among the service line contaminants were 32 compounds associated with PVC pyrolysis and 28 organic compounds also associated with the pyrolysis of polyethylene. The service line sample also contained 55 compounds associated with uncontrolled burning of biomass and waste materials. The findings support hypotheses that wildfires can contaminate drinking water systems both by thermal damage to plastic pipes and intrusion of smoke. Residual chlorine disinfectants in the water system modify the contaminant distribution observed In the experiment, the researchers used many compounds, for example, 2,2-Bis(((3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoyl)oxy)methyl)propane-1,3-diyl bis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoate) (cas: 6683-19-8Computed Properties of C73H108O12).

2,2-Bis(((3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoyl)oxy)methyl)propane-1,3-diyl bis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoate) (cas: 6683-19-8) belongs to esters. Carboxylic acid esters of low molecular weight are colourless, volatile liquids with pleasant odours, slightly soluble in water. Acyl chlorides and acid anhydrides alcoholysis is another way to produce esters. Acyl chlorides and acid anhydrides react with alcohols to produce esters. Anydrous conditions are recommended since both acyl chlorides and acid anhydrides react with water.Computed Properties of C73H108O12

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Multi-step polymer degradation kinetics using activation energy-dependent cataluminescence was written by Li, Zenghe;Feng, Jing;Tian, Rui;Lu, Chao. And the article was included in Green Chemistry in 2022.Synthetic Route of C73H108O12 This article mentions the following:

Understanding the mechanism of polymer degradation is vital to the development of rational strategies for polymer management. However, conventional techniques for polymer degradation evaluation rely on the determination of functional group or mol. weight, which fail to provide kinetic information on the steps for polymer degradation Herein, the degradation evolution and kinetics of polyoxymethylene (POM) are monitored using cataluminescence (CTL) dynamic curves of the generated formaldehyde. The two peaks in the CTL dynamic curves for POM under different atmospheres indicate the occurrence of different reaction pathways, dependent on the reaction kinetics and activation energies of the degradation steps. The activation energies of 31.44 and 48.14 kJ mol^-1 were attributed to the end-group rupture, and a higher activation energy of 119.52 kJ mol^-1 was responsible for the harsh oxidation reaction of POM. Therefore, we have demonstrated the capability of CTL for the real-time monitoring and effective differentiation of the degradation pathways for polymers. It is anticipated that this method will provide viable possibilities for the design of polymers with high reliability and sustainability. In the experiment, the researchers used many compounds, for example, 2,2-Bis(((3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoyl)oxy)methyl)propane-1,3-diyl bis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoate) (cas: 6683-19-8Synthetic Route of C73H108O12).

2,2-Bis(((3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoyl)oxy)methyl)propane-1,3-diyl bis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoate) (cas: 6683-19-8) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits, including apples, durians, pears, bananas, pineapples, and strawberries. Many esters have the potential for conformational isomerism, but they tend to adopt an s-cis (or Z) conformation rather than the s-trans (or E) alternative, due to a combination of hyperconjugation and dipole minimization effects. The preference for the Z conformation is influenced by the nature of the substituents and solvent, if present. Lactones with small rings are restricted to the s-trans (i.e. E) conformation due to their cyclic structure.Synthetic Route of C73H108O12

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Super-Tough Poly(lactic Acid)-Based Thermoplastic Vulcanizate Based on Selective Dispersion and In Situ Compatibilization of Commercial Reinforcing Fillers and Its Application in Three-Dimensional Printing was written by Gong, Zhou;Huang, Jiarong;Fan, Jianfeng;Chen, Xiaoqing;Wang, Hui;Chen, Yukun. And the article was included in Industrial & Engineering Chemistry Research in 2022.Computed Properties of C73H108O12 This article mentions the following:

Blending with elastomers is a commonly used method to improve the toughness of poly(lactic acid) (PLA). However, the poor compatibility between polar PLA and the nonpolar elastomer results in a limited improvement of the toughness. In this work, we report a simple but effective strategy to improve the compatibility between PLA and natural rubber (NR) and manufacture super-tough PLA-based thermoplastic vulcanizate (TPV). We choose the widely used reinforcing filler SiO₂ nanoparticles as the compatibilizer, whose modification using 3-(trimethoxysilyl)propyl methacrylate (KH570) is synchronized with the dynamic vulcanization. Simultaneously, the modified SiO₂ nanoparticles migrate from the NR phase to the PLA/NR interface due to the interfacial tension. The modified SiO₂ nanoparticles located at the interface entangle with the NR chains on the one hand and graft with the PLA chain on the other hand, acting as a “bridge” to improve the interfacial compatibility of the two phases. While only adding a small amount of filler, 20 phr SiO₂ nanoparticles in NR and 7 phr modifier in SiO₂, the impact strength of the PLA/NR (80/20) TPV increases to 95.96 kJ/m² (without fracture), which is 38-fold than pure PLA. Even in a low temperature of -30°C, the impact strength is still 7.93 kJ/m². Finally, the co-continuous structure and the excellent toughness with a small amount of toughener make the TPV have great potential for application in the 3D printing field (processing speed of 110 m/min, over 100 times bend after immersion in hot water). In the experiment, the researchers used many compounds, for example, 2,2-Bis(((3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoyl)oxy)methyl)propane-1,3-diyl bis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoate) (cas: 6683-19-8Computed Properties of C73H108O12).

2,2-Bis(((3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoyl)oxy)methyl)propane-1,3-diyl bis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoate) (cas: 6683-19-8) belongs to esters. Esters are also usually derived from carboxylic acids. It may also be obtained by reaction of acid anhydride or acid halides with alcohols or by the reaction of salts of carboxylic acids with alkyl halides. Esters contain a carbonyl center, which gives rise to 120° C–C–O and O–C–O angles. Unlike amides, esters are structurally flexible functional groups because rotation about the C–O–C bonds has a low barrier. Their flexibility and low polarity is manifested in their physical properties; they tend to be less rigid (lower melting point) and more volatile (lower boiling point) than the corresponding amides. Computed Properties of C73H108O12

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics