Category: 140-11-4

Vardini, Mohammad Taghi published the artcileGraphite electrode potentiometric sensor modified by surface imprinted silica gel to measure valproic acid, Recommanded Product: Benzyl acetate, the main research area is valproic acid silica gel graphite electrode potentiometric sensor.

The aim of the study was to produce a Polyvinyl chloride-based membrane containing a polymer imprinted with a valproic acid mol. which was directly coated on a graphite electrode to determine the amount of valproic acid in aqueous samples. With the dispersion of molecularly imprinted polymer particles in dioctyl phthalate plasticizer as a solvent mediator, this potentiometric sensor was designed and after that it was embedded in a polyvinyl chloride matrix. The designed electrode showed a near-Nernstian slope of 54.1 ± 1 mV decade-1 in the concentration range of 10-6-10-2 M and a detection limit of 10-6 M with a response time of about 40 s for valproic acid and can be used for 2 mo without divergence changing the potential. The fabricated electrode, in the pH range among 3.5-8.5, indicates the good sensitivity to valproic acid relative to the other ions. Finally, this electrode can be used as an indicator electrode in determining the concentration of valproic acid in valproic acid tablets.

Chemical Methodologies published new progress about Absorption. 140-11-4 belongs to class esters-buliding-blocks, name is Benzyl acetate, and the molecular formula is C9H10O2, Recommanded Product: Benzyl acetate.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Aszyk, Justyna published the artcileConcentration levels of selected analytes in the gas phase of an e-cigarette aerosol, Related Products of esters-buliding-blocks, the main research area is electronic cigarette gas phase aerosol.

The aerosols generated from e-cigarettes are composed of liquid and gas phases resulting from vaporized e-liquid The apportioning of substances from e-liquid into the liquid and gas phases during e-cigarette use has not been extensively studied. Partitioning of e-liquid components between the gas and the liquid phase of the aerosol influences the substances inhaled and exhaled by the users, leading to second-hand exposure. It seems important to determine which compounds and how much of them are transferred into the gas phase and may immediately enter the bloodstream. For this purpose, a method based on thermal desorption followed by gas chromatog. coupled with tandem mass spectrometry (GC-MS/MS) in electron ionization mode was developed. As in a previous study, an automatic generator of an aerosol from an e-cigarette with a collection tube filled with melt-blown non-woven fabric disks and equipped with Tenax TA sorption tubes was used. The melt-blown non-woven fabric is designed to capture liquid phase compounds, while sorption tubes are meant to sorb compounds in the gas phase of the aerosol. To control the e-liquid mass changes before and after a puff session, quantitation based on the mass change tracking approach (MCT) was applied. Accuracy of the developed method ranged between 91% and 110% regardless of the spiking level, with precision and reproducibility better than 10%. The limits of detection (LODs) ranged from 0.015 to 0.076 ng of substance emitted/mg of consumed e-liquid, while limits of quantitation (LOQs) ranged from 0.045 to 0.23 ng of substance emitted/mg of consumed e-liquid Most of the compounds are deposited in the liquid phase of the aerosol, while only trace levels of some substances may be observed in an actual, non-condensed gas phase.

Microchemical Journal published new progress about Adsorption. 140-11-4 belongs to class esters-buliding-blocks, name is Benzyl acetate, and the molecular formula is C9H10O2, Related Products of esters-buliding-blocks.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Yang, Ruijie published the artcileThe performance and reaction pathway of δ-MnO2/USY for catalytic oxidation of toluene in the presence of ozone at room temperature, Computed Properties of 140-11-4, the main research area is manganese oxide zeolite toluene catalytic oxidation ozone removal; Catalytic oxidation pathway; Ozone; Toluene; USY; δ-MnO(2).

In this work, a series of δ-MnO2/USY with different contents of δ-MnO2 (0.3 wt%, 1.5 wt%, 3.0 wt%, 10.0 wt%, and 15.0 wt%) were prepared In addition, their performances of the adsorption of toluene, degradation and mineralization of toluene, and removal of ozone (O3) were investigated. The results showed that, among all the samples, 3.0 wt% δ-MnO2/USY displayed the best performance of toluene adsorption, degradation and mineralization. Furthermore, according to the in situ DRIFTS and GC-MS anal., the intermediate byproducts during the toluene degradation progress were ascertained and the possible pathway of catalytic oxidation toluene by δ-MnO2/USY in the presence of O3 was proposed.

Chemosphere published new progress about Absorption. 140-11-4 belongs to class esters-buliding-blocks, name is Benzyl acetate, and the molecular formula is C9H10O2, Computed Properties of 140-11-4.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Kujur, Anupam published the artcileFabrication, Characterization, and Antifungal Assessment of Jasmine Essential Oil-Loaded Chitosan Nanomatrix Against Aspergillus flavus in Food System, Related Products of esters-buliding-blocks, the main research area is Aspergillus flavus jasmine essential oil chitosan antifungal food system.

The present study investigated the antifungal and aflatoxin B1 (AFB1) inhibitory efficacy of Jasmine essential oil-loaded in the chitosan nanoparticle (JEO-NP) with probable antifungal and anti-aflatoxin B1 mode of action against Aspergillus flavus. The prepared JEO-NP was characterized through FTIR and XRD. The maximum percent encapsulation efficiency (75.51% weight/weight) and loading capacity (5.65% weight/weight) were found at the 1:1 ratio of chitosan: JEO. The results of thermogravimetric anal. exhibited an increase in thermal stability of JEO-NP compared to the free JEO. The antifungal and AFB1 inhibitory concentration of JEO-NP was found to be 2.5μL/mL against A. flavus, which was lower than free form JEO (3.0μL/mL). Biochem. and in silico approaches revealed the antifungal mechanisms of action of JEO-NP were related to the inhibition in ergosterol biosynthesis, leakage of vital ions (Ca+2, Mg+2, and K+), impairment in carbon substrate utilization, and functioning of the AFB1 regulatory genes (ver-1 and omt A (in silico)) of A. flavus. JEO-NP exhibited free radical scavenging activity through DPPH assay (IC50 1.31μL/mL). The in situ results showed that JEO-NP significantly protects the maize seed samples from A. flavus growth, AFB1 contamination and also preserved its nutritional quality. The absorption, distribution, metabolism, excretion, and toxicity (ADMET) profiling revealed the JEO major components are non-mutagenic, non-hepatotoxic, non-carcinogenic, non-tumorigenic, biodegradable nature, and predicted toxicity (LD50 mg/kg rat) were ranged 3107.01 to 3960.22 mg/kg. The findings revealed that the nanoencapsulation technique could be used to enhance the antifungal efficacy of plant essential oil in the food system.

Food and Bioprocess Technology published new progress about Absorption. 140-11-4 belongs to class esters-buliding-blocks, name is Benzyl acetate, and the molecular formula is C9H10O2, Related Products of esters-buliding-blocks.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Peng, Baoxiang published the artcileExperimental verification of conservatively perturbed equilibrium for a complex non-linear chemical reaction, Safety of Benzyl acetate, the main research area is conservatively perturbed equilibrium nonlinear esterification transesterification reaction kinetics modeling.

The phenomenon of ”conservatively perturbed equilibrium” (CPE) for a complex non-linear chem. system was exptl. verified in a batch reactor in which ethanol and benzyl alc. react with acetic acid producing two different esters and water. Three possible CPE cases, i.e., acetic acid and water unperturbed, ethanol and Et acetate unperturbed, benzyl alc. and benzyl acetate unperturbed, were systematically investigated. For unperturbed substances with initial concentrations of their corresponding equilibrium concentrations, unavoidable extreme values were observed in relaxation to the equilibrium If the unperturbed substances were involved in two reactions, a proper momentary partial equilibrium was not observed at the transient extremum. However, the transient extremum could be an approx. momentary partial equilibrium for the reaction of the unperturbed substance if the rate of some step is insignificant. This fact provides essential information about the detailed mechanism of the complex reaction.

Chemical Engineering Science published new progress about Equilibrium. 140-11-4 belongs to class esters-buliding-blocks, name is Benzyl acetate, and the molecular formula is C9H10O2, Safety of Benzyl acetate.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Wang, Shuyan published the artcileComparison of volatiles in different jasmine tea grade samples using electronic nose and automatic thermal desorption-gas chromatography-mass spectrometry followed by multivariate statistical analysis, Recommanded Product: Benzyl acetate, the main research area is jasmine tea volatile electronic nose ATDGCMS multivariate; Chinese jasmine tea; automatic thermal desorption-gas-chromatography- mass spectrometry (ATD-GC-MS); electronic nose (E-nose); multivariate statistical analysis; tea grade; volatile organic compounds.

Chinese jasmine tea is a type of flower-scented tea, which is produced by mixing green tea with the Jasminum sambac flower repeatedly. Both the total amount and compound of volatiles absorbed from the Jasminum sambac flower are mostly responsible for its sensory quality grade. This study aims to compare volatile organic compound (VOC) differences in authoritative jasmine tea grade samples. Automatic thermal desorption-gas-chromatog.-mass spectrometry (ATD-GC-MS) and electronic nose (E-nose), followed by multivariate data anal. is conducted. Consequently, specific VOCs with a pos. or neg. correlation to the grades are screened out. Partial least squares-discriminant anal. (PLS-DA) and hierarchical cluster anal. (HCA) show a satisfactory discriminant effect on rank. It is intriguing to find that the E-nose is good at distinguishing the grade difference caused by VOC concentrations but is deficient in identifying essential aromas that attribute to the unique characteristics of excellent grade jasmine tea.

Molecules published new progress about Gas sensors. 140-11-4 belongs to class esters-buliding-blocks, name is Benzyl acetate, and the molecular formula is C9H10O2, Recommanded Product: Benzyl acetate.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Morales, M. L. published the artcileVolatile metabolites produced by different flor yeast strains during wine biological ageing, Formula: C9H10O2, the main research area is volatile metabolite yeast strain wine biol aging; Flor yeast; GC-MS analysis; Heatmap; Sherry wine; Volatile compound.

Sherry white wine called Fino is produced by dynamic biol. ageing under the action of flor yeasts using traditional practices aimed at ensuring uniform quality and characteristics over time. These kinds of yeasts provide typical sensory properties to Fino wines. Although there are studies of the volatile composition of these wines submitted to biol. ageing in wood barrels, there is a lack of knowledge on the particular volatile profile produced by different flor yeast strains from Sherry zone wineries. For this reason, the aim of this study was to analyze the volatile profiles produced by 15 pure culture flor velum yeasts, with the goal of observing their suitability for obtaining high quality Fino sherry wines. Volatile composition was determined by dual sequential stir bar sorptive extraction, followed by GC-MS anal. All yeast strains studied produced the increase of most acetals, highlighting acetaldehyde diethylacetal which was the compound that most increased. Among terpenes, nerolidol and farnesol underwent remarkable increases. However, results showed that in a month of biol. ageing, significant differences were observed among the volatile metabolites produced by flor yeast strains studied. Only some of them stood out for their high production of volatile compounds characteristic of Sherry Fino wines, which are good candidates for producing starter cultures.

Food Research International published new progress about Metabolites. 140-11-4 belongs to class esters-buliding-blocks, name is Benzyl acetate, and the molecular formula is C9H10O2, Formula: C9H10O2.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Ravichandran, Janani published the artcileAn atlas of fragrance chemicals in children’s products, Related Products of esters-buliding-blocks, the main research area is atlas fragrance chem product children potential health concern safety; Chemical regulation; Children’s products; FCCP database; Fragrance chemicals; Network analysis; Skin sensitizing chemicals.

Exposure to environmental chems. during early childhood is a potential health concern. At a tender age, children are exposed to fragrance chems. used in toys and child care products. Although there are few initiatives in Europe and United States towards monitoring and regulation of fragrance chems. in children’s products, such efforts are still lacking elsewhere. Besides there was no systematic effort to create a database compiling the surrounding knowledge on fragrance chems. used in children’s products from published literature. Here, we built a database of Fragrance Chems. in Children’s Products (FCCP) that compiles information on 153 fragrance chems. from published literature. The fragrance chems. in FCCP were classified based on their chem. structure, children’s product source, chem. origin and odor profile. Moreover, we have also compiled the physicochem. properties, predicted Absorption, Distribution, Metabolism, Excretion and Toxicity (ADMET) properties, mol. descriptors and human target genes for the fragrance chems. in FCCP. After building FCCP, we performed multiple analyses of the associated fragrance chem. space. Firstly, we assessed the regulatory status of the fragrance chems. in FCCP through a comparative anal. with 21 chem. lists reflecting current guidelines or regulations. We find that several fragrance chems. in children’s products are potential carcinogens, endocrine disruptors, neurotoxicants, phytotoxins and skin sensitizers. Secondly, we performed a similarity network based anal. of the fragrance chems. in children’s products to reveal the high structural diversity of the associated chem. space. Lastly, we identified skin sensitizing fragrance chems. in children’s products using ToxCast assays. In a nutshell, we present a comprehensive resource and detailed anal. of fragrance chems. in children’s products highlighting the need for their better risk assessment and regulation to deliver safer products for children. FCCP is accessible at: https://cb.imsc.res.in/fccp.

Science of the Total Environment published new progress about Carcinogens. 140-11-4 belongs to class esters-buliding-blocks, name is Benzyl acetate, and the molecular formula is C9H10O2, Related Products of esters-buliding-blocks.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Lebanov, Leo published the artcileComprehensive characterization of ylang-ylang essential oils according to distillation time, origin, and chemical composition using a multivariate approach applied to average mass spectra and segmented average mass spectral data, SDS of cas: 140-11-4, the main research area is ylang essential oil composition mass spectra data multivariate; Average mass spectrum; Gas chromatography mass spectrometry; Multivariate statistical analysis; Quality control; Ylang-ylang essential oil.

Analyses of the complex essential oil samples using gas chromatog. hyphenated with mass spectrometry (GC-MS) generate large three-way data arrays. Processing such large data sets and extracting meaningful information in the metabolic studies of natural products requires application of multivariate statistical techniques (MSTs). From the GC-MS raw data several different input data sets for the MSTs can be created, including total chromatogram average mass spectra (TCAMS), segmented average mass spectra (SAMS) and chem. composition Herein, we compared the performance of MSTs on average mass spectrum based data sets, TCAMS and SAMS, against chem. composition and attenuated total reflectance – Fourier transformation IR (ATR-FTIR) spectroscopy in the evaluation of quality of ylang-ylang essential oils, based on their grade, geog. origin and chem. composition, using principal component anal. (PCA), partial least squares regression (PLS) and discriminatory anal. (PLS-DA). PCA based on TCAMS, SAMS and chem. composition showed clear trends amongst the samples based on increase in grade (distillation time). PLS-DA applied to TCAMS, SAMS and ATR-FTIR discriminated between all geog. origins. Predicted relative abundances of the 18 most important compounds, using PLS regression models on TCAMS, SAMS and ATR-FTIR, were successfully applied to ylang-ylang essential oil quality assessment based on comparison with the ISO 3063:2004 standard, where the SAMS data set showed superior performance, compared to other data sets.

Journal of Chromatography A published new progress about Composition. 140-11-4 belongs to class esters-buliding-blocks, name is Benzyl acetate, and the molecular formula is C9H10O2, SDS of cas: 140-11-4.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Ishiguro, Takako published the artcileThe use of enteric capsules for releasing a fragrance over an extended period of time, Related Products of esters-buliding-blocks, the main research area is hypro mellose acetate succinate enteric capsule releasing fragrance; delayed release; enteric capsule; fragrance; pH adjustment; time lag.

A system for releasing a fragrance, citral (CR) over an extended period of time using three types of enteric capsules is reported. The L- and M-type capsules released CR into media with a pH above 6, while the H-type capsule released CR at a pH above 7. The pH of the releasing medium was controlled by sodium borate (SB), i.e., by adding SB-methylcellulose (MC) prepared in different weight ratios (SB-MC 1 : 2, 1 : 1 and 2 : 1) to tablets and by compressing them at different pressures. The tablet containing a large amount of SB and that was pressed at higher pressures permitted the pH of the releasing medium to be changed from 5 to 9, at 4-5 h after the addition of SB to the tablets, while negligible changes were observed for tablets containing low amounts of SB and which were compressed at lower pressures. Reflecting these pH changes, CR was released after different periods of time when SB-MC tablets and capsules containing CR were simultaneously added to the releasing medium. When enteric capsules containing CR and the pH adjusting tablets were simultaneously added to a benzyl acetate (BA) solution, BA was released at a constant rate, while CR was released for different periods of time depending on the type of capsule used. The results suggest that fragrances could be released over different time frames by using enteric capsules and pH adjusting agents, for example, the release of fragrances with sedative effects at night time and with stimulating effects in the morning.

Chemical & Pharmaceutical Bulletin published new progress about pH. 140-11-4 belongs to class esters-buliding-blocks, name is Benzyl acetate, and the molecular formula is C9H10O2, Related Products of esters-buliding-blocks.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics