Category: 1877-71-0

《Aromatic β-Diketone as a Novel Anchoring Ligand in Iridium(III) Complexes for Dye-Sensitized Solar Cells》 was written by Bezzubov, Stanislav I.; Zharinova, Irina S.; Khusyainova, Alfiya A.; Kiselev, Yuri M.; Taydakov, Ilya V.; Varaksina, Evgenia A.; Metlin, Mikhail T.; Tobohova, Aiyyna S.; Korshunov, Vladislav M.; Kozyukhin, Sergei A.; Dolzhenko, Vladimir D.. Reference of 3-(Methoxycarbonyl)benzoic acid And the article was included in European Journal of Inorganic Chemistry on August 19 ,2020. The article conveys some information:

A novel β-diketone ligand bearing a thiophene moiety and an anchoring Ph-COOCH3 unit has been designed, prepared and used in synthesis of cyclometalated benzimidazole-based iridium(III) complexes for application in dye-sensitized solar cells (DSSC). The replacement of traditional 4,4′-dicarboxy-2,2′-bipyridine by this aromatic β-diketone results in excellent tuning the redox potentials and excited state properties of these IrIII complexes, one of which exhibits good efficiency when used as a dye in DSSC. All the complexes demonstrate reversible redox behavior, with oxidation potentials (Ir4+/Ir3+) strongly depending on the electron-donor/withdrawing nature of the substituents in the cyclometalated ligands. Surprisingly, the latter has just a little effect on their luminescence spectra, in which structured emission bands are observed Time-resolved spectroscopic studies in combination with DFT calculations show that the complexes emit light by mixed 3MLCT-3LC excited states predominantly composed of the diketone ligand-centered triplet state. The experimental part of the paper was very detailed, including the reaction process of 3-(Methoxycarbonyl)benzoic acid(cas: 1877-71-0Reference of 3-(Methoxycarbonyl)benzoic acid)

3-(Methoxycarbonyl)benzoic acid(cas: 1877-71-0) belongs to esters. They are important in biology, being one of the main classes of lipids and comprising the bulk of animal fats and vegetable oils.Reference of 3-(Methoxycarbonyl)benzoic acid Polyesters are important plastics, with monomers linked by ester moieties.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

The author of 《Photo-induced synthesis of β-sulfonyl imides from carboxylic acids》 were Zeng, Linwei; Jin, Jian; He, Jixiao; Cui, Sunliang. And the article was published in Chemical Communications (Cambridge, United Kingdom) in 2021. Application of 1877-71-0 The author mentioned the following in the article:

A photo-induced imidation process of carboxylic acids is described. Numerous carboxylic acids could convert to β-sulfonyl imides in the presence of N-sulfonyl ynamides under visible light irradiation Control experiments and mechanistic studies demonstrate that this imidation process involves a hydroacyloxylation/radical rearrangement cascade. This protocol represents a direct imidation method from carboxylic acids under mild conditions, with broad scope and high atom-economy. The results came from multiple reactions, including the reaction of 3-(Methoxycarbonyl)benzoic acid(cas: 1877-71-0Application of 1877-71-0)

3-(Methoxycarbonyl)benzoic acid(cas: 1877-71-0) belongs to esters. They are important in biology, being one of the main classes of lipids and comprising the bulk of animal fats and vegetable oils.Application of 1877-71-0 They perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Polyesters are important plastics, with monomers linked by ester moieties.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

In 2020,Chemical Communications (Cambridge, United Kingdom) included an article by Wang, Yanwei; Jiang, Xiaomei; Wang, Baiquan. Name: 3-(Methoxycarbonyl)benzoic acid. The article was titled 《Cobalt-catalyzed carboxylation of aryl and vinyl chlorides with CO2》. The information in the text is summarized as follows:

The transition-metal-catalyzed carboxylation of aryl and vinyl chlorides with CO2 is rarely studied, and has been achieved only with a Ni catalyst or combination of palladium and photoredox. In this work, the cobalt-catalyzed carboxylation of aryl and vinyl chlorides and bromides with CO2 has been developed. These transformations proceed under mild conditions and exhibit a broad substrate scope, affording the corresponding carboxylic acids in good to high yields. In the experimental materials used by the author, we found 3-(Methoxycarbonyl)benzoic acid(cas: 1877-71-0Name: 3-(Methoxycarbonyl)benzoic acid)

3-(Methoxycarbonyl)benzoic acid(cas: 1877-71-0) belongs to esters. Esters are more polar than ethers but less polar than alcohols. Name: 3-(Methoxycarbonyl)benzoic acid They participate in hydrogen bonds as hydrogen-bond acceptors, but cannot act as hydrogen-bond donors, unlike their parent alcohols.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

《N-Iminopyridinium ylide-directed, cobalt-catalysed coupling of sp2 C-H bonds with alkynes》 was published in Chemical Communications (Cambridge, United Kingdom) in 2020. These research results belong to Kwak, Se Hun; Daugulis, Olafs. Reference of 3-(Methoxycarbonyl)benzoic acid The article mentions the following:

N-Iminopyridinium ylides were competent monodentate directing groups for cobalt-catalyzed annulation of sp2 C-H bonds with internal alkynes. The pyridine moiety in the ylide serves as an internal oxidant and was cleaved during the reaction. The annulation reactions possess excellent compatibility with heterocyclic substrates, tolerating furan, thiophene, pyridine, pyrrole, pyrazole, and indole functionalities. In the experiment, the researchers used 3-(Methoxycarbonyl)benzoic acid(cas: 1877-71-0Reference of 3-(Methoxycarbonyl)benzoic acid)

3-(Methoxycarbonyl)benzoic acid(cas: 1877-71-0) belongs to esters. Esters are more polar than ethers but less polar than alcohols. They participate in hydrogen bonds as hydrogen-bond acceptors, but cannot act as hydrogen-bond donors, unlike their parent alcohols. Reference of 3-(Methoxycarbonyl)benzoic acid

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

In 2021,Chemical Communications (Cambridge, United Kingdom) included an article by Zhang, Lili; Chen, Shuai; He, Hengchi; Li, Weipeng; Zhu, Chengjian; Xie, Jin. Application In Synthesis of 3-(Methoxycarbonyl)benzoic acid. The article was titled 《Photoredox/nickel-catalyzed hydroacylation of ethylene with aromatic acids》. The information in the text is summarized as follows:

A general, practical and scalable hydroacylation reaction of ethylene with aromatic carboxylic acids with the synergistic combination of nickel and photoredox catalysis was reported. Under ambient temperature and pressure, feedstock chems. such as ethylene could be converted into high-value-added aromatic ketones in moderate to good yields (up to 92%) with reaction time of 2-6 h. The experimental part of the paper was very detailed, including the reaction process of 3-(Methoxycarbonyl)benzoic acid(cas: 1877-71-0Application In Synthesis of 3-(Methoxycarbonyl)benzoic acid)

3-(Methoxycarbonyl)benzoic acid(cas: 1877-71-0) belongs to esters. They are important in biology, being one of the main classes of lipids and comprising the bulk of animal fats and vegetable oils.Application In Synthesis of 3-(Methoxycarbonyl)benzoic acid They perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

The author of 《Cp*CoIII-catalyzed formal [4+2] cycloaddition of benzamides to afford quinazolinone derivatives》 were Yang, Jingshu; Hu, Xiao; Liu, Zijie; Li, Xueyuan; Dong, Yi; Liu, Gang. And the article was published in Chemical Communications (Cambridge, United Kingdom) in 2019. Computed Properties of C9H8O4 The author mentioned the following in the article:

A Cp*CoIII-catalyzed arene C-H bond amidation/annulation of benzamides was developed to afford quinazolinone derivatives in one-pot with high yields and broad substrate scope. This method could be applied to the synthesis of quinazolinone drugs and late-stage modification of natural products. The experimental process involved the reaction of 3-(Methoxycarbonyl)benzoic acid(cas: 1877-71-0Computed Properties of C9H8O4)

3-(Methoxycarbonyl)benzoic acid(cas: 1877-71-0) belongs to esters. They are important in biology, being one of the main classes of lipids and comprising the bulk of animal fats and vegetable oils.Computed Properties of C9H8O4 They perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Peter Ventura, Alejandra M.; Haeberlein, Simone; Konopka, Leonie; Obermann, Wiebke; Gruenweller, Arnold; Grevelding, Christoph G.; Schlitzer, Martin published their research in Archiv der Pharmazie (Weinheim, Germany) on December 31 ,2021. The article was titled 《Synthesis and antischistosomal activity of linker- and thiophene-modified biaryl alkyl carboxylic acid derivatives》.Related Products of 1877-71-0 The article contains the following contents:

Schistosomiasis is a neglected tropical disease caused by blood flukes of the genus Schistosoma and causes severe morbidity in infected patients. In 2018, 290.8 million people required treatment, and 200,000 deaths are reported per yr. Treatment of this disease depends on a single drug, praziquantel (PZQ). However, in the past few years, reduced sensitivity of the parasites toward PZQ has been reported. Therefore, there is an urgent need for new drugs against this disease. In the past few years, we have focused on a new substance class called biaryl alkyl carboxylic acid derivatives, which showed promising antischistosomal activity in vitro. Structure-activity relationship (SAR) studies of the carboxylic acid moiety led to three promising carboxylic amides (morpholine, thiomorpholine, and Me sulfonyl piperazine) with an antischistosomal activity down to 10μM (morpholine derivative) and no cytotoxicity up to 100μM. Here, we show our continued work on this substance class. We investigated, in extended SAR studies, whether modification of the linker and the thiophene ring could improve the antischistosomal activity. We found that the exchange of the alkyl linker by a pentadienyl or benzyl linker was tolerated and led to similar antischistosomal effects, whereas the exchange of the thiophene ring was not tolerated. Our data suggest that the thiophene ring is important for the antischistosomal activity of this compound class. The results came from multiple reactions, including the reaction of 3-(Methoxycarbonyl)benzoic acid(cas: 1877-71-0Related Products of 1877-71-0)

3-(Methoxycarbonyl)benzoic acid(cas: 1877-71-0) belongs to esters. They are important in biology, being one of the main classes of lipids and comprising the bulk of animal fats and vegetable oils.Related Products of 1877-71-0 Polyesters are important plastics, with monomers linked by ester moieties.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Related Products of 1877-71-0On November 30, 2021 ,《Aziridine-2-carboxylic acid derivatives and its open-ring isomers as a novel PDIA1 inhibitors》 appeared in Chemistry of Heterocyclic Compounds (New York, NY, United States). The author of the article were Leite, Irena; Andrianov, Victor; Zelencova-Gopejenko, Diana; Loza, Einars; Kazhoka-Lapsa, Iveta; Domracheva, Ilona; Stoyak, Marta; Chlopicki, Stefan; Kalvins, Ivars. The article conveys some information:

Acyl derivatives of aziridine-2-carboxylic acid have been synthesized and tested as PDIA1 inhibitors. Calculations of charge value and distribution in aziridine ring system and some alkylating agents were performed. For the first time was found that acyl derivatives of aziridine-2-carboxylic acid are weak to moderately active PDIA1 inhibitors. In addition to this study using 3-(Methoxycarbonyl)benzoic acid, there are many other studies that have used 3-(Methoxycarbonyl)benzoic acid(cas: 1877-71-0Related Products of 1877-71-0) was used in this study.

3-(Methoxycarbonyl)benzoic acid(cas: 1877-71-0) belongs to esters. Esters are more polar than ethers but less polar than alcohols. They participate in hydrogen bonds as hydrogen-bond acceptors, but cannot act as hydrogen-bond donors, unlike their parent alcohols. Related Products of 1877-71-0

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics