Category: 99-27-4

Authors Panigrahi, A; Sahu, BP; Mandani, S; Nayak, D; Giri, S; Sarma, TK in ELSEVIER SCIENCE SA published article about AGGREGATION-INDUCED EMISSION; CONJUGATED POLYMER NANOPARTICLES; INTRAMOLECULAR EXCIMER FORMATION; LIGHT-UP PROBE; PICRIC ACID; TUNABLE EMISSION; TETRAPHENYLETHYLENE; EFFICIENCY; SENSORS; SIZE in [Panigrahi, Abhiram; Mandani, Sonam; Sarma, Tridib K.] Indian Inst Technol Indore, Discipline Chem, Khandwa Rd, Indore 453552, Madhya Pradesh, India; [Sahu, Basanta P.; Nayak, Debasis] Indian Inst Technol Indore, Ctr Biosci & Biomed Engn, Khandwa Rd, Indore 453552, Madhya Pradesh, India; [Giri, Santanab] Haldia Inst Technol, Sch Appl Sci & Humanities, Haldia 721657, India in 2019, Cited 66. Name: Dimethyl 5-aminoisophthalate. The Name is Dimethyl 5-aminoisophthalate. Through research, I have a further understanding and discovery of 99-27-4

Development of organic nanoparticles with high fluorescence, good biocompatibility along with strong resistance to photobleaching through simple synthetic routes is important for diverse applications such as sensing and bioimaging. Herein, we present the development of a pyrene excimer nanoaggregate which shows aggregation induced emission (AIE) effect in a solvent mixture of THE and water. The pyrene based fluorescent probe, dimethyl-5-(pyren-1-ylmethyleneamino)isophthalate (5-DP) was synthesized through a simple single step condensation reaction from inexpensive reagents. The photophysical studies of nanoaggregated system further corroborates the AIE active behavior of 5-DP probe at different water fractions (f(w) = 0% to 90%), where the hydrogen bonding interaction between imine and water molecules led to suppression of photoinduced electron transfer (PET) inducing significant enhancement in fluorescence. The highly photostable nanoaggregates were explored as a selective fluorescence turn off sensor for phenolic nitroaromatics and the chemo-selectivity was highly pronounced for 2,4,6-trinitrophenol (picric acid), that showed efficient quenching in aqueous as well as solid phase, with a detection limit of 10 nM in aqueous medium. The quenching efficiency of the nanoaggregates can be ascribed to a combination of factors including efficient fluorescence resonance energy transfer, inner filter effect and coulombic interaction between picric acid and the aggregated probe molecules. Further, random aggregation of the pyrene derivative could be controlled for the formation of fluorescent spherical nanoparticles using Pluoronics P-123 block copolymers as encapsulating agents. The resulting composite could be used as a neoteric cell imaging probe with significantly less cytotoxicity, thus showing their potential biological applications.

Name: Dimethyl 5-aminoisophthalate. About Dimethyl 5-aminoisophthalate, If you have any questions, you can contact Panigrahi, A; Sahu, BP; Mandani, S; Nayak, D; Giri, S; Sarma, TK or concate me.

Reference:
Patent; ASTRA ZENECA AB; NPS PHARMACEUTICALS, INC.; WO2004/14881; (2004); A2;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

COA of Formula: C10H11NO4. In 2019 FRONT CHEM published article about ACID; CATALYSIS; MOFS in [Karmakar, Anirban; Paul, Anup; Rubio, Guilherme M. D. M.; Soliman, Mohamed M. A.; Fatima, M.; Guedes da Silva, C.; Pombeiro, Armando J. L.] Univ Lisbon, Inst Super Tecn, Ctr Quim Estrutural, Lisbon, Portugal in 2019, Cited 31. The Name is Dimethyl 5-aminoisophthalate. Through research, I have a further understanding and discovery of 99-27-4.

A pyridine-based amide functionalized tetracarboxylic acid, 5,5 ‘-(pyridine-2, 6-dicarbonyl)bis(azanediyl)}diisophthalic acid (H4L), was synthesized and its coordination chemistry toward zinc(II) and cadmium(II) ions was studied. The reactions of H4L with Zn(NO3)(2).6H(2)O and Cd(NO3)(2).4H(2)O led to its full or partial deprotonation, respectively, and the formation of the 2D coordination polymers [Zn-2(L)(H2O)(4)](n).4n(H2O) (1) and [Cd-3(HL)(2)(DMF)(4)](n).4n(DMF) (2) (DMF = N,N’-dimethylformamide), respectively. They were characterized by elemental analysis, FT-IR, photoluminescence, thermogravimetry, and single-crystal and powder X-ray diffraction. In 1, the L4- ligand is planar with every carboxylate anion binding a Zn(II) cation and giving rise to a 2D grid with the metals with tetrahedral environments. In 2, the combination of bridging HL3- and dimethylformamide to form trinuclear Cd(II) clusters engenders secondary building block units and generates a layer-type 2D network with the metals with octahedral and pentagonal bipyramid coordination geometries. The topological analyses of 1 and 2 reveal 2,4-connected and 3,6-connected binodal nets, respectively. On account of the presence of Lewis acid (Zn or Cd centers) as well as basic (uncoordinated pyridine and amide groups) sites, 1 and (to a much lower extent) 2 effectively catalyze the one-pot cascade deacetalization-Knoevenagel condensation reactions under quite mild conditions. They act as heterogeneous catalysts, being easy to recover and recycle without losing activity.

COA of Formula: C10H11NO4. About Dimethyl 5-aminoisophthalate, If you have any questions, you can contact Karmakar, A; Paul, A; Rubio, GMDM; Soliman, MMA; Fatima, M; da Silva, CG; Pombeiro, AJL or concate me.

Reference:
Patent; ASTRA ZENECA AB; NPS PHARMACEUTICALS, INC.; WO2004/14881; (2004); A2;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

I found the field of Chemistry very interesting. Saw the article Facile Synthesis of Iron-Titanate Nanocomposite as a Sustainable Material for Selective Amination of Substitued Nitro-Arenes published in 2020. Product Details of 99-27-4, Reprint Addresses Sharif, M (corresponding author), King Fahd Univ Petr & Minerals, Dept Chem, Dhahran 31261, Saudi Arabia.. The CAS is 99-27-4. Through research, I have a further understanding and discovery of Dimethyl 5-aminoisophthalate

The fabrication of durable and low-cost nanostructured materials remains important in chemical, biologic and medicinal applications. Particularly, iron-based nanomaterials are of central importance due to the ‘noble’ features of iron such as its high abundance, low cost and non-toxicity. Herein we report a simple sol-gel method for the synthesis of novel iron-titanium nanocomposite-based material (Fe9TiO15@TiO2). In order to prepare this material, we made a polymeric gel using ferrocene, titanium isopropoxide and THF precursors. The calcination of this gel in air at 500 degrees C produced Fe-Ti bimetallic nanoparticles-based composite and nano-TiO(2)as support. Noteworthy, our methodology provides an excellent control over composition, size and shape of the resulting nanoparticles. The resulted Fe-based material provides a sustainable catalyst for selective synthesis of anilines, which are key intermediates for the synthesis of several chemicals, dyes and materials, via reduction of structurally diverse and functionalized nitroarenes.

Product Details of 99-27-4. About Dimethyl 5-aminoisophthalate, If you have any questions, you can contact Sohail, M; Tahir, N; Rubab, A; Beller, M; Sharif, M or concate me.

Reference:
Patent; ASTRA ZENECA AB; NPS PHARMACEUTICALS, INC.; WO2004/14881; (2004); A2;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

In 2021 TETRAHEDRON LETT published article about DIRECT ARYLATION; BOND; ACTIVATION; MILD; FUNCTIONALIZATION; ISOQUINOLINE; COPOLYMERS; ALKYNES; RH(III); OXIMES in [Zhang, Yuanfei; Chen, Zhe-Ning; Su, Weiping] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China; [Zhang, Yuanfei] Nanning Normal Univ, Guangxi Key Lab Nat Polymer Chem & Phys, Nanning 530001, Peoples R China in 2021, Cited 49. The Name is Dimethyl 5-aminoisophthalate. Through research, I have a further understanding and discovery of 99-27-4. Formula: C10H11NO4

A Rh(III)-catalyzed regioselective C-H nitrosation/annulation reaction of unsymmetrical azobenzenes with [NO][BF4] has been developed to achieve high-yielding syntheses of benzotriazole N-oxides with excellent functional group tolerance. Computational studies have revealed that this oxidative C-H functionalization reaction involves an interesting redox-neutral Rh(III)/Rh(III) pathway without the change of Rh oxidation state. (C) 2021 Elsevier Ltd. All rights reserved.

Formula: C10H11NO4. About Dimethyl 5-aminoisophthalate, If you have any questions, you can contact Zhang, YF; Chen, ZN; Su, WP or concate me.

Reference:
Patent; ASTRA ZENECA AB; NPS PHARMACEUTICALS, INC.; WO2004/14881; (2004); A2;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

An article Radical-Doped Metal-Organic Framework: Route to Nanoscale Defects and Magnetostructural Functionalities WOS:000474475800026 published article about ELECTRON-PARAMAGNETIC-RESONANCE; GAS-ADSORPTION; AEROBIC OXIDATION; CUPRIC IONS; DERIVATIVES; MIL-53; EPR; SPECTROSCOPY; BEHAVIOR; LINKER in [Poryvaev, Artem S.; Polyukhov, Daniil M.; Fedin, Matvey V.] RAS, SB, Int Tomog Ctr, Inst Skaya Str 3a, Novosibirsk 630090, Russia; [Gjuzi, Eva; Hoffmann, Frank; Froeba, Michael] Univ Hamburg, Inst Inorgan & Appl Chem, Martin Luther King Pl 6, D-20146 Hamburg, Germany; [Poryvaev, Artem S.; Fedin, Matvey V.] Novosibirsk State Univ, Pirogova Str 2, Novosibirsk 630090, Russia; [Polyukhov, Daniil M.] RAS, SB, NN Vorozhtsov Inst Organ Chem, Novosibirsk 630090, Russia in 2019, Cited 72. The Name is Dimethyl 5-aminoisophthalate. Through research, I have a further understanding and discovery of 99-27-4. Application In Synthesis of Dimethyl 5-aminoisophthalate

Nanosized structural defects in metal-organic frameworks (MOFs) attract growing attention and often remarkably enhance functional properties of these materials for various applications. In this work, a series of MOFs [Cu-2(TPTA)(1-x)(BDPBTR)(x)] (H(4)TPTA, [1,1′:3′,1 ”-terphenyl]-3,3 ”,5,5 ”-tetracarboxylic acid; H4BDPBTR, 1,3-bis(3,5,dicarboxyphenyl)-1,2,4-benzotriazin-4-yl radical)) with a new stable radical linker doped into the structure has been synthesized and investigated using Electron Paramagnetic Resonance (EPR). Mixed linkers H(4)TPTA and H4BDPBTR were used to bridge copper(II) paddle-wheel units into a porous framework, where H4BDPBTR is the close structural analogue of H(4)TPTA. MOFs with various x = 0-0.4 were investigated. EPR studies indicated that the radical linker binds to the copper(II) units differently compared to diamagnetic linker, resulting in the formation of nanosized structural defects. Moreover, remarkable kinetic phenomena were observed upon cooling of this MOF, where slow structural rearrangements and concomitant changes of magnetic interactions were induced. Thus, our findings demonstrate that doping of structurally mimicking radical linkers into MOFs represents an efficient approach for designing target nanosized defects and introducing new magnetostructural functionalities for a variety of applications.

About Dimethyl 5-aminoisophthalate, If you have any questions, you can contact Poryvaev, AS; Polyukhov, DM; Gjuzi, E; Hoffmann, F; Froba, M; Fedin, MV or concate me.. Application In Synthesis of Dimethyl 5-aminoisophthalate

Reference:
Patent; ASTRA ZENECA AB; NPS PHARMACEUTICALS, INC.; WO2004/14881; (2004); A2;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Application In Synthesis of Dimethyl 5-aminoisophthalate. In 2019 J MATER CHEM A published article about RETICULAR CHEMISTRY; KINETIC SEPARATION; EFFICIENT REMOVAL; PROPYNE; HYDROGENATION; SELECTIVITY; CAPACITY; STRATEGY; CATALYST; PROPANE in [Wu, Xue-Qian; Xie, Yabo; He, Tao; Zhang, Yong-Zheng; Kong, Xiang-Jing; Li, Jian-Rong] Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat, Dept Chem & Chem Engn, Coll Environm & Energy Engn, Beijing 100124, Peoples R China; [Liu, Jing-Hao; Yu, Jiamei] Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China in 2019, Cited 44. The Name is Dimethyl 5-aminoisophthalate. Through research, I have a further understanding and discovery of 99-27-4.

By integrating open metal sites, Lewis basic sites, and tortuous diffusion paths, a new metal-organic framework has been designed and synthesized, which exhibits high adsorption capacity and excellent selectivity for separating a C3H4/C3H6 mixture. Meanwhile, the molecular packing state, dynamic diffusion coefficient of gases within the framework, and binding interaction are studied by molecular simulations.

About Dimethyl 5-aminoisophthalate, If you have any questions, you can contact Wu, XQ; Xie, YB; Liu, JH; He, T; Zhang, YZ; Yu, JM; Kong, XJ; Li, JR or concate me.. Application In Synthesis of Dimethyl 5-aminoisophthalate

Reference:
Patent; ASTRA ZENECA AB; NPS PHARMACEUTICALS, INC.; WO2004/14881; (2004); A2;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Authors Panigrahi, A; Sahu, BP; Mandani, S; Nayak, D; Giri, S; Sarma, TK in ELSEVIER SCIENCE SA published article about AGGREGATION-INDUCED EMISSION; CONJUGATED POLYMER NANOPARTICLES; INTRAMOLECULAR EXCIMER FORMATION; LIGHT-UP PROBE; PICRIC ACID; TUNABLE EMISSION; TETRAPHENYLETHYLENE; EFFICIENCY; SENSORS; SIZE in [Panigrahi, Abhiram; Mandani, Sonam; Sarma, Tridib K.] Indian Inst Technol Indore, Discipline Chem, Khandwa Rd, Indore 453552, Madhya Pradesh, India; [Sahu, Basanta P.; Nayak, Debasis] Indian Inst Technol Indore, Ctr Biosci & Biomed Engn, Khandwa Rd, Indore 453552, Madhya Pradesh, India; [Giri, Santanab] Haldia Inst Technol, Sch Appl Sci & Humanities, Haldia 721657, India in 2019, Cited 66. Recommanded Product: Dimethyl 5-aminoisophthalate. The Name is Dimethyl 5-aminoisophthalate. Through research, I have a further understanding and discovery of 99-27-4

Development of organic nanoparticles with high fluorescence, good biocompatibility along with strong resistance to photobleaching through simple synthetic routes is important for diverse applications such as sensing and bioimaging. Herein, we present the development of a pyrene excimer nanoaggregate which shows aggregation induced emission (AIE) effect in a solvent mixture of THE and water. The pyrene based fluorescent probe, dimethyl-5-(pyren-1-ylmethyleneamino)isophthalate (5-DP) was synthesized through a simple single step condensation reaction from inexpensive reagents. The photophysical studies of nanoaggregated system further corroborates the AIE active behavior of 5-DP probe at different water fractions (f(w) = 0% to 90%), where the hydrogen bonding interaction between imine and water molecules led to suppression of photoinduced electron transfer (PET) inducing significant enhancement in fluorescence. The highly photostable nanoaggregates were explored as a selective fluorescence turn off sensor for phenolic nitroaromatics and the chemo-selectivity was highly pronounced for 2,4,6-trinitrophenol (picric acid), that showed efficient quenching in aqueous as well as solid phase, with a detection limit of 10 nM in aqueous medium. The quenching efficiency of the nanoaggregates can be ascribed to a combination of factors including efficient fluorescence resonance energy transfer, inner filter effect and coulombic interaction between picric acid and the aggregated probe molecules. Further, random aggregation of the pyrene derivative could be controlled for the formation of fluorescent spherical nanoparticles using Pluoronics P-123 block copolymers as encapsulating agents. The resulting composite could be used as a neoteric cell imaging probe with significantly less cytotoxicity, thus showing their potential biological applications.

Recommanded Product: Dimethyl 5-aminoisophthalate. About Dimethyl 5-aminoisophthalate, If you have any questions, you can contact Panigrahi, A; Sahu, BP; Mandani, S; Nayak, D; Giri, S; Sarma, TK or concate me.

Reference:
Patent; ASTRA ZENECA AB; NPS PHARMACEUTICALS, INC.; WO2004/14881; (2004); A2;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Application In Synthesis of Dimethyl 5-aminoisophthalate. Montes-Andres, H; Leo, P; Orcajo, G; Rodriguez-Dieguez, A; Choquesillo-Lazarte, D; Martos, C; Botas, JA; Calleja, G in [Montes-Andres, Helena; Orcajo, Gisela; Martos, Carmen; Angel Botas, Juan; Calleja, Guillermo] Rey Juan Carlos Univ, Dept Chem Energy & Mech Technol, Mostoles 28933, Spain; [Leo, Pedro] Rey Juan Carlos Univ, Dept Chem & Environm Technol, Mostoles 28933, Spain; [Rodriguez-Dieguez, Antonio] Univ Granada, Dept Inorgan Chem, Granada, Spain; [Choquesillo-Lazarte, Duane] Univ Granada, Lab Estudios Cristalograf, IACT, CSIC, Granada 18100, Spain published Synthesis, Structural Features, and Hydrogen Adsorption Properties of Three New Flexible Sulfur-Containing Metal-Organic Frameworks in 2020, Cited 62. The Name is Dimethyl 5-aminoisophthalate. Through research, I have a further understanding and discovery of 99-27-4.

Three novel flexible sulfur-containing MOF materials named Co-URJC-5, Cu-URJC-6 and Zn-URJC-7, based on the 5,5′-thiodiisophthalic acid linker have been synthesized through solvothermal methods and characterized by different physicochemical techniques. Hydrogen adsorption analysis at room temperature reveals that these compounds display a gate-opening type adsorption mechanism at low pressures, attributed to the flexible nature of the H4TBTC ligand. This behavior is even more noticeable for Cu-URJC-6, since the layer arrangement by p-p stacking interactions between the aromatic layers could contribute to the flexibility of the structure. These results can be considered as a representative example to elucidate how MOF structures are built using flexible ligands and more significantly as a promising route for designing materials with selective gas sorption properties.

About Dimethyl 5-aminoisophthalate, If you have any questions, you can contact Montes-Andres, H; Leo, P; Orcajo, G; Rodriguez-Dieguez, A; Choquesillo-Lazarte, D; Martos, C; Botas, JA; Calleja, G or concate me.. Application In Synthesis of Dimethyl 5-aminoisophthalate

Reference:
Patent; ASTRA ZENECA AB; NPS PHARMACEUTICALS, INC.; WO2004/14881; (2004); A2;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

I found the field of Chemistry very interesting. Saw the article A robust etb-type metal-organic framework showing polarity-exclusive adsorption of acetone over methanol for their azeotropic mixture published in 2019. Product Details of 99-27-4, Reprint Addresses Ling, Y (corresponding author), Fudan Univ, Shanghai Key Lab Mol Catalysis & Innovat Mat, Dept Chem, Shanghai 200438, Peoples R China.. The CAS is 99-27-4. Through research, I have a further understanding and discovery of Dimethyl 5-aminoisophthalate

We report a robust and rigid etb-type metal-organic framework, in which its pore surface is decorated with flexible ethoxyl groups. It shows unprecedentedly selective adsorption of acetone (E-N(T) value of 0.355, kinetic diameter of 4.6 angstrom) over methanol (E-N(T) value of 0.762, kinetic diameter of 3.6 angstrom) for their azeotropic mixture.

Product Details of 99-27-4. About Dimethyl 5-aminoisophthalate, If you have any questions, you can contact Hu, H; Zhu, JX; Yang, FL; Chen, ZX; Deng, ML; Weng, LH; Ling, Y; Zhou, YM or concate me.

Reference:
Patent; ASTRA ZENECA AB; NPS PHARMACEUTICALS, INC.; WO2004/14881; (2004); A2;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

An article Design, Synthesis and Structure-Activity Relationships of Plant-Based 2-Aryl-3,4-dihydroisoquinolin-2-iums as Potential Antifungal Agents WOS:000486906400026 published article about SANGUINARINE; SALTS in [Chen, Wei; Zuo, Huailong; Liu, Jiang; Zhou, Xianli] Southwest Jiaotong Univ, Sch Lifer Sci & Engn, Chengdu 610031, Sichuan, Peoples R China; [Li, Yuxin] Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China in 2019, Cited 17. The Name is Dimethyl 5-aminoisophthalate. Through research, I have a further understanding and discovery of 99-27-4. COA of Formula: C10H11NO4

In order to discover more potent antifungal, a series of 2-aryl-3,4-dihydroisoquinolin-2-iums were reasonable designed and productive synthesized by introducing benzoic acid and phenol pharmacophores into the 2-position of isoquinoline. Their structures were identified by NMR and HRMS. The preliminary in vitro antifungal results showed that most of the title compounds exhibited moderate to significant inhibitory activities against various phytopathogenic fungi at 50 mu g.mL(-1), and were equal to controls (chlorothalonil, carbendazim). The concentration of 50% inhibition rate (EC50]) of 2-(3-ethoxycarbonyl-phenyl)-3,4-dihydroisoquinolin-2-ium (4j) against R. solani was 3.8495 mu g.mL(-1), which was significantly superior to chlorothalonil (4.6328 mu g.mL(-1)). All the EC50 values of 5 compounds (7.4583 similar to 15.4495 mu g.mL(-1)) against R. cerealis were better than chlorothalonil (16.0137 mu g.mL(-1)), and 2-(4-methoxycarbonylphenyl)-3,4-dihydroisoquinolin-2-ium (4f) is the best one. The present results provide valuable information for development of plant-based antifungal agents.

COA of Formula: C10H11NO4. About Dimethyl 5-aminoisophthalate, If you have any questions, you can contact Chen, W; Zuo, HL; Li, YX; Liu, J; Zhou, XL or concate me.

Reference:
Patent; ASTRA ZENECA AB; NPS PHARMACEUTICALS, INC.; WO2004/14881; (2004); A2;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics