Tandon, Nitin’s team published research in RSC Advances in 2021 | CAS: 140-11-4

RSC Advances published new progress about Acylation. 140-11-4 belongs to class esters-buliding-blocks, name is Benzyl acetate, and the molecular formula is C9H10O2, Quality Control of 140-11-4.

Tandon, Nitin published the artcileMagnetically recyclable silica-coated ferrite magnetite-K10 montmorillonite nanocatalyst and its applications in O, N, and S-acylation reaction under solvent-free conditions, Quality Control of 140-11-4, the main research area is silica coated ferrite magnetite montmorillonite nanocatalyst; oxygen nitrogen sulfer acylation reaction solvent free condition.

Novel silica-coated ferrite nanoparticles supported with montmorillonite (K10) have been prepared successfully by using a simple impregnation method. Further, these nanoparticles were characterized by using different anal. methods like FT-IR, PXRD, EDS, and FE-SEM techniques. In addition, these nanoparticles have been explored for their catalytic activity for the O, N, and S-acylation reactions under solvent-free conditions which gave moderate to excellent yields in a much shorter reaction time. Moreover, these nanoparticles could easily be separated out from the reaction medium after the reaction completion by using an external magnetic field and have been re-used for 10 cycles without any significant loss of the catalytic activity.

RSC Advances published new progress about Acylation. 140-11-4 belongs to class esters-buliding-blocks, name is Benzyl acetate, and the molecular formula is C9H10O2, Quality Control of 140-11-4.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Luna-Mora, Ricardo Alfredo’s team published research in Journal of the Mexican Chemical Society in 2019 | CAS: 140-11-4

Journal of the Mexican Chemical Society published new progress about Acylation. 140-11-4 belongs to class esters-buliding-blocks, name is Benzyl acetate, and the molecular formula is C9H10O2, Application of Benzyl acetate.

Luna-Mora, Ricardo Alfredo published the artcileSimultaneous infrared-ultrasound irradiation in organic synthesis: acylation of amines alcohols and amino alcohols, Application of Benzyl acetate, the main research area is amine acylation IR ultrasonication green chem; alc acylation IR ultrasonication.

The acylation of both aliphatic and aromatic amines, alcs. and amino alcs. by simultaneous IR-ultrasound irradiation (SIUI) in solvent-free conditions in short reaction times and with good to excellent yields was achieved. The results obtained with SIUI and for thermal, IR and ultrasound energy sources are compared. This is the first report regarding to the application of SIUI in acylation reactions.

Journal of the Mexican Chemical Society published new progress about Acylation. 140-11-4 belongs to class esters-buliding-blocks, name is Benzyl acetate, and the molecular formula is C9H10O2, Application of Benzyl acetate.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Porras, Julian D.’s team published research in Water, Air, & Soil Pollution in 2020-10-31 | CAS: 142-90-5

Water, Air, & Soil Pollution published new progress about Acylation. 142-90-5 belongs to class esters-buliding-blocks, name is Dodecyl 2-methylacrylate, and the molecular formula is C16H30O2, Recommanded Product: Dodecyl 2-methylacrylate.

Porras, Julian D. published the artcileDevelopment of an Adsorbent for Bisphenol A Based on a Polymer Grafted from Microcrystalline Cellulose, Recommanded Product: Dodecyl 2-methylacrylate, the main research area is bisphenol polymer grafted microcrystalline cellulose adsorbent development.

We aimed to develop a sustainable adsorbent for bisphenol A (BPA), an endocrine disruptor that seriously threatens human health. First, microcrystalline cellulose (MCC) was reacted with 2-bromoisobutyrylbromide to obtain a surface initiator (SI) for the grafting of polystyrene (PS), poly(lauryl methacrylate) (PLMA), and poly(N,N-dimethylaminoethyl methacrylate) (PDM) through ARGET-ATRP. These polymers may have favorably interacted with BPA, which led to its removal. SIs were characterized by FTIR and XPS to corroborate the grafting of 2-bromoisobutyryl and determine its abundance. X-ray diffraction anal. indicated retained crystal morphol. with decreased MCC crystallinity. FTIR, thermogravimetric, and elemental analyses confirmed the grafting of MCC with polymers and revealed their composition PS and PLMA had a minor effect on the crystallinity and morphol. of MCC microfibers, whereas grafting PDM decreased the crystallinity of cellulose and the particle size. MCC grafted with polymers were tested as adsorbents of BPA by measuring the equilibrium uptake and removal through column filtration. PDM was found to endow cellulose with superior capacity of removing BPA, which was enhanced with increased amount of grafted polymer. A comparison of MCC grafted with PDM with activated carbon as adsorbents of BPA suggested the superior performance of the developed materials based on the largest maximum uptake.

Water, Air, & Soil Pollution published new progress about Acylation. 142-90-5 belongs to class esters-buliding-blocks, name is Dodecyl 2-methylacrylate, and the molecular formula is C16H30O2, Recommanded Product: Dodecyl 2-methylacrylate.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Ait Khouya, Ahmed’s team published research in Chemical Communications (Cambridge, United Kingdom) in 2019 | CAS: 140-11-4

Chemical Communications (Cambridge, United Kingdom) published new progress about Acylation. 140-11-4 belongs to class esters-buliding-blocks, name is Benzyl acetate, and the molecular formula is C9H10O2, Safety of Benzyl acetate.

Ait Khouya, Ahmed published the artcileCoating of polydopamine on polyurethane open cell foams to design soft structured supports for molecular catalysts, Safety of Benzyl acetate, the main research area is polyurethane open cell foam polydopamine coating catalyst support.

Polydopamine-coated polyurethane open cell foams are used as structured supports for mol. catalysts through the covalent anchoring of alkoxysilyl arms by the catechol groups of the mussel-inspired layer. This strong bonding prevents their leaching. No alteration of the mech. properties of the flexible support is observed after repeated uses of the catalytic materials.

Chemical Communications (Cambridge, United Kingdom) published new progress about Acylation. 140-11-4 belongs to class esters-buliding-blocks, name is Benzyl acetate, and the molecular formula is C9H10O2, Safety of Benzyl acetate.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Behera, Satyaranjan’s team published research in Applied Catalysis, A: General in 2021-08-05 | CAS: 140-11-4

Applied Catalysis, A: General published new progress about Acylation. 140-11-4 belongs to class esters-buliding-blocks, name is Benzyl acetate, and the molecular formula is C9H10O2, Application In Synthesis of 140-11-4.

Behera, Satyaranjan published the artcileAn efficient, economical and eco-friendly acylation of alcohols and amines by alum doped nanopolyaniline under solvent-free condition, Application In Synthesis of 140-11-4, the main research area is alum nanopolyaniline catalyst alc amine acylation.

We report acylation of alcs. and amines employing acetic acid as an acylating agent in solvent-free condition by using alum doped nanopolyaniline (NDPANI) as a catalyst. This environmentally benign method does not use corrosive acid anhydrides and acid chlorides for acylation and does not produce waste product. Also, a non-toxic potash alum was used for doping of polyaniline rather than corrosive acids. The reaction conditions represent an advance over established method not only in omitting the need for expensive catalysts or solvents but also in shortening the reaction time significantly. The advantages of this catalyst are non-hazardous, cheap, reusable, easy to prepare and handling.

Applied Catalysis, A: General published new progress about Acylation. 140-11-4 belongs to class esters-buliding-blocks, name is Benzyl acetate, and the molecular formula is C9H10O2, Application In Synthesis of 140-11-4.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Takemoto, Kohei’s team published research in Organic Letters in 2019-09-20 | CAS: 5405-41-4

Organic Letters published new progress about Acylation. 5405-41-4 belongs to class esters-buliding-blocks, name is Ethyl 3-hydroxybutanoate, and the molecular formula is C6H12O3, Related Products of esters-buliding-blocks.

Takemoto, Kohei published the artcileSite-selective esterifications of polyol β-hydroxyamides and applications to serine-selective glycopeptide modifications, Related Products of esters-buliding-blocks, the main research area is glycopeptide synthesis serine sugar steric hindrance; hydroxyamide polyol esterification hydroxyl group acylation.

The site-selective acylations of β-hydroxyamides in the presence of other hydroxyl groups are described. Central to the success of this modification is the metal-template-driven acylation using pyridine ketoxime esters as acylating reagents in combination with CuOTf. This strategy enables β-hydroxyl groups to be site-selectively acylated in various derivatives, including sterically hindered secondary β-alc. The utility of this methodol. is showcased by the serine-selective modification of a glycopeptide with unprotected sugar.

Organic Letters published new progress about Acylation. 5405-41-4 belongs to class esters-buliding-blocks, name is Ethyl 3-hydroxybutanoate, and the molecular formula is C6H12O3, Related Products of esters-buliding-blocks.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Scheiger, Johannes M.’s team published research in Advanced Functional Materials in 2021-12-02 | CAS: 142-90-5

Advanced Functional Materials published new progress about Actuators. 142-90-5 belongs to class esters-buliding-blocks, name is Dodecyl 2-methylacrylate, and the molecular formula is C16H30O2, Recommanded Product: Dodecyl 2-methylacrylate.

Scheiger, Johannes M. published the artcileInherently UV Photodegradable Poly(methacrylate) Gels, Recommanded Product: Dodecyl 2-methylacrylate, the main research area is acrylic polymer photodegradable gel.

Organogels (hydrophobic polymer gels) are soft materials based on polymeric networks swollen in organic solvents. They are hydrophobic and possess a high content of solvent and low surface adhesion, rendering them interesting in applications such as encapsulants, drug delivery, actuators, slippery surfaces (self-cleaning, anti-waxing, anti-bacterial), or for oil-water separation To design functional organogels, strategies to control their shape and surface structure are required. Herein, the inherent UV photodegradability of poly(methacrylate) organogels is reported. No addnl. photosensitizers are required to efficiently degrade organogels on the minute scale. A low UV absorbance and a high swelling ability of the solvent infusing the organogel are found to be beneficial for fast photodegradation, which is expected to be transferrable to other gel photochem. Organogel arrays, films, and structured organogel surfaces are prepared, and their extraction ability and slippery properties are examined Films of inherently photodegradable organogels on copper circuit boards serve as the first ever pos. gel photoresist. Spatially photodegraded organogel films protect or reveal copper surfaces against an etchant (FeCl3 aqueous).

Advanced Functional Materials published new progress about Actuators. 142-90-5 belongs to class esters-buliding-blocks, name is Dodecyl 2-methylacrylate, and the molecular formula is C16H30O2, Recommanded Product: Dodecyl 2-methylacrylate.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Liao, Yinfei’s team published research in Fuel in 2022-08-01 | CAS: 106-32-1

Fuel published new progress about Actuators. 106-32-1 belongs to class esters-buliding-blocks, name is Ethyl octanoate, and the molecular formula is C10H20O2, Recommanded Product: Ethyl octanoate.

Liao, Yinfei published the artcileAlkanes-esters mixed collector enhanced low rank coal flotation: Interfacial interaction between oil drop and coal particle, Recommanded Product: Ethyl octanoate, the main research area is coal particle rank flotation interfacial interaction oil drop.

The interaction between oil collector drop and coal particle is important for low-rank coal (LRC) flotation. This paper investigated such interactions using dodecane (D), Et esters (E) and dodecane-esters mixed collector (MC). Measurements of oil drop-coal induction time and detachment force were conducted at a mesoscopic scale. The micro adsorption mechanism of oil collectors was revealed by wetting heats and FTIR measurements. Flotation results showed MC, especially dodecane-Et laurate, obtained high yield and low ash clean coal. There was a shorter induction time and higher adhesion strength between LRC particle and MC drop. The wetting heat of MC was greater than the sum of wetting heat of the two single collectors. FTIR anal. indicated that D validly adsorbed to the Me or aromatic groups, and E bonded with the oxygen-containing groups. The macro flotation results was well interpreted by the interfacial interaction of collector-coal at the mesoscopic and micro scales.

Fuel published new progress about Actuators. 106-32-1 belongs to class esters-buliding-blocks, name is Ethyl octanoate, and the molecular formula is C10H20O2, Recommanded Product: Ethyl octanoate.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Roggatz, Christina C.’s team published research in Journal of Chemical Ecology in 2022-04-30 | CAS: 929-77-1

Journal of Chemical Ecology published new progress about Acid rain. 929-77-1 belongs to class esters-buliding-blocks, name is Methyl docosanoate, and the molecular formula is C23H46O2, Application of Methyl docosanoate.

Roggatz, Christina C. published the artcileModelling Antifouling compounds of Macroalgal Holobionts in Current and Future pH Conditions, Application of Methyl docosanoate, the main research area is pH ocean acidification antifouling compound Rhodophyta Chlorophyta; Macroalgae; and macro-colonizers; antifouling; chemical communication; climate change; micro; ocean acidification.

Marine macroalgae are important ecosystem engineers in marine coastal habitats. Macroalgae can be neg. impacted through excessive colonization by harmful bacteria, fungi, microalgae, and macro-colonisers and thus employ a range of chem. compounds to minimize such colonization. Recent research suggests that environmental pH conditions potentially impact the functionality of such chem. compounds Here we predict if and how naturally fluctuating pH conditions and future conditions caused by ocean acidification will affect macroalgal (antifouling) compounds and thereby potentially alter the chem. defense mediated by these compounds We defined the relevant ecol. pH range, analyzed and scored the pH-sensitivity of compounds with antifouling functions based on their modelled chem. properties before assessing their distribution across the phylogenetic macroalgal groups, and the proportion of sensitive compounds for each investigated function. For some key compounds, we also predicted in detail how the associated ecol. function may develop across the pH range. The majority of compounds were unaffected by pH, but compounds containing phenolic and amine groups were found to be particularly sensitive to pH. Future pH changes due to predicted average open ocean acidification pH were found to have little effect. Compounds from Rhodophyta were mainly pH-stable. However, key algal species amongst Phaeophyceae and Chlorophyta were found to rely on highly pH-sensitive compounds for their chem. defense against harmful bacteria, microalgae, fungi, and biofouling by macro-organisms. All quorum sensing disruptive compounds were found the be unaffected by pH, but the other ecol. functions were all conveyed in part by pH-sensitive compounds For some ecol. keystone species, all of their compounds mediating defense functions were found to be pH-sensitive based on our calculations, which may not only affect the health and fitness of the host alga resulting in host breakdown but also alter the associated ecol. interactions of the macroalgal holobiont with micro and macrocolonisers, eventually causing ecosystem restructuring and the functions (e.g. habitat provision) provided by macroalgal hosts. Our study investigates a question of fundamental importance because environments with fluctuating or changing pH are common and apply not only to coastal marine habitats and estuaries but also to freshwater environments or terrestrial systems that are subject to acid rain. Hence, while warranting exptl. validation, this investigation with macroalgae as model organisms can serve as a basis for future investigations in other aquatic or even terrestrial systems.

Journal of Chemical Ecology published new progress about Acid rain. 929-77-1 belongs to class esters-buliding-blocks, name is Methyl docosanoate, and the molecular formula is C23H46O2, Application of Methyl docosanoate.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Yun, Wan-Chu’s team published research in Journal of Colloid and Interface Science in 2019-05-01 | CAS: 539-88-8

Journal of Colloid and Interface Science published new progress about IR spectra. 539-88-8 belongs to class esters-buliding-blocks, name is Ethyl 4-oxopentanoate, and the molecular formula is C7H12O3, Recommanded Product: Ethyl 4-oxopentanoate.

Yun, Wan-Chu published the artcileWater-born zirconium-based metal organic frameworks as green and effective catalysts for catalytic transfer hydrogenation of levulinic acid to γ-valerolactone: Critical roles of modulators, Recommanded Product: Ethyl 4-oxopentanoate, the main research area is zirconium MOF levulinic acid valerolactone transfer hydrogenation catalyst; Levulinic acid; MOF-801; Modulators; Zr fumarate; γ-valerolactone.

While zirconium (Zr)-based metal organic frameworks (MOFs) are promising for conversion of levulinic acid (LA) to γ-valerolactone (GVL) through catalytic transform hydrogenation (CTH), these reported Zr MOFs for LA conversion must be synthesized in toxic DMF (DMF). From the viewpoint of sustainability, it is preferable to avoid usage of DMF-based solvents to prepare these Zr MOFs. As water is a green solvent, the aim of this study is to develop and investigate Zr MOFs, which are prepared in water, for LA conversion to GVL. Specifically, monocarboxylic acids (e.g., formic acid, acetic acid and propanoic acid) are employed as modulators during the preparation of water-born ZrF. The role of modulators is extremely important for the well-developed formation of water-born ZrF. In addition, different monocarboxylic acid modulators also significantly influence the morphol. of water-born ZrF; nevertheless, their crystalline structures and acidities are equivalent As for LA conversion, these water-born modulated ZrF MOFs are validated to successfully convert LA to GVL. Especially, the formic acid-modulated ZrF can exhibit LA conversion = 96%, selectivity for GVL = 98% and yield of GVL = 98%. These water-born modulated ZrF also exhibit even higher catalytic activities than the typical DMF-based ZrF and reported Zr-based MOFs in LA conversion to GVL. These water-born ZrF could be also reused even without regeneration for multiple cyclic LA conversion. These results and findings prove that the water-born ZrF is not only environmentally benign but also more effective for LA conversion to GVL.

Journal of Colloid and Interface Science published new progress about IR spectra. 539-88-8 belongs to class esters-buliding-blocks, name is Ethyl 4-oxopentanoate, and the molecular formula is C7H12O3, Recommanded Product: Ethyl 4-oxopentanoate.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics