Tag: 100-200

The One-pot Encapsulation of Palladium Complexes into Covalent Organic Frameworks Enables the Alkoxycarbonylation of Olefins was written by Yang, Xin;Du, Yi-Ran;Guan, Peng-Xin;Liu, Hong-Ying;Wang, Yao-Feng;Xu, Bao-Hua. And the article was included in ChemCatChem in 2022.Name: Methyl heptanoate The following contents are mentioned in the article:

In this study, palladium-based heterogeneous catalysts were successfully prepared by encapsulating the palladium diphosphine complexes into an imine-linked 2D-COF (TPB-DMTP-COF) through a one pot self-assembly approach. It not only prevents the oxidation of phosphine-based ligand during the stepwise impregnation but also suppresses the coordination of imine linkers at the COF host to the palladium guest, thus enabling highly efficient encapsulation of the active bidentate phosphine chelated palladium complex by the widely explored imine-linked COF. Besides, the dosage of diphosphine ligand (Xantphos-SO₃H, L) and the ratio of palladium to L in the preparation of [Pd]@COF hybrids can be readily adjusted under such one pot procedure to satisfy the requirement of crystallinity, porosity, active sites, and CO adsorption capacity for the catalytic performance in the methoxycarbonylation of olefins. The resultant [Pd]@COF-A-0.25-0.5 provides satisfied catalytic performance for both aliphatic and aromatic olefins with total esters up to 92.1% under optimized conditions. These findings provide the basis for a novel design concept to design heterogeneous catalysts with high efficiency for reaction processes comprising the alkoxycarbonylation of olefins. This study involved multiple reactions and reactants, such as Methyl heptanoate (cas: 106-73-0Name: Methyl heptanoate).

Methyl heptanoate (cas: 106-73-0) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Liquid esters of low volatility serve as softening agents for resins and plastics. Esters also include many industrially important polymers. Polymethyl methacrylate is a glass substitute sold under the names Lucite and Plexiglas; polyethylene terephthalate is used as a film (Mylar) and as textile fibres sold as Terylene, Fortrel, and Dacron.Name: Methyl heptanoate

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Functional microbial agents enhance ethanol contents and regulate the volatile compounds in Chinese Baijiu was written by Hong, Lixia;Fu, Guiming;Liu, Ting;Chen, Yanru;Wu, Shengwen;Cai, Wenqin;Xie, Zijun;Wan, Yin. And the article was included in Food Bioscience in 2021.Application In Synthesis of Isopentyl hexanoate The following contents are mentioned in the article:

In this study, functional microbial agents (FMA) with different ester-producing yeasts as variables were used instead of traditional Daqu to simulate the solid-state fermentation (SSF) of special-flavor Baijiu. The effects of FMA on the ethanol contents, volatile compounds and microbial community of Jiupei after 30 days of brewing were studied. Results showed that the ethanol contents in Jiupei with functional microbial agent groups (FMG) were higher than that of the control group with traditional Daqu (G5), and the ethanol content in Jiupei using the agents fortified with Wickerhamomyces anomalus (G3) was the highest (3.67% volume/volume). Results of high-throughput sequencing technol. showed that Lactobacillus genus was dominant bacterial genus in the bacterial community, and the relative abundance of Lactobacillus genus in Jiupei with G3 was 87.0%, which was similar to that in Jiupei with G5 (87.6%). The content of volatile compounds in Jiupei with G3 was 136.02 mg/kg, which was the highest in Jiupei with FMG and the closest to the Jiupei with G5. These results showed that the use of FMA to replace traditional Daqu could increase the yield of ethanol in Chinese Baijiu brewing, and the volatile compounds in Jiupei with G3 were close to that of the G5. This study involved multiple reactions and reactants, such as Isopentyl hexanoate (cas: 2198-61-0Application In Synthesis of Isopentyl hexanoate).

Isopentyl hexanoate (cas: 2198-61-0) belongs to esters. Volatile esters with characteristic odours are used in synthetic flavours, perfumes, and cosmetics. Certain volatile esters are used as solvents for lacquers, paints, and varnishes. Esters contain a carbonyl center, which gives rise to 120° C–C–O and O–C–O angles. Unlike amides, esters are structurally flexible functional groups because rotation about the C–O–C bonds has a low barrier. Their flexibility and low polarity is manifested in their physical properties; they tend to be less rigid (lower melting point) and more volatile (lower boiling point) than the corresponding amides. Application In Synthesis of Isopentyl hexanoate

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Chemical, physical, and sensory effects of the use of bentonite at different stages of the production of traditional sparkling wines was written by Ubeda, Cristina;Lambert-Royo, Maria Ignacia;i Cortiella, Mariona Gil;Del Barrio-Galan, Ruben;Pena-Neira, Alvaro. And the article was included in Foods in 2021.Computed Properties of C11H22O2 The following contents are mentioned in the article:

The addition of bentonite to wine to eliminate unstable haze-forming proteins and as a riddling adjuvant in the remuage is not selective, and other important mols. are lost in this process. The moment of the addition of bentonite is a key factor. Volatile profile (SPME-GC-MS), foam characteristics (Mosalux method), and sensory analyses were performed to study the effect of the distribution of the dosage of bentonite for stabilization of the wine among the addition on the base wine before the tirage (50%, 75%, and 100% bentonite dosage) and during the tirage (addition of the remaining dosage for each case). Results showed that the addition of 50% of the bentonite to the base wine (before the tirage) resulted in sparkling wines with the lowest quantity of volatile compounds, mainly esters and norisoprenoids. No significant differences were found among the sparkling wines after 9 mo of aging in relation to foam properties measured by Mosalux, although higher foamability and crown’s persistence were perceived in the sparkling wines with the addition of 75% and 100% of the bentonite dosage in sensory trials. The results of this study suggested that the amount of bentonite added as a fining agent in the tirage had greater effects than during the addition of this agent in the base wine. This study involved multiple reactions and reactants, such as Isopentyl hexanoate (cas: 2198-61-0Computed Properties of C11H22O2).

Isopentyl hexanoate (cas: 2198-61-0) belongs to esters. Volatile esters with characteristic odours are used in synthetic flavours, perfumes, and cosmetics. Certain volatile esters are used as solvents for lacquers, paints, and varnishes. Esters are more polar than ethers but less polar than alcohols. They participate in hydrogen bonds as hydrogen-bond acceptors, but cannot act as hydrogen-bond donors, unlike their parent alcohols. This ability to participate in hydrogen bonding confers some water-solubility.Computed Properties of C11H22O2

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Long term exposure to virgin and recycled ldpe microplastics induced minor effects in the freshwater and terrestrial crustaceans Daphnia magna and Porcellio scaber was written by Kokalj, Anita Jemec;Dolar, Andraz;Titova, Jelizaveta;Visnapuu, Meeri;Skrlep, Luka;Drobne, Damjana;Vija, Heiki;Kisand, Vambola;Heinlaan, Margit. And the article was included in Polymers (Basel, Switzerland) in 2021.Category: esters-buliding-blocks The following contents are mentioned in the article:

The effects of microplastics (MP) are extensively studied, yet hazard data from long-term exposure studies are scarce. Moreover, for sustainable circular use in the future, knowledge on the biol. impact of recycled plastics is essential. The aim of this study was to provide long-term toxicity data of virgin vs recycled (mech. recycling) low d. polyethylene (LDPE) for two commonly used ecotoxicity models, the freshwater crustacean Daphnia magna and the terrestrial crustacean Porcellio scaber. LDPE MP was tested as fragments of 39.8 ± 8.82 μm (virgin) and 205 ± 144 μm (recycled) at chronic exposure levels of 1-100 mg LDPE/L (D. magna) and 0.2-15 g LDPE/kg soil (P. scaber). Mortality, reproduction, body length, total lipid content, feeding and immune response were evaluated. With the exception of very low inconsistent offspring mortality at 10 mg/L and 100 mg/L of recycled LDPE, no MP exposure-related adverse effects were recorded for D. magna. For P. scaber, increased feeding on non-contaminated leaves was observed for virgin LDPE at 5 g/kg and 15 g/kg. In addition, both LDPE induced a slight immune response at 5 g/kg and 15 g/kg with more parameters altered for virgin LDPE. Our results indicated different sublethal responses upon exposure to recycled compared to virgin LDPE MP. This study involved multiple reactions and reactants, such as Ethyl methyl adipate (cas: 18891-13-9Category: esters-buliding-blocks).

Ethyl methyl adipate (cas: 18891-13-9) belongs to esters. Volatile esters with characteristic odours are used in synthetic flavours, perfumes, and cosmetics. Certain volatile esters are used as solvents for lacquers, paints, and varnishes. Because of their lack of hydrogen-bond-donating ability, esters do not self-associate. Consequently, esters are more volatile than carboxylic acids of similar molecular weight.Category: esters-buliding-blocks

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Chemical profiling and cytotoxic activity of 150-year old original sample of Jerusalem Balsam was written by Lyczko, Jacek;Pawlak, Aleksandra;Augustynski, Iwo;Okinczyc, Piotr;Szperlik, Jakub;Kulma, Anna;Rozanski, Henryk;Obminska-Mrukowicz, Bozena;Szumny, Antoni. And the article was included in Food and Chemical Toxicology in 2020.Category: esters-buliding-blocks The following contents are mentioned in the article:

Herbal formulations have been used in ethnomedicine and pharmacy around the world for thousands of years. One of them is Jerusalem Balsam (JB), which came into use in the seventeenth century. Today, people still produce and use it regularly as prophylactic supplement. JB has been widely used in Europe since the nineteenth century, as a remedy possessing antibacterial, antifungal and anti-inflammatory activities. The composition of the product was not known, although possible formulations were reported. In this study the original sample, which dated back to 1870, was investigated for chem. composition and cytotoxic activity. The obtained results were compared with results from more recently produced samples. Several tests were carried out, namely GC-MS, UPLC-PDA-Q-TOF-MS and MTT. Only the 150-yr old sample showed a significant cytotoxic activity on cancer cell lines. At a concentration of 125μg/mL after 72 h of incubation, the original sample inhibited almost 90% of cell metabolic activity, while contemporary samples showed none or little activity. None of the tested samples showed a significant impact on normal cells. These results may be attributed to the activities of benzoic acid and its derivatives, cinnamic acid derivatives, vanillin, group of sesquiterpenes and cembrene. This study involved multiple reactions and reactants, such as Octyl acetate (cas: 112-14-1Category: esters-buliding-blocks).

Octyl acetate (cas: 112-14-1) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits, including apples, durians, pears, bananas, pineapples, and strawberries. Cyclic esters are called lactones, regardless of whether they are derived from an organic or inorganic acid. One example of an organic lactone is γ-valerolactone.Category: esters-buliding-blocks

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Polymeric protective coatings for MEMS wet-etch processes was written by Ruben, Kimberly A.;Flaim, Tony D.;Li, Chenghong. And the article was included in Proceedings of SPIE-The International Society for Optical Engineering in 2004.Reference of 763-69-9 The following contents are mentioned in the article:

Microelectromech. systems (MEMS) device manufacturers today are faced with the challenge of protecting electronic circuitry and other sensitive device structures during deep Si wet-etch processes. Etch processes of this nature require prolonged exposure of the device to harsh corrosive mixtures of aqueous acids and bases at higher than ambient temperatures A need exists for a spin-applied polymeric coating to prevent the exposure of such circuitry against the corrosive etchants. The challenge exists in developing protective coatings that will not decompose or dissolve in the etchants during the etch process. Such coatings require superior adhesion to the substrate without destroying the sensitive features below. Brewer Science, Inc., has developed a multilayer coating system for basic etchants which is compatible with a variety of semiconductor materials and offers protection against concentrated KOH etchants at prolonged exposure times of >8 h. In addition, a 2nd multilayer coating system is being developed for use with strong HF and other various mixed acid etchants (MAEs) for exposures of 30 min or longer. These materials are specifically designed to protect circuitry subjected to concentrated MAEs during the wafer thinning processes used by MEMS device manufacturers. This study involved multiple reactions and reactants, such as Ethyl 3-ethoxypropanoate (cas: 763-69-9Reference of 763-69-9).

Ethyl 3-ethoxypropanoate (cas: 763-69-9) belongs to esters. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Because of their lack of hydrogen-bond-donating ability, esters do not self-associate. Consequently, esters are more volatile than carboxylic acids of similar molecular weight.Reference of 763-69-9

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

A chemometric approach to compare Portuguese native hops with worldwide commercial varieties was written by Martins, Zita E.;Machado, Julio C. Jr.;Cunha, Sara C.;Barata, Ana Maria;Ferreira, Isabel M. P. L. V. O.. And the article was included in Journal of Chemometrics in 2020.Name: Methyl heptanoate The following contents are mentioned in the article:

A diversity of native hops can be found in Portugal, but little is known concerning their volatile and sensory profiles. Nowadays, the exponential growth of the craft beer sector and the preference for more flavoured beers promote the research of unexplored wild hops that have the advantage of being well adapted to the Portuguese edaphoclimatic conditions. Therefore, the goal of this study was to characterize the volatile profile of 75 native Portuguese hops and compare with 34 com. varieties by means of headspace solid-phase microextraction gas chromatog./mass spectrometry (HS-SPME-GC/MS), in order to select those that present similarities with commercialized hops and confirm by check-all-that-apply (CATA) anal. if they present similar organoleptic characteristics. Due to the complexity of hop volatile profile and the great number of samples analyzed, robust chemometric treatment of chromatog. and sensorial data was required to make reliable conclusions. Twelve Portuguese hops present a volatile profile and sensory characteristics quite similar to some com. varieties, because 11 Portuguese hops were grouped with the European varieties Challenger, Hallertauer Magnum and Perle, both in volatile profile and sensory anal. and one clustered with American registered varieties. This study involved multiple reactions and reactants, such as Methyl heptanoate (cas: 106-73-0Name: Methyl heptanoate).

Methyl heptanoate (cas: 106-73-0) belongs to esters. Esters are also usually derived from carboxylic acids. It may also be obtained by reaction of acid anhydride or acid halides with alcohols or by the reaction of salts of carboxylic acids with alkyl halides. Esters are more polar than ethers but less polar than alcohols. They participate in hydrogen bonds as hydrogen-bond acceptors, but cannot act as hydrogen-bond donors, unlike their parent alcohols. This ability to participate in hydrogen bonding confers some water-solubility.Name: Methyl heptanoate

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

A chemometric approach to compare Portuguese native hops with worldwide commercial varieties was written by Martins, Zita E.;Machado, Julio C. Jr.;Cunha, Sara C.;Barata, Ana Maria;Ferreira, Isabel M. P. L. V. O.. And the article was included in Journal of Chemometrics in 2020.Category: esters-buliding-blocks The following contents are mentioned in the article:

A diversity of native hops can be found in Portugal, but little is known concerning their volatile and sensory profiles. Nowadays, the exponential growth of the craft beer sector and the preference for more flavoured beers promote the research of unexplored wild hops that have the advantage of being well adapted to the Portuguese edaphoclimatic conditions. Therefore, the goal of this study was to characterize the volatile profile of 75 native Portuguese hops and compare with 34 com. varieties by means of headspace solid-phase microextraction gas chromatog./mass spectrometry (HS-SPME-GC/MS), in order to select those that present similarities with commercialized hops and confirm by check-all-that-apply (CATA) anal. if they present similar organoleptic characteristics. Due to the complexity of hop volatile profile and the great number of samples analyzed, robust chemometric treatment of chromatog. and sensorial data was required to make reliable conclusions. Twelve Portuguese hops present a volatile profile and sensory characteristics quite similar to some com. varieties, because 11 Portuguese hops were grouped with the European varieties Challenger, Hallertauer Magnum and Perle, both in volatile profile and sensory anal. and one clustered with American registered varieties. This study involved multiple reactions and reactants, such as Octyl acetate (cas: 112-14-1Category: esters-buliding-blocks).

Octyl acetate (cas: 112-14-1) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Polyesters are important plastics, with monomers linked by ester moieties. Liquid esters of low volatility serve as softening agents for resins and plastics. Esters also include many industrially important polymers. Polymethyl methacrylate is a glass substitute sold under the names Lucite and Plexiglas; polyethylene terephthalate is used as a film (Mylar) and as textile fibres sold as Terylene, Fortrel, and Dacron.Category: esters-buliding-blocks

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Use of Hanseniaspora guilliermondii and Hanseniaspora opuntiae to enhance the aromatic profile of beer in mixed-culture fermentation with Saccharomyces cerevisiae was written by Bourbon-Melo, Nuno;Palma, Margarida;Rocha, Miguel Pinto;Ferreira, Antonio;Bronze, Maria Rosario;Elias, Hugo;Sa-Correia, Isabel. And the article was included in Food Microbiology in 2021.Reference of 112-14-1 The following contents are mentioned in the article:

Beer production is predominantly carried out by Saccharomyces species, such as S. cerevisiae and S. pastorianus. However, the introduction of non-Saccharomyces yeasts in the brewing process is now seen as a promising strategy to improve and differentiate the organoleptic profile of beer. In this study, 17 non-Saccharomyces strains of 12 distinct species were isolated and submitted to a preliminary sensory evaluation to determine their potential for beer bioflavouring. Hanseniaspora guilliermondii IST315 and H. opuntiae IST408 aroma profiles presented the highest acceptability and were described as having ‘fruity’ and ‘toffee’ notes, resp. Their presence in mixed-culture fermentations with S. cerevisiae US-05 did not influence attenuation and ethanol concentration of beer but had a significant impact in its volatile composition Notably, while both strains reduced the total amount of Et esters, H. guilliermondii IST315 greatly increased the concentration of acetate esters, especially when sequentially inoculated, leading to an 8.2-fold increase in phenylethyl acetate (‘rose’, ‘honey’ aroma) in the final beverage. These findings highlight the importance of non-Saccharomyces yeasts in shaping the aroma profile of beer and suggest a role for Hanseniaspora spp. in improving it. This study involved multiple reactions and reactants, such as Octyl acetate (cas: 112-14-1Reference of 112-14-1).

Octyl acetate (cas: 112-14-1) belongs to esters. Esters are also usually derived from carboxylic acids. It may also be obtained by reaction of acid anhydride or acid halides with alcohols or by the reaction of salts of carboxylic acids with alkyl halides. Esterification is the general name for a chemical reaction in which two reactants (typically an alcohol and an acid) form an ester as the reaction product. Esters are common in organic chemistry and biological materials.Reference of 112-14-1

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Characterization of key odorants in Hanyuan and Hancheng fried pepper (Zanthoxylum bungeanum) oil was written by Sun, Jie;Sun, Baoguo;Ren, Fazheng;Chen, Haitao;Zhang, Ning;Zhang, Yuyu. And the article was included in Journal of Agricultural and Food Chemistry in 2020.Application of 112-14-1 The following contents are mentioned in the article:

Fried pepper (Zanthoxylum bungeanum Maxim.) oil has been widely used in traditional Chinese cuisine and has recently become increasingly popular in food manufacturing Thus, the aroma profiles of Hancheng pepper oil (HCPO) and Hanyuan pepper oil (HYPO) from two regions were investigated by aroma extract dilution anal. (AEDA) combined with gas chromatog.-mass spectrometry-olfactometry (GC-MS-O). Results from AEDA showed that more aroma compounds with flavor dilution factors ≥9 were detected in HCPO than in HYPO. The odor activity values (OAVs) revealed 28 odorants with OAVs ≥1 in HCPO or HYPO. High OAVs were in particular obtained for 1,8-cineole, (E)-2-heptenal, β-myrcene, β-ocimene, limonene, and linalool. Then, the aroma profiles of HCPO and HYPO were successfully simulated through aroma recombination models. Omission tests suggested that β-phellandrene, p-cymene, acetic acid octyl ester, octanal, citronellol, and sabinene played key roles in aroma differences between HCPO and HYPO. In addition, varying enantiomeric ratios of linalool (floral) and limonene (citrus-like and lemon-like) in HCPO and HYPO were observed by chiral GC-MS, and the odor impressions of limonene and linalool were in good agreement with the odor descriptions of S-(-)-limonene and S-(+)-linalool. This study involved multiple reactions and reactants, such as Octyl acetate (cas: 112-14-1Application of 112-14-1).

Octyl acetate (cas: 112-14-1) belongs to esters. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Many esters have the potential for conformational isomerism, but they tend to adopt an s-cis (or Z) conformation rather than the s-trans (or E) alternative, due to a combination of hyperconjugation and dipole minimization effects. The preference for the Z conformation is influenced by the nature of the substituents and solvent, if present. Lactones with small rings are restricted to the s-trans (i.e. E) conformation due to their cyclic structure.Application of 112-14-1

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics