Tag: 100-200

Triphenylphosphine-catalyzed Michael addition of alcohols to acrylic compounds was written by Liu, Hai-Ling;Jiang, Huan-Feng;Wang, Yu-Gang. And the article was included in Chinese Journal of Chemistry in 2007.Reference of 763-69-9 The following contents are mentioned in the article:

A facile PPh₃-catalyzed Michael addition of alcs. to acrylic compounds was described. The reaction was carried out in open air at reflux temperature in the presence of 10 mol% PPh₃. Michael addition of saturated and unsaturated alcs. to acrylonitrile or acrylates was examined The reaction gave β-alkoxy derivatives with isolated yields of 5-79%. PPh₃ is cheaper and more stable than those trialkylphosphines previously used for the similar reactions, and the products can be easily separated from the reaction mixture via distillation This study involved multiple reactions and reactants, such as Ethyl 3-ethoxypropanoate (cas: 763-69-9Reference of 763-69-9).

Ethyl 3-ethoxypropanoate (cas: 763-69-9) belongs to esters. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Because of their lack of hydrogen-bond-donating ability, esters do not self-associate. Consequently, esters are more volatile than carboxylic acids of similar molecular weight.Reference of 763-69-9

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Conversion of single crystals of a nickel(II) dithiocarbamate complex to nickel sulfide crystals was written by Angeloski, Alexander;Cortie, Michael B.;Scott, John A.;Bordin, Dayanne M.;McDonagh, Andrew M.. And the article was included in Inorganica Chimica Acta in 2019.Application of 2253-73-8 The following contents are mentioned in the article:

Single crystals of bis(κ²S,S’-di(isopropyl)dithiocarbamato) Ni(II) were used as a single source precursor for the formation of NiS via thermolysis. The complex decomposed at ∼250° to form α-NiS exclusively with no β-NiS detected. Anal. of the thermolysis regime using in situ techniques showed that the thermolysis occurs in a single step with the major volatile side-products being isopropyl-isothiocyanate and CS₂. The resultant NiS was examined using SEM and TEM to reveal a retention of precursor crystal edge-length and angle relations. This study involved multiple reactions and reactants, such as Isopropylisothiocyanate (cas: 2253-73-8Application of 2253-73-8).

Isopropylisothiocyanate (cas: 2253-73-8) belongs to esters. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Many esters have the potential for conformational isomerism, but they tend to adopt an s-cis (or Z) conformation rather than the s-trans (or E) alternative, due to a combination of hyperconjugation and dipole minimization effects. The preference for the Z conformation is influenced by the nature of the substituents and solvent, if present. Lactones with small rings are restricted to the s-trans (i.e. E) conformation due to their cyclic structure.Application of 2253-73-8

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Conversion of single crystals of a nickel(II) dithiocarbamate complex to nickel sulfide crystals was written by Angeloski, Alexander;Cortie, Michael B.;Scott, John A.;Bordin, Dayanne M.;McDonagh, Andrew M.. And the article was included in Inorganica Chimica Acta in 2019.Application of 2253-73-8 The following contents are mentioned in the article:

Single crystals of bis(κ²S,S’-di(isopropyl)dithiocarbamato) Ni(II) were used as a single source precursor for the formation of NiS via thermolysis. The complex decomposed at ∼250° to form α-NiS exclusively with no β-NiS detected. Anal. of the thermolysis regime using in situ techniques showed that the thermolysis occurs in a single step with the major volatile side-products being isopropyl-isothiocyanate and CS₂. The resultant NiS was examined using SEM and TEM to reveal a retention of precursor crystal edge-length and angle relations. This study involved multiple reactions and reactants, such as Isopropylisothiocyanate (cas: 2253-73-8Application of 2253-73-8).

Isopropylisothiocyanate (cas: 2253-73-8) belongs to esters. Esters are also usually derived from carboxylic acids. It may also be obtained by reaction of acid anhydride or acid halides with alcohols or by the reaction of salts of carboxylic acids with alkyl halides. Acyl chlorides and acid anhydrides alcoholysis is another way to produce esters. Acyl chlorides and acid anhydrides react with alcohols to produce esters. Anydrous conditions are recommended since both acyl chlorides and acid anhydrides react with water.Application of 2253-73-8

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

A one-pot route to thioamides discovered by gas-phase studies: palladium-mediated CO₂ extrusion followed by insertion of isothiocyanates was written by Noor, Asif;Li, Jiawei;Khairallah, George N.;Li, Zhen;Ghari, Hossein;Canty, Allan J.;Ariafard, Alireza;Donnelly, Paul S.;O’Hair, Richard A. J.. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2017.Quality Control of Isopropylisothiocyanate The following contents are mentioned in the article:

A new palladium mediated “one pot” synthesis of thioamides ArC(S)NHR (R = CH₃, p-F₃CC₆H₄, C₆H₅, etc.; Ar = Ph, 2,6-dimethoxyphenyl) from aromatic carboxylic acids such as 2,6-dimethoxybenzoic acid and benzoic acid (ArCO₂H + RNCS → ArC(S)NHR + CO₂) was discovered by gas-phase experiments and theor. studies. Palladium-mediated decarboxylation of aromatic carboxylic acids followed by addition of substituted isothiocyanates leads to the corresponding thioamide derivatives This study involved multiple reactions and reactants, such as Isopropylisothiocyanate (cas: 2253-73-8Quality Control of Isopropylisothiocyanate).

Isopropylisothiocyanate (cas: 2253-73-8) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits. Esters contain a carbonyl center, which gives rise to 120° C–C–O and O–C–O angles. Unlike amides, esters are structurally flexible functional groups because rotation about the C–O–C bonds has a low barrier. Their flexibility and low polarity is manifested in their physical properties; they tend to be less rigid (lower melting point) and more volatile (lower boiling point) than the corresponding amides. Quality Control of Isopropylisothiocyanate

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

CuBr-Catalysed one-pot multicomponent synthesis of 3-substituted 2-thioxo-2,3-dihydroquinazolin-4(1H)-one derivatives was written by Sayahi, Mohammad Hosein;Saghanezhad, Seyyed Jafar;Bahadorikhalili, Saeed;Mahdavi, Mohammad. And the article was included in Applied Organometallic Chemistry in 2019.Formula: C4H7NS The following contents are mentioned in the article:

A novel methodol. was developed for the synthesis of 3-substituted 2-thioxo-2,3-dihydroquinazolin-4(1H)-one derivatives I [R = i-Pr, Ph, Bn, etc.] based on the multicomponent one-pot reaction of Me 2-bromobenzoate, phenylisothiocyanate derivatives and sodium azide in the presence of copper bromide and L-proline under basic conditions. To show the generality of the method, various phenylisothiocyanates bearing electron-donating or electron-withdrawing functionalities were used and desired products were obtained in high isolated yields. This study involved multiple reactions and reactants, such as Isopropylisothiocyanate (cas: 2253-73-8Formula: C4H7NS).

Isopropylisothiocyanate (cas: 2253-73-8) belongs to esters. Esters are also usually derived from carboxylic acids. It may also be obtained by reaction of acid anhydride or acid halides with alcohols or by the reaction of salts of carboxylic acids with alkyl halides. Liquid esters of low volatility serve as softening agents for resins and plastics. Esters also include many industrially important polymers. Polymethyl methacrylate is a glass substitute sold under the names Lucite and Plexiglas; polyethylene terephthalate is used as a film (Mylar) and as textile fibres sold as Terylene, Fortrel, and Dacron.Formula: C4H7NS

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Intermolecular carbon-carbon bond formation followed by intramolecular cyclization of electrochemically generated magnesium anthracenes and esters in the presence of chlorotrimethylsilane was written by Matsumoto, Kouichi;Matsumoto, Masahiro;Hayashi, Terumasa;Maekawa, Masahiko;Nishiwaki, Keiji;Kashimura, Shigenori. And the article was included in Electrochemistry (Tokyo, Japan) in 2020.Reference of 106-73-0 The following contents are mentioned in the article:

The electrochem. reduction of anthracenes in the presence of esters and chlorotrimethylsilane in LiClO4/THF in the undivided cell equipped with magnesium electrodes affords the corresponding cyclized products at low to moderate yields. Herein, the chem. structure of the product is determined by X-ray anal., as well as ¹H NMR, ¹³C NMR, and HRMS. The in situ generation of magnesium anthracenes is indicated. The scope and limitations of the current reactions using anthracene and its derivatives with various esters are investigated. This study involved multiple reactions and reactants, such as Methyl heptanoate (cas: 106-73-0Reference of 106-73-0).

Methyl heptanoate (cas: 106-73-0) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits, including apples, durians, pears, bananas, pineapples, and strawberries. Esters contain a carbonyl center, which gives rise to 120° C–C–O and O–C–O angles. Unlike amides, esters are structurally flexible functional groups because rotation about the C–O–C bonds has a low barrier. Their flexibility and low polarity is manifested in their physical properties; they tend to be less rigid (lower melting point) and more volatile (lower boiling point) than the corresponding amides. Reference of 106-73-0

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Trametes versicolor (L.) mushrooms liquefaction in supercritical solvents: Effects of operating conditions on product yields and chromatographic characterization was written by Durak, Halil. And the article was included in Journal of Supercritical Fluids in 2018.HPLC of Formula: 2253-73-8 The following contents are mentioned in the article:

In this study, the effect of reaction temperature, solvent and catalyst were examined on conversion of Trametes versicolor mushroom. Supercritical liquefaction experiments were made in a cylindrical reactor in acetone and isopropanol under supercritical circumstances with (Aluminum oxide, calcium hydroxide) and without catalyst at the temperatures of 250, 270, 290 ^°C. The bio-oils obtained at 250 and 290 °C in liquefaction were analyzed and characterized by chromatog. and spectroscopic techniques containing GC-MS, FT-IR and elemental anal. This study involved multiple reactions and reactants, such as Isopropylisothiocyanate (cas: 2253-73-8HPLC of Formula: 2253-73-8).

Isopropylisothiocyanate (cas: 2253-73-8) belongs to esters. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Esterification is the general name for a chemical reaction in which two reactants (typically an alcohol and an acid) form an ester as the reaction product. Esters are common in organic chemistry and biological materials.HPLC of Formula: 2253-73-8

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Copper-Catalyzed One-Pot Synthesis of 2,5-Disubstituted 1,3,4-Oxadiazoles from Arylacetic Acids and Hydrazides via Dual Oxidation was written by Lekkala, Chinnari;Bodala, Varaprasad;Yettula, Kumari;Karasala, Bharat Kumar;Podugu, Rajitha Lakshmi;Vidavalur, Siddaiah. And the article was included in ACS Omega in 2022.Quality Control of Methyl heptanoate The following contents are mentioned in the article:

A simple and efficient protocol was developed to access sym. and unsym. 2,5-disubstituted 1,3,4-oxadiazoles from arylacetic acids and hydrazides via copper-catalyzed dual oxidation under an oxygen atm. Oxidative decarboxylation of arylacetic acids and oxidative functionalization of the imine C-H bond were the key steps. This was the first example of the synthesis of 2,5-disubstituted 1,3,4-oxadiazoles through dual oxidation in one-pot. Avoidance of the expensive ligand and high yield of the products were advantageous features of the developed method. This study involved multiple reactions and reactants, such as Methyl heptanoate (cas: 106-73-0Quality Control of Methyl heptanoate).

Methyl heptanoate (cas: 106-73-0) belongs to esters. Volatile esters with characteristic odours are used in synthetic flavours, perfumes, and cosmetics. Certain volatile esters are used as solvents for lacquers, paints, and varnishes. Liquid esters of low volatility serve as softening agents for resins and plastics. Esters also include many industrially important polymers. Polymethyl methacrylate is a glass substitute sold under the names Lucite and Plexiglas; polyethylene terephthalate is used as a film (Mylar) and as textile fibres sold as Terylene, Fortrel, and Dacron.Quality Control of Methyl heptanoate

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Aerobic Copper-Catalyzed O-Methylation with Methylboronic Acid was written by Jacobson, Clare E.;Martinez-Munoz, Noelia;Gorin, David J.. And the article was included in Journal of Organic Chemistry in 2015.Product Details of 18891-13-9 The following contents are mentioned in the article:

The oxidative coupling of alkylboronic acids with oxygen nucleophiles offers a strategy for replacing toxic, electrophilic alkylating reagents. Although the Chan-Lam reaction has been widely applied in the arylation of heteroatom nucleophiles, O-alkylation with boronic acids is rare. We report a Cu-catalyzed nondecarboxylative methylation of carboxylic acids with methylboronic acid that proceeds in air with no addnl. oxidant. An isotope-labeling study supports an oxidative cross-coupling mechanism, in analogy to that proposed for Chan-Lam arylation. This study involved multiple reactions and reactants, such as Ethyl methyl adipate (cas: 18891-13-9Product Details of 18891-13-9).

Ethyl methyl adipate (cas: 18891-13-9) belongs to esters. Carboxylic acid esters of low molecular weight are colourless, volatile liquids with pleasant odours, slightly soluble in water. Esters contain a carbonyl center, which gives rise to 120° C–C–O and O–C–O angles. Unlike amides, esters are structurally flexible functional groups because rotation about the C–O–C bonds has a low barrier. Their flexibility and low polarity is manifested in their physical properties; they tend to be less rigid (lower melting point) and more volatile (lower boiling point) than the corresponding amides. Product Details of 18891-13-9

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Synthesis of new spiro pyrrole/pyrrolizine/thiazole derivatives via (3+2) cycloaddition reactions was written by Mali, Prakash R.;Khomane, Navnath B.;Sridhar, B.;Meshram, H. M.;Likhar, Pravin R.. And the article was included in New Journal of Chemistry in 2018.Application of 2253-73-8 The following contents are mentioned in the article:

A series of spiro pyrrole/pyrrolizine/thiazole compounds, e.g., I, were synthesized using [3+2]-dipolar cycloadditions via three-component condensation reactions of ninhydrin and α-amino acids with different dipolarophiles such as maleimide, malic anhydride, 2-benzyl-2-methylcyclopent-4-ene-1,3-dione and isothiocyanates. Another four-component protocol was developed in which ninhydrin, proline, maleimide and phenacyl bromides are reacted to afford a novel library of pyrrolizine derivatives in good yields without the use of catalyst. This study involved multiple reactions and reactants, such as Isopropylisothiocyanate (cas: 2253-73-8Application of 2253-73-8).

Isopropylisothiocyanate (cas: 2253-73-8) belongs to esters. Esters are also usually derived from carboxylic acids. It may also be obtained by reaction of acid anhydride or acid halides with alcohols or by the reaction of salts of carboxylic acids with alkyl halides. Cyclic esters are called lactones, regardless of whether they are derived from an organic or inorganic acid. One example of an organic lactone is γ-valerolactone.Application of 2253-73-8

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics