Category: 112-63-0

Dowling, Sally D.; Mullin, Jerry L.; Seitz, W. Rudolf published the artcile< Binding of sulfonated fluorophors by metal-polyethylenimine complexes>, Computed Properties of 112-63-0, the main research area is pyrenesulfonate binding polyethylenimine metal complex; anilinonaphthalenesufonate binding polyethylenimine metal complex; copper polyethylenimine complex binding sulfonate; zinc polyethylenimine complex binding sulfonate; silver polyethylenimine complex binding sulfonate; fluorescence polyethylenimine complex binding sulfonate.

The binding of Na 1-pyrenesulfonate (I) [59323-54-5], tetra-Na 1,3,6,8-pyrenetetrasulfonate (II) [59572-10-0] and magnesium 1,8-anilinonaphthalenesulfonate (III) [18108-68-4] to the Cu(II), Zn(II), and Ag(I) complexes of poly(ethylenimine) (IV) was studied by measuring fluorescence intensities and excitation and emission spectra at various metal-to-pyrene ratios in the presence of IV. I reacts to form ground-state dimers when bound to Cu(II)- and Zn(II)-IV: on Cu(II)- and Zn(II)-IV and to a lesser extent on Ag(I)-IV the amounts of bound I exceed that required for electroneutrality under certain conditions: II binds more strongly to Ag(I)-IV than to Cu(II)-IV. I forms excimers to only a very small extent when bound to protonated IV. III emits at shorter wavelength when bound to Zn(II)-IV than when bound to protonated IV. The results are interpreted as indicating that binding to Cu(II)- and Zn(II)-IV is predominantly hydrophobic and territorial because the IV shields the bound counterion from the charge on the metal ion. On Ag(I)-IV and particularly on protonated IV the charge on the polyelectrolyte is more acceptable to bound counterions, causing electrostatic interactions to be more important and binding to be more site specific.

Macromolecules published new progress about Excimer. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Computed Properties of 112-63-0.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Lee, Yunjeong; Weerawongwiwat, Veeraya; Kim, Jong-Hwa; Yoon, Jung-Hoon; Suh, Min Kuk; Kim, Han Sol; Lee, Jung-Sook; Sukhoom, Ampaitip; Kim, Wonyong published the artcile< Sneathiella sedimenti sp. nov., isolated from marine sediment>, Related Products of 112-63-0, the main research area is sequence Sneathiella marine sediment menaquinone10 phosphatidylethanolamine fatty acids phylogeny; 16S rRNA gene sequence; Alphaproteobacteria; Sneathiella sedimenti; Sneathiellaceae; genome sequencing; marine sediment.

A novel bacterium, designated CAU 1612T, was isolated from coastal sediment sampled in the Republic of Korea. Cells of the strain were Gram-stain-neg., rod-shaped and motile. Optimum growth occurred at 30 °C, at pH 7.0 and with 1.0 % (w/v) NaCl. Based on 16S rRNA gene sequences, phylogenetic anal. revealed that strain CAU 1612T belonged to the genus Sneathiella and showed highest similarity to ′Sneathiella litorea′ JCM 33810T (98.5 %), followed by Sneathiella chungangensis KCTC 32476T (97.7 %), Sneathiella aquimaris KCTC 12842T (96.0 %), Sneathiella chinensis LMG 23452T (95.5 %), Sneathiella limimaris KCTC 52846T (95.5 %) and Sneathiella glossodoripedis KCTC 12842T (95.4 %). The average nucleotide identity and digital DNA-DNA hybridization values of strain CAU 1612T were estimated to be 68.5-81.7 % and ≤23.7 %, resp., to members of the genus Sneathiella. The DNA G + C content was 54.1 mol%. The major cellular fatty acids (>10 %) were C16 : 0, C19 : 0 cyclo ω8c and summed feature 8 (C18 : 1 ω7c and/or C18 : 1 ω6c). The major menaquinone was Q-10 and the predominant polar lipids were phosphatidylmethylethanolamine, phosphatidylethanolamine and phosphatidylglycerol. On the basis of taxonomic evidence, strain CAU 1612T represents a novel species, for which the name Sneathiella sedimenti sp. nov. is proposed. The type strain is CAU 1612T (= KCTC 82427T = MCCC 1K06082T). The 16S rRNA gene and the whole-genome sequences of strain CAU 1612T have been deposited in GenBank/EMBL/DDBJ with the accession numbers MW192779 and JAFLNC000000000, resp.

International Journal of Systematic and Evolutionary Microbiology published new progress about 16S rRNA Role: BSU (Biological Study, Unclassified), BIOL (Biological Study). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Related Products of 112-63-0.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Li, Fang-Fang; Ma, Jian-Fang; Yang, Jin; Jia, Heng-Qing; Hu, Ning-Hai published the artcile< Syntheses, structures and luminescence of silver(I) sulfonate complexes with PPh3 ligand>, Computed Properties of 112-63-0, the main research area is silver sulfonate phosphine preparation structure luminescence; crystal structure silver arylsulfonato phosphine complex.

Four new luminescent silver(I) sulfonate complexes with PPh3, Ag(L1)(PPh3)2 (1), Ag(L2)(PPh3)3 (2), [Ag2(L3)(PPh3)4(H2O)]·1.5CH3CN·0.5H2O (3) and [Ag4(L4)(PPh3)10]·8H2O (4), where L1 = p-toluenesulfonate, L2 = 1-naphthalenesulfonate, L3 = 3-carboxylate-4-hydroxybenzenesulfonate, L4 = 1,3,6,8-pyrenetetrasulfonate and PPh3 = triphenylphosphine, were synthesized and characterized. The crystal structures were determined by single-crystal x-ray diffraction method. Compounds 1, 2, 3 and 4 adopt discrete structures rather than polymeric structures. Compounds 1 and 2 show mononuclear structures while 3 and 4 are dinuclear and tetranuclear mols., resp. Also the numbers of PPh3 mols. coordinating to one silver center are two or three. The photoluminescent properties of 1, 2 and 3 are discussed.

Journal of Molecular Structure published new progress about Crystal structure. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Computed Properties of 112-63-0.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Nakamatsu, Seiken; Toyota, Shinji; Jones, William; Toda, Fumio published the artcile< The important role of solvent vapor in an organic solid state reaction>, Category: esters-buliding-blocks, the main research area is solvent vapor important role organic solid state reaction.

Some organic reactions in the solid state proceeded very efficiently and selectively in the presence of a small amount of solvent vapor.

Chemical Communications (Cambridge, United Kingdom) published new progress about Addition reaction. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Category: esters-buliding-blocks.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Ishola, Ahmed Adebayo; Adewole, Kayode Ezekiel published the artcile< Phytosterols and triterpenes from Morinda lucida Benth. exhibit binding tendency against class I HDAC and HDAC7 isoforms>, Safety of (9Z,12Z)-Methyl octadeca-9,12-dienoate, the main research area is Morinda phytosterol triterpene HDAC isoform; Anticancer; HDACs; Morinda lucida; Phytosterols; Triterpenes.

The important role of histone deacetylases (HDACs) in the development of cancer has been demonstrated by various studies. Thus targeting HDACs with inhibitors is a major focus in anticancer drug research. Although few synthetic HDAC inhibitors (HDIs) have been approved for cancer treatment, they have significant undesirable side effects. Therefore emphases have been placed on natural HDIs as substitutes for the synthetic ones. In a bid to identify more HDIs, this study evaluated the binding tendency of compounds derived from Morinda lucida Benth. towards selected HDACs for the discovery of potent HDIs as potential candidates for anticancer therapeutics, based on the report of anticancer potentials of Morinda lucida-derived extracts and compounds Druglikeness and Absorption-Distribution-Metabolism-Excretion (ADME) parameters of the top 7 compounds were evaluated using the Swiss online ADME web tool. The results revealed that out of the 49 compounds, 3 phytosterols (campesterol, cycloartenol, and stigmasterol) and 2 triterpenes (oleanolic acid and ursolic acid) exhibited high HDAC inhibitory activity compared to givinostat. These 5 compounds also fulfill oral drugability of Lipinski rule of five. Morinda lucida-derived phytosterols and triterpenes show high binding tendency towards the selected HDACs and exhibited good drugability characteristics and are therefore good candidates for further studies in the search for therapies against abnormalities linked with over-activity of HDACs.

Molecular Biology Reports published new progress about Morinda lucida. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Safety of (9Z,12Z)-Methyl octadeca-9,12-dienoate.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Linnenkugel, Sebastian; Paterson, Anthony H. J.; Huffman, Lee M.; Bronlund, John E. published the artcile< Prediction of the effect of water on the glass transition temperature of low molecular weight and polysaccharide mixtures>, COA of Formula: C19H34O2, the main research area is polysaccharide mixture water glass transition temperature low mol weight.

The right storage conditions for food powders containing amorphous carbohydrates are crucial to avoid structural changes. By combining the sorption isotherm and the glass transition temperature (Tg) data for these food powders enables the determination of appropriate moisture and temperature conditions for their storage. In this study, the modified Flory-Huggins free volume theory was utilized to predict the stability diagrams purely from the composition of the powders. The validation of the approach using the literature data of blends of grapefruit, mango and acai powders with various blends of maltodextrin (MD) and gum Arabic. The blends of fructose, glucose individual and in combination with citric acids as well as blackcurrant juice concentrate with MD DE 9-13 were also investigated. The alignment of exptl. and predicted data of fruit powders demonstrates that it was possible to predict the relation of the Tg well as a function of the water activity for carbohydrate mixtures

Food Hydrocolloids published new progress about Absorption. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, COA of Formula: C19H34O2.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Holland, Herbert L.; Kindermann, Maik; Kumaresan, Sudalaiyandi; Stefanac, Tomislav published the artcile< Side chain hydroxylation of aromatic compounds by fungi. Part 5. Exploring the benzylic hydroxylase of Mortierella isabellina>, Safety of (9Z,12Z)-Methyl octadeca-9,12-dienoate, the main research area is hydroxylation stereochem aromatic compound fungi; Mortierella isabellina hydroxylation aromatic compound; active site model benzylic hydroxylase enzyme.

The active site topog. of the hydroxylase enzyme of Mortierella isabellina ATCC 42613, which carries out the benzylic hydroxylation of toluene, ethylbenzene, and related compounds, has been explored. Operating in a whole cell biotransformation mode, this enzyme shows selectivity in substrate processing based on the nature, position and size of substituent side chains close to the site of hydroxylation. The results of determination of the yield and stereochem. of hydroxylation of over twenty substrates and potential substrates, together with previously reported data, have been used to propose an active site model for the benzylic hydroxylase enzyme.

Tetrahedron: Asymmetry published new progress about Hydroxylation, enzymic. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Safety of (9Z,12Z)-Methyl octadeca-9,12-dienoate.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Krapcho, A. Paul; Jahngen, Edwin G. E. Jr.; Kashdan, David S. published the artcile< α-Carbalkoxylations of carboxylic acids. General synthetic route to monoesters of malonic acids>, Formula: C19H34O2, the main research area is carboxylation carboxylic acid; malonic acid monoester.

Treatment of α-anions of acyclic and alicyclic carboxylic acids, prepared by reaction of the acid with LiN(CHMe2)2, with either ClCO2Et or (RO)2CO (R = Me, Et) gave 46-88% of monoesters of malonic acids. Thus, Me2CHCO2H reacted with ClCO2Et in the presence of LiN(CHMe2)2 to give 85% Me2C(CO2H)CO2Et.

Tetrahedron Letters published new progress about Carboxylation. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Formula: C19H34O2.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Li, Xing; Chen, Honglin; Xie, Shuting; Wang, Ning; Wu, Sujuan; Duan, Yuyou; Zhang, Minmin; Shui, Lingling published the artcile< Fabrication of photo-crosslinkable poly (trimethylene carbonate)/polycaprolactone nanofibrous scaffolds for tendon regeneration>, Safety of (9Z,12Z)-Methyl octadeca-9,12-dienoate, the main research area is polyester polycarbonate scaffold youngs modulus yield strain; composite scaffolds; creep resistance; photo-crosslinking; poly(trimethylene carbonate); tissue engineering.

The treatment of tendon injuries remains a challenging problem in clin. due to their slow and insufficient natural healing process. Scaffold-based tissue engineering provides a promising strategy to facilitate tendon healing and regeneration. However, many tissue engineering scaffolds have failed due to their poor and unstable mech. properties. To address this, we fabricated nanofibrous polycaprolactone/methacrylated poly(trimethylene carbonate) (PCL/PTMC-MA) composite scaffolds via electrospinning. PTMC-MA was characterized by NMR. Fiber morphol. of composite scaffolds was evaluated using SEM. The monotonic tensile test was performed for determining the mech. properties of composite scaffolds. Cell viability and collagen deposition were assessed via PrestoBlue assay and ELISA, resp. These PCL/PTMC-MA composite scaffolds had an increase in mech. properties as PTMC-MA content increase. After photo-crosslinking, they showed further enhanced mech. properties including creep resistance, which was superior to pure PCL scaffolds. It is worth noting that photo-crosslinked PCL/PTMC-MA (1:3) composite scaffolds had a Young’s modulus of 31.13 ± 1.30 MPa and Max stress at break of 23.80 ± 3.44 MPa that were comparable with the mech. properties of native tendon (Young’s modulus 20-1200 MPa, max stress at break 5-100 MPa). In addition, biol. experiments demonstrated that PCL/PTMC-MA composite scaffolds were biocompatible for cell adhesion, proliferation, and differentiation.

International Journal of Nanomedicine published new progress about Electrospinning. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Safety of (9Z,12Z)-Methyl octadeca-9,12-dienoate.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Konstandaras, Nicholas; Dunn, Michelle H.; Guerry, Max S.; Barnett, Christopher D.; Cole, Marcus L.; Harper, Jason B. published the artcile< The impact of cation structure upon the acidity of triazolium salts in dimethyl sulfoxide>, Product Details of C19H34O2, the main research area is triazolium salt acidity DMSO.

A series of triazolium salts, selected for their varying electronic and steric properties, were prepared and their pKa values were determined in DMSO at 25 °C using the bracketing indicator method. The effect of each systematic structural variation upon the acidity of the triazolium cation has been considered, in particular examining the effects of systematically altering electronic properties, quantified through the use of Hammett σ parameters. The first pKa value for an azolium salt that generates a mesionic carbene is also reported. These new data allow for the selection of appropriate bases for the deprotonation of such triazolium salts and the potential to correlate the pKa values determined herein with the nucleophilicity of the corresponding carbenes.

Organic & Biomolecular Chemistry published new progress about Bronsted acidity. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Product Details of C19H34O2.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics