Category: 103-26-4

Recommanded Product: 103-26-4. In 2020.0 ARAB J CHEM published article about ASSISTED EXTRACTION; ANTIOXIDANT CAPACITY; CHEMICAL-COMPOSITION; ROSMARINIC ACID; ESSENTIAL OILS; BIOSYNTHESIS; QUALITY; PEPPER; YIELD in [Mahmoudi, Hela] Univ Tunis El Manar, Lab Prod Vegetale & Contraintes Environm, Campus Univ, Tunis 2092, Tunisia; [Marzouki, Moomen] Inst Natl Rech & Anal Phys Chim, Lab Mat Utiles, Sidi Thabet 2020, Tunisia; [M’Rabet, Yassine; Mezni, Mohamed; Hosni, Karim] Inst Natl Rech & Anal Phys Chim, Lab Subst Nat, Sidi Thabet 2020, Tunisia; [Ouazzou, Abdenour Ait] Univ Benyoucef Benkhedda, Lab Valorisat & Bioingn Ressources Nat, Algiers 1, Algeria in 2020.0, Cited 43.0. The Name is Methyl 3-phenyl-2-propenoate. Through research, I have a further understanding and discovery of 103-26-4.

In the present study, the effect of enzyme pretreatment on essential oil recoveries from sweet basil (Ocimum basilicum L.) leaves was evaluated. Moreover, the consideration on the use of hydrodistilled residue by-products as a source of bioactive phytochemicals with antioxidant, antimicrobial, and repellent effects against the stored-grain pest Tribolium castaneum was examined. Results showed that the enzymatic pretreatment increased the extraction yield of essential oil by 400, 417, and 478% in hemicellulase-, cellulase-, and viscozyme-treated samples, respectively. Phenylpropanoids including methyl cinnamate, methyl eugenol, eugenol and estragol were found as the main components, and were particularly abundant in cellulase-treated samples. From the hydrodistilled residue of enzyme-treated samples, better recoveries of total phenols (TPC) (258.3-470.9 mg GAE/g extract) and flavonoids (TFC) (59.4-94.3 mg QE/g extract) were observed. Using the DPPH, ABTS, and FRAP assays, a strong antioxidant activity of the rosmarinic-rich extract was observed. Such an activity which was mediated through electron transfer mechanism was highly correlated with the TPC, TFC and rosmarinic acid content. The in vitro bioassay showed that methanol extract (6.29 and 12.58 mu L/cm(2)) had repellent activity against the stored-grain pest Tribolium castaneum. These results suggest the potential of enzyme pretreatment to promote the use of hydrodistilled residue by-products as a valuable source of natural antioxidants and repellents ingredients. (C) 2020 Published by Elsevier B.V. on behalf of King Saud University.

About Methyl 3-phenyl-2-propenoate, If you have any questions, you can contact Mahmoudi, H; Marzouki, M; M’Rabet, Y; Mezni, M; Ouazzou, AA; Hosni, K or concate me.. Recommanded Product: 103-26-4

Reference:
Article; Weng, Shiue-Shien; Ke, Chih-Shueh; Chen, Fong-Kuang; Lyu, You-Fu; Lin, Guan-Ying; Tetrahedron; vol. 67; 9; (2011); p. 1640 – 1648;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Authors Li, Z; Guo, CJ; Chen, J; Yao, YM; Luo, YJ in WILEY published article about CATALYZED DIRECT AMIDATION; EARTH-METAL AMIDES; UNACTIVATED ESTERS; MILD AMIDATION; BOND FORMATION; ALDEHYDES; HYDROPHOSPHONYLATION; HYDROAMINATION; AMINOLYSIS; NITRILES in [Li, Zhao; Guo, Chenjun; Luo, Yunjie] Ningbo Univ, Sch Mat Sci & Chem Engn, Ningbo 315211, Peoples R China; [Li, Zhao; Yao, Yingming] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China; [Chen, Jue] Zhejiang Univ, Sch Biol & Chem Engn, Ningbo Inst Technol, Ningbo 315100, Peoples R China in 2020, Cited 52. HPLC of Formula: C10H10O2. The Name is Methyl 3-phenyl-2-propenoate. Through research, I have a further understanding and discovery of 103-26-4

The development of catalysts capable of catalyzing amidation of esters with amines to construct amides under mild conditions is of great importance. Compared to aliphatic amines, the direct catalytic amidation of esters with less nucleophilic aromatic amines is rather difficult. Employing simple lanthanide tris (amide) complexes Ln[N (SiMe3)(2)](3)(mu-Cl)Li (THF)(3) as the catalysts, it was found a broad range of aromatic amines and esters were efficiently converted into various amides in good yields under mild conditions. A plausible mechanism for this transformation was experimentally supported as starting from an amide exchange reaction between the lanthanide tris (amide) complex and the substrate amine.

HPLC of Formula: C10H10O2. About Methyl 3-phenyl-2-propenoate, If you have any questions, you can contact Li, Z; Guo, CJ; Chen, J; Yao, YM; Luo, YJ or concate me.

Reference:
Article; Weng, Shiue-Shien; Ke, Chih-Shueh; Chen, Fong-Kuang; Lyu, You-Fu; Lin, Guan-Ying; Tetrahedron; vol. 67; 9; (2011); p. 1640 – 1648;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

An article Molecular and phytochemical stability of long term micropropagated greater galanga (Alpinia galanga) revealed suitable for industrial applications WOS:000527912200018 published article about CORONARIUM J. KOENIG; BIOCHEMICAL FIDELITY; ANTIOXIDANT ACTIVITY; PLANT-REGENERATION; CLONAL PROPAGATION; PROTOCOL in [Sahoo, Suprava; Singh, Subhashree; Sahoo, Ambika; Sahoo, Bhaskar Chandra; Jena, Sudipta; Kar, Basudeba; Nayak, Sanghamitra] Siksha O Anusandhan Deemed Be Univ, Ctr Biotechnol, Bhubaneswar 751003, Odisha, India in 2020.0, Cited 47.0. Product Details of 103-26-4. The Name is Methyl 3-phenyl-2-propenoate. Through research, I have a further understanding and discovery of 103-26-4

Alpinia galanga is a wild medicinal plant having tremendous industrial importance. However, lack of quality planting material in natural resources restricted its wide exposure in industrial sector. Thus, a standardised protocol for stable supply of quality planting materials with genetical and phytochemical stability is need of the hour to meet commercial requirements. The current study reports an efficient protocol to regenerate micropropagated plantlets with long term stability in molecular as well as phytochemical level. Murashige and Skoog (MS) media augmented with 3 mg/l 6-Benzyladenine (BA), 3 mg/l Kinetin (Kn) and 1 mg/l Napthalene Acetic acid (NAA) was found optimum for regeneration and multiplication of plantlets. In order to establish genetic stability molecular marker-based profiling of micropropagated plants were done at every 6 months intervals up to 6 years. Monomorphic banding pattern were found that are identical to the mother plants. After six years of in vitro conservation, the regenerated plants were transplanted to the field and its drug yielding potential were evaluated through phytoconstituent analysis along with bioactivity studies. A comparative Gas chromatography (GC) and mass spectroscopy (MS) analysis of essential oils showed no significant differences in phytoconstituents between the conventional and in vitro propagated plants. The bioactivities like antioxidant, antimicrobial and anticancerous study along with total phenolic and total flavonoid content of in vitro plants were compared with mother plants and found stable with negligible variation. Thus, the present study has enough significance towards commercial exploitation of A. galanga with phytochemical and molecular stability.

Product Details of 103-26-4. About Methyl 3-phenyl-2-propenoate, If you have any questions, you can contact Sahoo, S; Singh, S; Sahoo, A; Sahoo, BC; Jena, S; Kar, B; Nayak, S or concate me.

Reference:
Article; Weng, Shiue-Shien; Ke, Chih-Shueh; Chen, Fong-Kuang; Lyu, You-Fu; Lin, Guan-Ying; Tetrahedron; vol. 67; 9; (2011); p. 1640 – 1648;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Application In Synthesis of Methyl 3-phenyl-2-propenoate. Recently I am researching about PERMEABILITY, Saw an article supported by the Sichuan Science and Technology Program [2019JDRC0074]; National Science and Technology Major Project of the Ministry of Science and Technology of China [2018Z-X09721004009-002]; China Postdoctoral Science FoundationChina Postdoctoral Science Foundation [2018M631071]. Published in PHARMACOTHERAPY GROUP in BENIN CITY ,Authors: Zhang, Q; Li, RL; Liu, J; Peng, W; Gao, YX; Wu, CJ; Pu, XF. The CAS is 103-26-4. Through research, I have a further understanding and discovery of Methyl 3-phenyl-2-propenoate

Purpose: To investigate by in silico screening the anti-inflammatory constituents of Cinnamomum cassia twigs. Methods: Information on the constituents of C. cassia twigs was retrieved from the online Traditional Chinese Medicines (TCM) database and literature. Inflammation-related target proteins were identified from DrugBank, Online Mendelian Inheritance in Man (OMIM), Therapeutic Target Database (TTD), Genetic Association Database (GAD), and PharmGKB. The identified compounds were filtered by Lipinski’s rules with Discovery Studio software. The Libdock module was used to perform molecular docking; LibdockScores and default cutoff values for hydrogen bonds and van der Weals interactions were recorded. LibdockScores between the prototype ligand and target protein were set as the threshold; compounds with higher LibdockScores than threshold were regarded as active compounds. Cytoscape software was used to construct active constituent-target protein interaction networks. Results: Sixty-nine potential inflammatory constituents with good drug-like properties in C. cassia twigs were screened in silico based on molecular docking and network pharmacology analysis. JAK2, mPEGS-1, COX-2, IL-1 beta, and PPAR gamma were considered the five most important target proteins. Compounds such as methyl dihydromelilotoside, hierochin B, dihydromelilotoside, dehydrodiconiferyl alcohol, balanophonin, phenethyl (E)-3-[4-methoxyphenyl]-2-propenoate, quercetin, and luteolin each interacted with more than six of the selected target proteins. Conclusion: C. cassia twigs possess active compounds with good drug-like properties that can potentially be developed to treat inflammation with multi-components on multi-targets.

About Methyl 3-phenyl-2-propenoate, If you have any questions, you can contact Zhang, Q; Li, RL; Liu, J; Peng, W; Gao, YX; Wu, CJ; Pu, XF or concate me.. Application In Synthesis of Methyl 3-phenyl-2-propenoate

Reference:
Article; Weng, Shiue-Shien; Ke, Chih-Shueh; Chen, Fong-Kuang; Lyu, You-Fu; Lin, Guan-Ying; Tetrahedron; vol. 67; 9; (2011); p. 1640 – 1648;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Authors Sangon, S; Supanchaiyamat, N; Sherwood, J; McElroy, CR; Hunt, AJ in ROYAL SOC CHEMISTRY published article about BAYLIS-HILLMAN REACTION; BIO-BASED SOLVENTS; GAMMA-VALEROLACTONE; PROPYLENE CARBONATE; HECK REACTION; DIHYDROLEVOGLUCOSENONE CYRENE; MECHANISM; CHALLENGES; REACTIVITY; CATALYST in [Sangon, Suwiwat; Supanchaiyamat, Nontipa; Hunt, Andrew J.] Khon Kaen Univ, Fac Sci, Mat Chem Res Ctr, Dept Chem, Khon Kaen 40002, Thailand; [Sherwood, James; McElroy, Con R.] Univ York, Green Chem Ctr Excellence, Dept Chem, York YO10 5DD, N Yorkshire, England in 2020.0, Cited 44.0. COA of Formula: C10H10O2. The Name is Methyl 3-phenyl-2-propenoate. Through research, I have a further understanding and discovery of 103-26-4

There is a lot of interest in the development of new, safer and more sustainable polar aprotic solvents due to their importance in industrial applications and significant safety issues with the most commonly used examples. One such area of application is in pharmaceutically relevant C-C coupling reactions, where polar aprotic solvents are commonly used for solubility and to stabilise reaction intermediates. Although there are now a number of excellent alternatives in the literature, to date they have not been compared in a single study. This study demonstrates the effectiveness of the green solventsN-butylpyrrolidinone (NBP), gamma-valerolactone (GVL), propylene carbonate (PC) and dihydrolevoglucosenone (Cyrene) in Heck and Baylis-Hillman reactions. Good conversions and initial rates were observed in GVL and NBP in Heck reactions. Cyrene exhibited high initial rates of reaction and high yields in the Baylis-Hillman reaction. This demonstrates Cyrene to be a promising alternative polar aprotic solvent for this reaction.

COA of Formula: C10H10O2. About Methyl 3-phenyl-2-propenoate, If you have any questions, you can contact Sangon, S; Supanchaiyamat, N; Sherwood, J; McElroy, CR; Hunt, AJ or concate me.

Reference:
Article; Weng, Shiue-Shien; Ke, Chih-Shueh; Chen, Fong-Kuang; Lyu, You-Fu; Lin, Guan-Ying; Tetrahedron; vol. 67; 9; (2011); p. 1640 – 1648;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

An article Photostable Ruthenium(II) Isocyanoborato Luminophores and Their Use in Energy Transfer and Photoredox Catalysis WOS:000669536600013 published article about SUBSTITUTED BIPYRIDYL COMPLEXES; CHARGE-TRANSFER STATES; ALPHA-AMINO-ACIDS; VISIBLE-LIGHT; POLYPYRIDINE COMPLEXES; IRIDIUM(III) COMPLEXES; ELECTRON-TRANSFER; DECARBOXYLATIVE ARYLATION; PHOTOINDUCED ELECTRON; REDUCTIVE-ELIMINATION in [Schmid, Lucius; Prescimone, Alessandro; Wenger, Oliver S.] Univ Basel, Dept Chem, CH-4056 Basel, Switzerland; [Kerzig, Christoph] Johannes Gutenberg Univ Mainz, Dept Chem, D-55128 Mainz, Germany in 2021, Cited 154. SDS of cas: 103-26-4. The Name is Methyl 3-phenyl-2-propenoate. Through research, I have a further understanding and discovery of 103-26-4

Ruthenium(II) polypyridine complexes are among the most popular sensitizers in photocatalysis, but they face some severe limitations concerning accessible excited-state energies and photostability that could hamper future applications. In this study, the borylation of heteroleptic ruthenium(II) cyanide complexes with alpha-diimine ancillary ligands is identified as a useful concept to elevate the energies of photoactive metal-to-ligand charge-transfer (MLCT) states and to obtain unusually photorobust compounds suitable for thermodynamically challenging energy transfer catalysis as well as oxidative and reductive photoredox catalysis. B(C6F5)(3) groups attached to the CN- ligands stabilize the metal-based t(2g)-like orbitals by similar to 0.8 eV, leading to high (MLCT)-M-3 energies (up to 2.50 eV) that are more typical for cyclometalated iridium(III) complexes. Through variation of their alpha-diimine ligands, nonradiative excited-state relaxation pathways involving higher-lying metal-centered states can be controlled, and their luminescence quantum yields and MLCT lifetimes can be optimized. These combined properties make the respective isocyanoborato complexes amenable to photochemical reactions for which common ruthenium(II)-based sensitizers are unsuited, due to a lack of sufficient triplet energy or excited-state redox power. Specifically, this includes photoisomerization reactions, sensitization of nickel-catalyzed cross-couplings, pinacol couplings, and oxidative decarboxylative C-C couplings. Our work is relevant in the greater context of tailoring photoactive coordination compounds to current challenges in synthetic photochemistry and solar energy conversion.

About Methyl 3-phenyl-2-propenoate, If you have any questions, you can contact Schmid, L; Kerzig, C; Prescimone, A; Wenger, OS or concate me.. SDS of cas: 103-26-4

Reference:
Article; Weng, Shiue-Shien; Ke, Chih-Shueh; Chen, Fong-Kuang; Lyu, You-Fu; Lin, Guan-Ying; Tetrahedron; vol. 67; 9; (2011); p. 1640 – 1648;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

An article Coumaric acid derivatives as tyrosinase inhibitors: Efficacy studies through in silico, in vitro and ex vivo approaches WOS:000575792000006 published article about ANTIOXIDANT ACTIVITY; CAFFEIC ACID; MELANOGENESIS; EUGENOL; MELANIN; IMAGE; ESTER in [Varela, Marina Themoteo; Ferrarini, Marcio; Mercaldi, Vitoria Gallo; Fernandes, Joao Paulo S.] Univ Fed Sao Paulo, Inst Environm Chem & Pharmaceut Sci, Dept Pharmaceut Sci, Rua Sao Nicolau 210, BR-09913030 Diadema, SP, Brazil; [Sufi, Bianca da Silva; Padovani, Giovana; Sbrugnera Nazato, Lucas Idacir] Chemyun Quim Ltda, Res & Dev Dept, Av Independencia 1501, BR-18087101 Sorocaba, SP, Brazil in 2020.0, Cited 47.0. The Name is Methyl 3-phenyl-2-propenoate. Through research, I have a further understanding and discovery of 103-26-4. Formula: C10H10O2

p-Coumaric acid is a known inhibitor of tyrosinase, an enzyme involved in the initial steps of the melanin synthesis in human and other species. However, its low lipophilicity impairs its penetration through skin and efficacy as antimelanogenic agent indeed. Accordingly, this paper reports the assessment of several coumaric acid derivatives as tyrosinase inhibitors and antimelanogenic agents in in vitro, in silico and ex vivo assays. The compounds were designed with modifications in the aromatic and acid moieties of p-coumaric acid, being the coumarate esters the most promising derivatives. The compounds showed higher tyrosinase inhibitory activity (pIC(50), 3.7-4.2) than the parent acid, being compounds 1d, 1e and 1f the most potent inhibitors. Docking analysis showed that these esters are competitive inhibitors per se, and act independently of a redox mechanism as suggested by DPPH assays. Moreover, the esters showed efficacy in reducing the melanin deposition in human skin fragments at 0.1% concentration, especially compound le. In summary, there is an important equilibria between tyrosinase affinity and lipophilicity that must be considered to get effective antimelanogenic agents with adequate permeability in the skin.

Formula: C10H10O2. About Methyl 3-phenyl-2-propenoate, If you have any questions, you can contact Varela, MT; Ferrarini, M; Mercaldi, VG; Sufi, BD; Padovani, G; Nazato, LIS; Fernandes, JPS or concate me.

Reference:
Article; Weng, Shiue-Shien; Ke, Chih-Shueh; Chen, Fong-Kuang; Lyu, You-Fu; Lin, Guan-Ying; Tetrahedron; vol. 67; 9; (2011); p. 1640 – 1648;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

I found the field of Biochemistry & Molecular Biology; Plant Sciences very interesting. Saw the article Biosynthesis and tissue-specific partitioning of camphor and eugenol in Ocimum kilimandscharicum published in 2020.0. Safety of Methyl 3-phenyl-2-propenoate, Reprint Addresses Giri, AP (corresponding author), CSIR Natl Chem Lab, Div Biochem Sci, Pune 411008, Maharashtra, India.. The CAS is 103-26-4. Through research, I have a further understanding and discovery of Methyl 3-phenyl-2-propenoate

In Ocimum kilimandscharicum, the relative volatile composition of camphor in leaves was as high as 55%, while that of eugenol in roots was 57%. These metabolites were differentially partitioned between the aerial and root tissues. Global metabolomics revealed tissue-specific biochemical specialization, evident by the differential distribution of 2588 putative metabolites across nine tissues. Next-generation sequencing analysis indicated differential expression of 51 phenylpropanoid and 55 terpenoid pathway genes in aerial and root tissues. By integrating metabolomics with transcriptomics, the camphor biosynthesis pathway in O. kilimandscharicum was elucidated. In planta bioassays revealed the role of geranyl diphosphate synthase (gpps) and borneol dehydrogenase (bdh) in camphor biosynthesis. Further, the partitioning of camphor was attributed to tissue-specific gene expression of both the pathway entry point (gpps) and terminal (bdh) enzyme. Unlike camphor, eugenol accumulated more in roots; however, absence of the eugenol synthase gene in roots indicated long distance transport from aerial tissues. In silico co-expression analysis indicated the potential involvement of ATP-binding cassette, multidrug and toxic compound extrusion, and sugar transporters in eugenol transport. Similar partitioning was evident across five other Ocimum species. Overall, our work indicates that metabolite partitioning maybe a finely regulated process, which may have implications on plant growth, development, and defense.

About Methyl 3-phenyl-2-propenoate, If you have any questions, you can contact Singh, P; Kalunke, RM; Shukla, A; Tzfadia, O; Thulasiram, HV; Giri, AP or concate me.. Safety of Methyl 3-phenyl-2-propenoate

Reference:
Article; Weng, Shiue-Shien; Ke, Chih-Shueh; Chen, Fong-Kuang; Lyu, You-Fu; Lin, Guan-Ying; Tetrahedron; vol. 67; 9; (2011); p. 1640 – 1648;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

HPLC of Formula: C10H10O2. In 2019.0 J ORG CHEM published article about N-HETEROCYCLIC CARBENES; ARYLBORONIC ACIDS; BETA-BORATION; CARBONYL-COMPOUNDS; LIGANDS; HYDROGENATION; REDUCTION; PLANAR in [Miwa, Yuya; Kamimura, Takumi; Sato, Kiyoaki; Shishido, Daichi; Yoshida, Kazuhiro] Chiba Univ, Dept Chem, Grad Sch Sci, Inage Ku, Yayoi Cho, Chiba 2638522, Japan; [Yoshida, Kazuhiro] Chiba Univ, Mol Chiral Res Ctr, Inage Ku, Yayoi Cho, Chiba 2638522, Japan in 2019.0, Cited 39.0. The Name is Methyl 3-phenyl-2-propenoate. Through research, I have a further understanding and discovery of 103-26-4.

The potential of using chiral bicyclic NHC ligands that exhibit modularity was investigated in the Cu-catalyzed asymmetric borylation reaction of alpha,beta-unsaturated esters. After screening for ligands and optimization of the reaction conditions, the corresponding products were afforded with good enantioselectivities (up to 85% ee).

HPLC of Formula: C10H10O2. About Methyl 3-phenyl-2-propenoate, If you have any questions, you can contact Miwa, Y; Kamimura, T; Sato, K; Shishido, D; Yoshida, K or concate me.

Reference:
Article; Weng, Shiue-Shien; Ke, Chih-Shueh; Chen, Fong-Kuang; Lyu, You-Fu; Lin, Guan-Ying; Tetrahedron; vol. 67; 9; (2011); p. 1640 – 1648;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Computed Properties of C10H10O2. Canestrari, D; Cioffi, C; Biancofiore, I; Lancianesi, S; Ghisu, L; Ruether, M; O’Brien, J; Adamo, MFA; Ibrahim, H in [Canestrari, Daniele; Cioffi, Caterina; Biancofiore, Ilaria; Lancianesi, Stefano; Ghisu, Lorenza; Adamo, Mauro F. A.; Ibrahim, Hasim] Royal Coll Surgeons Ireland, CSCB, Dept Chem, 123 St Stephens Green, Dublin 2, Ireland; [Biancofiore, Ilaria] IRBM Sci Pk SpA, Dept Med Chem, Via Pontina 30-600, I-00071 Pomezia, RM, Italy; [Ruether, Manuel; O’Brien, John] Univ Dublin, Trinity Coll, Sch Chem, Trinity Biomed Sci Inst, Dublin 2, Ireland published Sulphide as a leaving group: highly stereoselective bromination of alkyl phenyl sulphides in 2019.0, Cited 72.0. The Name is Methyl 3-phenyl-2-propenoate. Through research, I have a further understanding and discovery of 103-26-4.

A conceptionally novel nucleophilic substitution approach to synthetically important alkyl bromides is presented. Using molecular bromine (Br-2), readily available secondary benzyl and tertiary alkyl phenyl sulphides are converted into the corresponding bromides under exceptionally mild, acid- and base-free reaction conditions. This simple transformation allows the isolation of elimination sensitive benzylic beta-bromo carbonyl and nitrile compounds in mostly high yields and purities. Remarkably, protic functionalities such as acids and alcohols are tolerated. Enantioenriched benzylic beta-sulphido esters, readily prepared by asymmetric sulpha-Michael addition, produce the corresponding inverted bromides with high stereoselectivities, approaching complete enantiospecificity at -40 degrees C. Significantly, the reported benzylic beta-bromo esters can be stored without racemisation for prolonged periods at -20 degrees C. Their synthetic potential was demonstrated by the one-pot preparation of gamma-azido alcohol (S)-5 in 90% ee. NMR studies revealed an initial formation of a sulphide bromine adduct, which in turn is in equilibrium with a postulated dibromosulphurane intermediate that undergoes C-Br bond formation.

About Methyl 3-phenyl-2-propenoate, If you have any questions, you can contact Canestrari, D; Cioffi, C; Biancofiore, I; Lancianesi, S; Ghisu, L; Ruether, M; O’Brien, J; Adamo, MFA; Ibrahim, H or concate me.. Computed Properties of C10H10O2

Reference:
Article; Weng, Shiue-Shien; Ke, Chih-Shueh; Chen, Fong-Kuang; Lyu, You-Fu; Lin, Guan-Ying; Tetrahedron; vol. 67; 9; (2011); p. 1640 – 1648;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics