Kurkiewicz, S.’s team published research in Pharmazie in 2020 | CAS: 539-88-8

Pharmazie published new progress about Impatiens. 539-88-8 belongs to class esters-buliding-blocks, name is Ethyl 4-oxopentanoate, and the molecular formula is C7H12O3, SDS of cas: 539-88-8.

Kurkiewicz, S. published the artcileContemporary analytical techniques reveal the secret composition of a 19th century Jerusalem Balsam, SDS of cas: 539-88-8, the main research area is vanillic acid Impatiens volatile compound.

In 1719, Antonio Menzani di Cuna from the Saint Savior monastery published an alc. extract formula made from plant and herb resins under the name Jerusalem Balsam. The Balsam gained high popularity due to its remedial benefits. At the end of the 19th century, Jerusalem Balsam produced by the hermit Johannes Treutler was found to be particularly popular. We analyzed a sample of a valuable find coming from the last decade of the 19th century, making it probably the oldest surviving Jerusalem Balsam in the world. The purpose of this work was to investigate the composition of the historical sample and to try to determine the origin of its components. This was achieved by comparing the profile of volatile compounds extracted from the balsam using HS-SPME technique with the profile characteristic for plant resins as classic ingredients of the Johannes Treutler formula. The use of two chromatog. columns of different polarity, as well as the transformation of the polar components of the sample into TMS derivatives, allowed to obtain new information on the historical composition of the Balsam. Also, it can be stated with high probability that plant resins were indeed used in the production of the Balsam as referred to in the original recipe of Johannes Treutler. We also discuss challenges in determining the original composition of the Balsam.

Pharmazie published new progress about Impatiens. 539-88-8 belongs to class esters-buliding-blocks, name is Ethyl 4-oxopentanoate, and the molecular formula is C7H12O3, SDS of cas: 539-88-8.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Kurkiewicz, S.’s team published research in Pharmazie in 2020 | CAS: 123-29-5

Pharmazie published new progress about Impatiens. 123-29-5 belongs to class esters-buliding-blocks, name is Ethyl nonanoate, and the molecular formula is C11H22O2, Name: Ethyl nonanoate.

Kurkiewicz, S. published the artcileContemporary analytical techniques reveal the secret composition of a 19th century Jerusalem Balsam, Name: Ethyl nonanoate, the main research area is vanillic acid Impatiens volatile compound.

In 1719, Antonio Menzani di Cuna from the Saint Savior monastery published an alc. extract formula made from plant and herb resins under the name Jerusalem Balsam. The Balsam gained high popularity due to its remedial benefits. At the end of the 19th century, Jerusalem Balsam produced by the hermit Johannes Treutler was found to be particularly popular. We analyzed a sample of a valuable find coming from the last decade of the 19th century, making it probably the oldest surviving Jerusalem Balsam in the world. The purpose of this work was to investigate the composition of the historical sample and to try to determine the origin of its components. This was achieved by comparing the profile of volatile compounds extracted from the balsam using HS-SPME technique with the profile characteristic for plant resins as classic ingredients of the Johannes Treutler formula. The use of two chromatog. columns of different polarity, as well as the transformation of the polar components of the sample into TMS derivatives, allowed to obtain new information on the historical composition of the Balsam. Also, it can be stated with high probability that plant resins were indeed used in the production of the Balsam as referred to in the original recipe of Johannes Treutler. We also discuss challenges in determining the original composition of the Balsam.

Pharmazie published new progress about Impatiens. 123-29-5 belongs to class esters-buliding-blocks, name is Ethyl nonanoate, and the molecular formula is C11H22O2, Name: Ethyl nonanoate.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Kurkiewicz, S.’s team published research in Pharmazie in 2020 | CAS: 623-50-7

Pharmazie published new progress about Impatiens. 623-50-7 belongs to class esters-buliding-blocks, name is Ethyl 2-hydroxyacetate, and the molecular formula is C4H8O3, Formula: C4H8O3.

Kurkiewicz, S. published the artcileContemporary analytical techniques reveal the secret composition of a 19th century Jerusalem Balsam, Formula: C4H8O3, the main research area is vanillic acid Impatiens volatile compound.

In 1719, Antonio Menzani di Cuna from the Saint Savior monastery published an alc. extract formula made from plant and herb resins under the name Jerusalem Balsam. The Balsam gained high popularity due to its remedial benefits. At the end of the 19th century, Jerusalem Balsam produced by the hermit Johannes Treutler was found to be particularly popular. We analyzed a sample of a valuable find coming from the last decade of the 19th century, making it probably the oldest surviving Jerusalem Balsam in the world. The purpose of this work was to investigate the composition of the historical sample and to try to determine the origin of its components. This was achieved by comparing the profile of volatile compounds extracted from the balsam using HS-SPME technique with the profile characteristic for plant resins as classic ingredients of the Johannes Treutler formula. The use of two chromatog. columns of different polarity, as well as the transformation of the polar components of the sample into TMS derivatives, allowed to obtain new information on the historical composition of the Balsam. Also, it can be stated with high probability that plant resins were indeed used in the production of the Balsam as referred to in the original recipe of Johannes Treutler. We also discuss challenges in determining the original composition of the Balsam.

Pharmazie published new progress about Impatiens. 623-50-7 belongs to class esters-buliding-blocks, name is Ethyl 2-hydroxyacetate, and the molecular formula is C4H8O3, Formula: C4H8O3.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Pan, Shenxin’s team published research in Macromolecular Materials and Engineering in 2019 | CAS: 142-90-5

Macromolecular Materials and Engineering published new progress about Hydrogels. 142-90-5 belongs to class esters-buliding-blocks, name is Dodecyl 2-methylacrylate, and the molecular formula is C16H30O2, Application In Synthesis of 142-90-5.

Pan, Shenxin published the artcileHigh-Strength, Rapidly Self-Recoverable, and Antifatigue Nano-SiO2/Poly(Acrylamide-Lauryl Methacrylate) Composite Hydrogels, Application In Synthesis of 142-90-5, the main research area is self recoverable antifatigue acrylic polymer composite hydrogel silica strength.

Creating load-bearing hydrogels with superior mech. strength and toughness is of vital importance for promoting the development of polymer hydrogels toward practical applications. Herein, a type of composite hydrogel is facilely fabricated employing simple and effective UV irradiation one-pot method by introducing cheap and available nanosilica sol into hydrophobic association poly(acrylamide-lauryl methacrylate) (HAPAM gels). Composite hydrogels exhibit enhanced mech. strength (compression stress reaching 4.4 MPa) and toughness (compression hysteresis energy achieved is 151.15 kJ m-3) compared to HAPAM gels. Composite hydrogels also demonstrate rapid self-recovery behavior (95.91% stress recovery and 92.19% hysteresis energy recovery after restoration for 15 min, resp.) and favorable fatigue-resistant ability without the help of external stimuli at room temperature based on the cyclic loading-unloading compression measurements. The simple and effective design strategy may help the development of hydrogel materials toward practical applications for soft sensors, tissue engineering, and actuators.

Macromolecular Materials and Engineering published new progress about Hydrogels. 142-90-5 belongs to class esters-buliding-blocks, name is Dodecyl 2-methylacrylate, and the molecular formula is C16H30O2, Application In Synthesis of 142-90-5.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Belal, Babita’s team published research in Pharma Innovation in 2019 | CAS: 929-77-1

Pharma Innovation published new progress about Genotypes. 929-77-1 belongs to class esters-buliding-blocks, name is Methyl docosanoate, and the molecular formula is C23H46O2, Synthetic Route of 929-77-1.

Belal, Babita published the artcileAltitudinal variations in chemical profile and antioxidant activities of lentil (Lens culinaris Medik.) genotypes, Synthetic Route of 929-77-1, the main research area is Lens phytoconstituent antioxidant activity genotype.

The present investigation was carried out to evaluate the altitudinal variation between two lentil (Lens culinaris Medik.) genotypes on the basis of their chem. profile, total phenolic content and antioxidant activitiy. Pulse samples were collected from two different altitudes of Uttarakhand state. The chem. profiling was done via Gas chromatog.-Mass spectrometry anal. A total of 45 and 33 phytoconstituents accounting for 76.51% and 81.03% of the total extract has been identified in the sample from lower altitude and higher altitude resp. Antioxidant activity was determined in terms of 2, 2-diphenyl-1-picrylhydrazyl (DPPH) radical scavenging, hydroxyl radical scavenging and metal chelating assays. Results revealed that the genotype from higher altitude exhibits higher antioxidant potential than the genotype from lower altitude. A significant pos. correlation has been observed between altitude and total phenolic content, whereas a significant neg. correlation between altitude and 50% inhibitory concentration (IC50) of both genotypes.

Pharma Innovation published new progress about Genotypes. 929-77-1 belongs to class esters-buliding-blocks, name is Methyl docosanoate, and the molecular formula is C23H46O2, Synthetic Route of 929-77-1.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Zhou, Chengzhe’s team published research in Postharvest Biology and Technology in 2022-01-31 | CAS: 140-11-4

Postharvest Biology and Technology published new progress about Flowering. 140-11-4 belongs to class esters-buliding-blocks, name is Benzyl acetate, and the molecular formula is C9H10O2, COA of Formula: C9H10O2.

Zhou, Chengzhe published the artcileIntegrated volatile metabolome, multi-flux full-length sequencing, and transcriptome analyses provide insights into the aroma formation of postharvest jasmine (Jasminum sambac) during flowering, COA of Formula: C9H10O2, the main research area is Jasminum sambac volatile metabolome transcriptome aroma formation flowering.

Jasmine [Jasminum sambac (L.) Aiton] flowers usually bloom and release their fragrance at night. However, the underlying regulatory mechanisms of aroma formation during flowering in postharvest jasmine are still poorly understood. Here, we profiled the volatile metabolome, multi-flux full-length sequencing, and transcriptome anal. to investigate volatile biosynthesis and global transcriptomic changes in postharvest flowering jasmine. A total of 102 volatiles were identified. Of these, 16 volatiles were considered key odorants of jasmine flowers. Linalool, a-farnesene, D-nerolidol, geraniol, α-cadinol, benyzl alc., benzaldehyde, benzyl acetate, benzyl benzoate, 3-hexen-1-ol benzoate, and (Z)-3-hexen-1-ol acetate play decisive roles in the typical jasmine fragrance, while benzeneacetaldehyde, benzoic acid, Me anthranilate, Me 2-(methylamino) benzoate, and (E)-2-hexenal modify the aroma of jasmine. Meanwhile, we built the first reference full-length transcriptome of postharvest jasmine flowers, which had 366,081 non-redundant isoforms. Among them, 280,326 (76.57%) were annotated with at least one hit in the NT, NR, Swissprot, KEGG, KOG, Pfam, and GO databases. Combined with second-generation transcriptome anal., we identified 52 differentially expressed transcripts (DETs) involved in terpenoid metabolic pathways and 28 DETs involved in phenylpropanoid/benzenoid metabolic pathway, and 31 β-glucosidase transcripts may be related to aroma formation of postharvest jasmine during flowering. In addition, the expression of 42 heat shock protein (HSP) transcripts was pos. correlated with the content of 11 key odorants, as revealed by weighted gene co-expression network anal. (WGCNA). The present results advance the knowledge of the regulatory mechanism of aroma formation in postharvest jasmine during flowering and provide an abundant genetic resource for further studies on gene discovery in jasmine.

Postharvest Biology and Technology published new progress about Flowering. 140-11-4 belongs to class esters-buliding-blocks, name is Benzyl acetate, and the molecular formula is C9H10O2, COA of Formula: C9H10O2.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Son, Yeongkwon’s team published research in Chemical Research in Toxicology in 2019-06-17 | CAS: 140-11-4

Chemical Research in Toxicology published new progress about E-liquids. 140-11-4 belongs to class esters-buliding-blocks, name is Benzyl acetate, and the molecular formula is C9H10O2, SDS of cas: 140-11-4.

Son, Yeongkwon published the artcileHydroxyl Radicals in E-Cigarette Vapor and E-Vapor Oxidative Potentials under Different Vaping Patterns, SDS of cas: 140-11-4, the main research area is hydroxyl radical E cigarette vapor oxidative stress vaping flavor.

Available studies, while limited in number, suggest that e-cigarette vaping induces oxidative stress, with one potential mechanism being the direct formation of reactive oxygen species (ROS) in e-vapor. In the present studies, we measured the formation of hydroxyl radical (•OH), the most destructive ROS, in e-vapor under a range of vaping patterns (i.e., power settings, solvent concentrations, flavorings). Study results show that increased power output and puff volume correspond with the formation of significantly higher amounts of •OH in e-vapor because of elevated coil temperature and oxygen supply. Vegetable glycerin (VG) e-liquids generated higher •OH levels than propylene glycol (PG) e-liquids, as did flavored e-liquids relative to nonflavored e-liquids E-vapor in combination with ascorbic acid, which is an abundant biol. mol. in human epithelial lining fluid, can also induce •OH formation. The dose of radical per puff associated with e-cigarette vaping was 10-1000 times lower than the reported dose generated by cigarette smoking. However, the daily average •OH dose can be comparable to that from cigarette smoking depending on vaping patterns. Overall, e-cigarette users who use VG-based flavored e-cigarettes at higher power output settings may be at increased risk for •OH exposures and related health consequences such as asthma and chronic obstructive pulmonary disease.

Chemical Research in Toxicology published new progress about E-liquids. 140-11-4 belongs to class esters-buliding-blocks, name is Benzyl acetate, and the molecular formula is C9H10O2, SDS of cas: 140-11-4.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Verhagen, Rory’s team published research in Chemosphere in 2019-05-31 | CAS: 71617-10-2

Chemosphere published new progress about Diffusion. 71617-10-2 belongs to class esters-buliding-blocks, name is Isopentyl 3-(4-methoxyphenyl)acrylate, and the molecular formula is C15H20O3, Application In Synthesis of 71617-10-2.

Verhagen, Rory published the artcileCalibration parameters for the passive sampling of organic UV filters by silicone; diffusion coefficients and silicone-water partition coefficients, Application In Synthesis of 71617-10-2, the main research area is organic UV filter passive sampling silicone water partition coefficient; Diffusion coefficient; Organic UV filters; Partition coefficient; Passive sampling; Single dose design.

In recent years, organic UV filters (UVFs) received considerable attention as a group of emerging contaminants, including in Australia where the use of UVFs is particularly relevant. Passive sampling using polymers has become widely used for routine monitoring of chems. in the aquatic environment. Application of passive samplers for monitoring chems. in the water relies on calibration data such as chem.’s polymer-water partition coefficient (Kpw) and diffusion coefficients in the sampling material (Dp), for understanding uptake and kinetic limitations. In the present study, Kpw and Dp for nine UVFs were estimated Kpw values were determined in different water – polymer partition experiments where (1) a given mass of chems. was dosed into the water and (2) into the polymer. Diffusion coefficients were determined using the stacking method. The estimated log Kpw and log Dp ranged from 2.9 to 6.4 L kg-1 and -11.1 to -10.5 m2s-1, resp. The sufficient high Dp allows application of kinetic models that only consider water boundary-controlled uptake for converting silicone sampler uptake into an aqueous phase concentration using the presented Kpw.

Chemosphere published new progress about Diffusion. 71617-10-2 belongs to class esters-buliding-blocks, name is Isopentyl 3-(4-methoxyphenyl)acrylate, and the molecular formula is C15H20O3, Application In Synthesis of 71617-10-2.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Blanco-Zubiaguirre, L.’s team published research in Talanta in 2020-02-01 | CAS: 71617-10-2

Talanta published new progress about Diffusion. 71617-10-2 belongs to class esters-buliding-blocks, name is Isopentyl 3-(4-methoxyphenyl)acrylate, and the molecular formula is C15H20O3, Computed Properties of 71617-10-2.

Blanco-Zubiaguirre, L. published the artcileTarget and suspect screening of substances liable to migrate from food contact paper and cardboard materials using liquid chromatography-high resolution tandem mass spectrometry, Computed Properties of 71617-10-2, the main research area is food contact paper cardboard substance migration LC HRMS; Food contact paper and board materials; Liquid chromatography-high resolution mass spectrometry; Migration; Quantitative target analysis; Suspect screening; Tenax®.

This work describes the anal. of both target and non-target compounds in paper and cardboard materials together with the characterization of their migration to Tenax by means of liquid chromatog. coupled to both low (LC-QqQ) and high resolution tandem mass spectrometry (LC-q-Orbitrap), resp. To this aim, an entire anal. procedure was fully developed and validated for both matrixes: paper/cardboard and Tenax. A total of 97 chems., including photoinitiators, phthalates, biocides, antioxidants, etc., listed by the European Regulation, were found in the materials under study together with other substances not included in this list. Moreover, the majority of annotated substances were present in the simulant, giving evidence of their migration capacity. Migration percentages of 10 photoinitiators, 4 phthalates, bisphenol A, bis-(2-ethylhexyl) adipate, acetyltributyl citrate and caprolactam to Tenax were quantified. Despite not exceeding the established specific migration limit (SML) in any case, benzophenone, 4-phenylbenzophenone and bisphenol A concentrations in some paper and cardboard materials were very close to the SML values established by the EU legislation.

Talanta published new progress about Diffusion. 71617-10-2 belongs to class esters-buliding-blocks, name is Isopentyl 3-(4-methoxyphenyl)acrylate, and the molecular formula is C15H20O3, Computed Properties of 71617-10-2.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Li, Miaosi’s team published research in Journal of Colloid and Interface Science in 2019-05-01 | CAS: 142-90-5

Journal of Colloid and Interface Science published new progress about Diffusion. 142-90-5 belongs to class esters-buliding-blocks, name is Dodecyl 2-methylacrylate, and the molecular formula is C16H30O2, Recommanded Product: Dodecyl 2-methylacrylate.

Li, Miaosi published the artcileControlled addition of new liquid component into surface droplet arrays by solvent exchange, Recommanded Product: Dodecyl 2-methylacrylate, the main research area is drop swelling diffusion size; Droplet arrays; Microlens; Multicomponent; Solvent exchange; Surface gradient.

Microscopic droplets integrating multiple functionalities are essential in the microcompartmentalized related reaction and applications. Solvent exchange is a simple approach for producing femtoliter surface droplets by the transit oversaturation created at the mixing front of a solution by a poor solvent. But it remains challenging to control the compositions in nanodroplets. Our hypothesis is the new liquid component can be added to the pre-formed surface droplets at certain ratios controlled by solvent exchange. In this work we investigate the growth of the droplets during addition of a new component by solvent exchange. Two-component droplets were formed on a microdomain patterned substrate as highly ordered arrays. The phys. and chem. parameters that control droplet composition and a possible application of the binary droplet arrays were presented in this work. The added amount of the second component in the binary droplet can be quant. controlled by the solution and flow conditions. The theor. prediction of the component ratio based on the droplet diffusive growth dynamics mode shows a good agreement with the exptl. results. The results show that the solvent exchange on the surface with pre-formed droplets provides a highly efficient method to tune the droplet compositions to desired ratio. The unique feature of this approach enables a gradient structure of droplet composition over the surface, demonstrated by an application of different microlens performance on a surface.

Journal of Colloid and Interface Science published new progress about Diffusion. 142-90-5 belongs to class esters-buliding-blocks, name is Dodecyl 2-methylacrylate, and the molecular formula is C16H30O2, Recommanded Product: Dodecyl 2-methylacrylate.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics