Interesting scientific research on Methyl 3-phenyl-2-propenoate

About Methyl 3-phenyl-2-propenoate, If you have any questions, you can contact Niziol, J; Misiorek, M; Ruman, T or concate me.. COA of Formula: C10H10O2

An article Mass spectrometry imaging of low molecular weight metabolites in strawberry fruit (Fragaria x ananassa Duch.) cv. Primoris with Ag-109 nanoparticle enhanced target WOS:000458710000002 published article about AROMA COMPOUNDS; 2,5-DIMETHYL-4-HYDROXY-3(2H)-FURANONE FURANEOL; FLAVOR QUALITY; PHENOLIC-ACIDS; VITAMIN-C; CULTIVARS; PROANTHOCYANIDINS; IDENTIFICATION; BIOSYNTHESIS; ACCUMULATION in [Niziol, Joanna; Misiorek, Maria; Ruman, Tomasz] Rzeszow Univ Technol, Fac Chem, 6 Powstancow Warszawy Ave, PL-35959 Rzeszow, Poland in 2019.0, Cited 98.0. The Name is Methyl 3-phenyl-2-propenoate. Through research, I have a further understanding and discovery of 103-26-4. COA of Formula: C10H10O2

Strawberry (Fragaria x ananassa Duch., Rosaceae) is the subject of many research studies due to its numerous features such as unique taste, aroma and health qualities. The distribution of low molecular weight metabolites belonging to aldehydes, ketones, alcohols, esters, organic acids, phenolics, amino acids and sugars classes within strawberry fruit cross-section was studied using mass spectrometry imaging (MSI) method with Ag-109 nano-particle enhanced target ((AgNPET)-Ag-109). Correlation of distribution of over thirty compounds found in cross-section of strawberry with their biological function is also included.

About Methyl 3-phenyl-2-propenoate, If you have any questions, you can contact Niziol, J; Misiorek, M; Ruman, T or concate me.. COA of Formula: C10H10O2

Reference:
Article; Weng, Shiue-Shien; Ke, Chih-Shueh; Chen, Fong-Kuang; Lyu, You-Fu; Lin, Guan-Ying; Tetrahedron; vol. 67; 9; (2011); p. 1640 – 1648;,
Ester – Wikipedia,
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Name: Methyl 3-phenyl-2-propenoate. About Methyl 3-phenyl-2-propenoate, If you have any questions, you can contact Zhang, JW; Wang, Y; Feng, YX; Du, SS; Jia, LM or concate me.

An article Contact Toxicity and Repellent Efficacy of Essential Oil from Aerial Parts of Melaleuca bracteata and its Major Compositions against Three Kinds of Insects WOS:000649623700001 published article about CALLOSOBRUCHUS-CHINENSIS L.; INSECTICIDAL ACTIVITIES; CHEMICAL-COMPOSITION; SITOPHILUS-ORYZAE; DERMATOPHAGOIDES-FARINAE; BOTANICAL INSECTICIDES; CONSTITUENTS; BIOACTIVITIES; ANTIOXIDANT; GROWTH in [Zhang, Jiawei; Jia, Liming] Beijing Forestry Univ, Key Lab Silviculture & Conservat, Minist Educ, 35,Tsinghua East Rd, Beijing 100083, Peoples R China; [Wang, Yang; Feng, Yixi; Du, Shushan] Beijing Normal Univ, Fac Geog Sci, Beijing Key Lab Tradit Chinese Med Protect & Util, 19 Xinjiekouwai St, Beijing 100875, Peoples R China; [Jia, Liming] Beijing Forestry Univ, Natl Energy R&D Ctr Nonfood Biomass, 35,Tsinghua East Rd, Beijing 100083, Peoples R China in 2021.0, Cited 56.0. Name: Methyl 3-phenyl-2-propenoate. The Name is Methyl 3-phenyl-2-propenoate. Through research, I have a further understanding and discovery of 103-26-4

Synthetic insecticides, a traditional tool to avoid the reduction of stored-product due to insects, have emerged a serious of hazards to the environment for years, therefore, botanicals have entered people’s vision. This work aimed to present the essential oil composition of Melaleuca bracteata, and the contact as well as repellent activities against three stored-product insects, i.e. Lasioderma serricorne (Coleoptera: Ptinidae), Tribolium castaneum (Coleoptera: Tenebrionidae), and Sitophilus oryzae (Coleoptera: Curculionidae). For determining the composition, the analysis was performed by GC/FID and GC/MS. Among 11 identified compounds, the principal compounds were methyl eugenol (88.52 %) and methyl cinnamate (7.90 %). The essential oil demonstrated contact toxicity against L. serricorne, T. castaneum, and S. oryzae which LD50 values were 3.2, 22.6, and 20.4 mu g/adult, respectively. Methyl cinnamate was more effective than methyl eugenol. The repellent activity indicated that essential oil and major compositions of M. bracteata were effective against L. serricorne and T. castaneum, but no use for S. oryzae. In the contact assay, L. serricorne showed more sensitivity, however, in repellency assay, T. castaneum was susceptible. We seek to provide a new application of the popular ornamental plant, M. bracteata, and offer an alternative material to botanical insecticides development.

Name: Methyl 3-phenyl-2-propenoate. About Methyl 3-phenyl-2-propenoate, If you have any questions, you can contact Zhang, JW; Wang, Y; Feng, YX; Du, SS; Jia, LM or concate me.

Reference:
Article; Weng, Shiue-Shien; Ke, Chih-Shueh; Chen, Fong-Kuang; Lyu, You-Fu; Lin, Guan-Ying; Tetrahedron; vol. 67; 9; (2011); p. 1640 – 1648;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Why do aromatic interactions matter of compound:Methyl 3-phenyl-2-propenoate

About Methyl 3-phenyl-2-propenoate, If you have any questions, you can contact Yang, B; Ying, Y; Zou, J; Ge, SY; Zuo, LH or concate me.. Safety of Methyl 3-phenyl-2-propenoate

An article Comprehensive characterization and quantification of multiple components in Dan-Huang-Qu-Yu capsule using a multivariate data processing approach based on microwave-assisted extraction with UHPLC and Q Exactive quadrupole-orbitrap high-resolution mass spectrometry WOS:000470023400013 published article about LOCATIONS in [Yang, Bo; Ying, Yin; Ge, Shuyu] Tongde Hosp Zhejiang Prov, Dept Pharm, 234 Gucui Rd, Hangzhou 310012, Zhejiang, Peoples R China; [Zuo, Lihua] Zhengzhou Univ, Dept Pharm, Affiliated Hosp 1, Zhengzhou, Henan, Peoples R China; [Zou, Jie] 117th Hosp PLA, Dept Pharm, Hangzhou, Zhejiang, Peoples R China in 2019.0, Cited 20.0. Safety of Methyl 3-phenyl-2-propenoate. The Name is Methyl 3-phenyl-2-propenoate. Through research, I have a further understanding and discovery of 103-26-4

Dan-Huang-Qu-Yu capsule, a Chinese herbal medicine compound preparation, is widely used for chronic pelvic inflammatory disease. In this study, a rapid, selective, and sensitive microwave-assisted extraction ultra-high-performance liquid chromatography-Q Exactive quadrupole-orbitrap high-resolution mass spectrometry method was developed for analyzing its chemical compositions. A total of 85 compounds, including 22 flavonoids, 8 terpenoids, 5 quinones, 5 phthaleolactone, 23 organic acids, and 22 other compounds were identified from Dan-Huang-Qu-Yu capsule. Among them, 35 major compounds were unambiguously detected by comparing them with reference standards and selected as quality control markers, which were simultaneously determined in Dan-Huang-Qu-Yu capsule. The established method was successfully validated and applied for simultaneous determination of 35 bioactive compounds in Dan-Huang-Qu-Yu capsule from ten sample batches. The quantitative data of the analytes were analyzed by principal component analysis for quality assessment of Dan-Huang-Qu-Yu capsule. Six compounds (e. g., astragaloside IV, salvianolic acid B, ellagic acid, chlorogenic acid, N-butylidenephthalide, and luteolin) were screened out and regarded as chemical markers for quality control of Dan-Huang-Qu-Yu capsule. The established method has been proved to be a novel and useful tool for rapid research of Dan-Huang-Qu-Yu capsule. This research will provide reference for the scientific research of traditional Chinese medicines.

About Methyl 3-phenyl-2-propenoate, If you have any questions, you can contact Yang, B; Ying, Y; Zou, J; Ge, SY; Zuo, LH or concate me.. Safety of Methyl 3-phenyl-2-propenoate

Reference:
Article; Weng, Shiue-Shien; Ke, Chih-Shueh; Chen, Fong-Kuang; Lyu, You-Fu; Lin, Guan-Ying; Tetrahedron; vol. 67; 9; (2011); p. 1640 – 1648;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

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About Methyl 3-phenyl-2-propenoate, If you have any questions, you can contact Hajipour, AR; Khorsandi, Z; Abeshtian, Z or concate me.. Formula: C10H10O2

Authors Hajipour, AR; Khorsandi, Z; Abeshtian, Z in ELSEVIER published article about MIZOROKI-HECK; CO; NANOPARTICLES; CHEMISTRY; LIGANDS; HALIDES; OXIDE in [Hajipour, Abdol R.; Khorsandi, Zahra; Abeshtian, Zahra] Isfahan Univ Technol, Dept Chem, Esfahan 84156, Iran; [Hajipour, Abdol R.] Univ Wisconsin, Sch Med, Dept Neurosci, Madison, WI USA in 2019.0, Cited 29.0. Formula: C10H10O2. The Name is Methyl 3-phenyl-2-propenoate. Through research, I have a further understanding and discovery of 103-26-4

A novel, biodegradable and environmental friendly magnetic cross-linked chitosan fibers and its cobalt complex was prepared and characterized by various techniques such as FT-IR, SEM, EDX, Elemental mapping, TEM, TGA, XRD and VSM analysis. This palladium and phosphine-free catalyst was found as a highly active heterogeneous catalyst for Heck and Sonogashira reactions in green media. The catalyst was easily separated using an external magnet and the recovered catalyst was reused for six cycles without significant loss of catalytic activity.

About Methyl 3-phenyl-2-propenoate, If you have any questions, you can contact Hajipour, AR; Khorsandi, Z; Abeshtian, Z or concate me.. Formula: C10H10O2

Reference:
Article; Weng, Shiue-Shien; Ke, Chih-Shueh; Chen, Fong-Kuang; Lyu, You-Fu; Lin, Guan-Ying; Tetrahedron; vol. 67; 9; (2011); p. 1640 – 1648;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

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About Methyl 3-phenyl-2-propenoate, If you have any questions, you can contact Cheung, CW; Shen, N; Wang, SP; Ullah, A; Hu, XL; Ma, JA or concate me.. SDS of cas: 103-26-4

SDS of cas: 103-26-4. Recently I am researching about AMIDE BOND FORMATION; PEPTIDE COUPLING REAGENTS; SECONDARY AMIDES; CARBOXYLIC-ACIDS; TRANSAMIDATION; METAL; HYDROAMINATION; ACTIVATION; AMINES, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21225208, 21472137, 21532008]; National Basic Research Program of China (973 Program)National Basic Research Program of China [2014CB745100]; Tianjin University. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Cheung, CW; Shen, N; Wang, SP; Ullah, A; Hu, XL; Ma, JA. The CAS is 103-26-4. Through research, I have a further understanding and discovery of Methyl 3-phenyl-2-propenoate

Amides are ubiquitous molecules in nature and in synthetic chemistry. Here we report a convenient and efficient method to synthesize N-aryl amides via amidation of esters with nitroarenes. In the presence of manganese metal, this amidation proceeded smoothly without the need for additional catalysts or ligands. Various esters and nitroarenes are suitable substrates to afford a wide range of N-aryl amides, including bio-active molecules and intermediates to drug molecules.

About Methyl 3-phenyl-2-propenoate, If you have any questions, you can contact Cheung, CW; Shen, N; Wang, SP; Ullah, A; Hu, XL; Ma, JA or concate me.. SDS of cas: 103-26-4

Reference:
Article; Weng, Shiue-Shien; Ke, Chih-Shueh; Chen, Fong-Kuang; Lyu, You-Fu; Lin, Guan-Ying; Tetrahedron; vol. 67; 9; (2011); p. 1640 – 1648;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

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Application In Synthesis of Methyl 3-phenyl-2-propenoate. About Methyl 3-phenyl-2-propenoate, If you have any questions, you can contact Varela, MT; Ferrarini, M; Mercaldi, VG; Sufi, BD; Padovani, G; Nazato, LIS; Fernandes, JPS or concate me.

An article Coumaric acid derivatives as tyrosinase inhibitors: Efficacy studies through in silico, in vitro and ex vivo approaches WOS:000575792000006 published article about ANTIOXIDANT ACTIVITY; CAFFEIC ACID; MELANOGENESIS; EUGENOL; MELANIN; IMAGE; ESTER in [Varela, Marina Themoteo; Ferrarini, Marcio; Mercaldi, Vitoria Gallo; Fernandes, Joao Paulo S.] Univ Fed Sao Paulo, Inst Environm Chem & Pharmaceut Sci, Dept Pharmaceut Sci, Rua Sao Nicolau 210, BR-09913030 Diadema, SP, Brazil; [Sufi, Bianca da Silva; Padovani, Giovana; Sbrugnera Nazato, Lucas Idacir] Chemyun Quim Ltda, Res & Dev Dept, Av Independencia 1501, BR-18087101 Sorocaba, SP, Brazil in 2020.0, Cited 47.0. Application In Synthesis of Methyl 3-phenyl-2-propenoate. The Name is Methyl 3-phenyl-2-propenoate. Through research, I have a further understanding and discovery of 103-26-4

p-Coumaric acid is a known inhibitor of tyrosinase, an enzyme involved in the initial steps of the melanin synthesis in human and other species. However, its low lipophilicity impairs its penetration through skin and efficacy as antimelanogenic agent indeed. Accordingly, this paper reports the assessment of several coumaric acid derivatives as tyrosinase inhibitors and antimelanogenic agents in in vitro, in silico and ex vivo assays. The compounds were designed with modifications in the aromatic and acid moieties of p-coumaric acid, being the coumarate esters the most promising derivatives. The compounds showed higher tyrosinase inhibitory activity (pIC(50), 3.7-4.2) than the parent acid, being compounds 1d, 1e and 1f the most potent inhibitors. Docking analysis showed that these esters are competitive inhibitors per se, and act independently of a redox mechanism as suggested by DPPH assays. Moreover, the esters showed efficacy in reducing the melanin deposition in human skin fragments at 0.1% concentration, especially compound le. In summary, there is an important equilibria between tyrosinase affinity and lipophilicity that must be considered to get effective antimelanogenic agents with adequate permeability in the skin.

Application In Synthesis of Methyl 3-phenyl-2-propenoate. About Methyl 3-phenyl-2-propenoate, If you have any questions, you can contact Varela, MT; Ferrarini, M; Mercaldi, VG; Sufi, BD; Padovani, G; Nazato, LIS; Fernandes, JPS or concate me.

Reference:
Article; Weng, Shiue-Shien; Ke, Chih-Shueh; Chen, Fong-Kuang; Lyu, You-Fu; Lin, Guan-Ying; Tetrahedron; vol. 67; 9; (2011); p. 1640 – 1648;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

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About Methyl 3-phenyl-2-propenoate, If you have any questions, you can contact Mahmoudi, H; Marzouki, M; M’Rabet, Y; Mezni, M; Ouazzou, AA; Hosni, K or concate me.. SDS of cas: 103-26-4

An article Enzyme pretreatment improves the recovery of bioactive phytochemicals from sweet basil (Ocimum basilicum L.) leaves and their hydrodistilled residue by-products, and potentiates their biological activities WOS:000554775400010 published article about ASSISTED EXTRACTION; ANTIOXIDANT CAPACITY; CHEMICAL-COMPOSITION; ROSMARINIC ACID; ESSENTIAL OILS; BIOSYNTHESIS; QUALITY; PEPPER; YIELD in [Mahmoudi, Hela] Univ Tunis El Manar, Lab Prod Vegetale & Contraintes Environm, Campus Univ, Tunis 2092, Tunisia; [Marzouki, Moomen] Inst Natl Rech & Anal Phys Chim, Lab Mat Utiles, Sidi Thabet 2020, Tunisia; [M’Rabet, Yassine; Mezni, Mohamed; Hosni, Karim] Inst Natl Rech & Anal Phys Chim, Lab Subst Nat, Sidi Thabet 2020, Tunisia; [Ouazzou, Abdenour Ait] Univ Benyoucef Benkhedda, Lab Valorisat & Bioingn Ressources Nat, Algiers 1, Algeria in 2020.0, Cited 43.0. The Name is Methyl 3-phenyl-2-propenoate. Through research, I have a further understanding and discovery of 103-26-4. SDS of cas: 103-26-4

In the present study, the effect of enzyme pretreatment on essential oil recoveries from sweet basil (Ocimum basilicum L.) leaves was evaluated. Moreover, the consideration on the use of hydrodistilled residue by-products as a source of bioactive phytochemicals with antioxidant, antimicrobial, and repellent effects against the stored-grain pest Tribolium castaneum was examined. Results showed that the enzymatic pretreatment increased the extraction yield of essential oil by 400, 417, and 478% in hemicellulase-, cellulase-, and viscozyme-treated samples, respectively. Phenylpropanoids including methyl cinnamate, methyl eugenol, eugenol and estragol were found as the main components, and were particularly abundant in cellulase-treated samples. From the hydrodistilled residue of enzyme-treated samples, better recoveries of total phenols (TPC) (258.3-470.9 mg GAE/g extract) and flavonoids (TFC) (59.4-94.3 mg QE/g extract) were observed. Using the DPPH, ABTS, and FRAP assays, a strong antioxidant activity of the rosmarinic-rich extract was observed. Such an activity which was mediated through electron transfer mechanism was highly correlated with the TPC, TFC and rosmarinic acid content. The in vitro bioassay showed that methanol extract (6.29 and 12.58 mu L/cm(2)) had repellent activity against the stored-grain pest Tribolium castaneum. These results suggest the potential of enzyme pretreatment to promote the use of hydrodistilled residue by-products as a valuable source of natural antioxidants and repellents ingredients. (C) 2020 Published by Elsevier B.V. on behalf of King Saud University.

About Methyl 3-phenyl-2-propenoate, If you have any questions, you can contact Mahmoudi, H; Marzouki, M; M’Rabet, Y; Mezni, M; Ouazzou, AA; Hosni, K or concate me.. SDS of cas: 103-26-4

Reference:
Article; Weng, Shiue-Shien; Ke, Chih-Shueh; Chen, Fong-Kuang; Lyu, You-Fu; Lin, Guan-Ying; Tetrahedron; vol. 67; 9; (2011); p. 1640 – 1648;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Discover the magic of the 103-26-4

Category: esters-buliding-blocks. About Methyl 3-phenyl-2-propenoate, If you have any questions, you can contact Sangon, S; Supanchaiyamat, N; Sherwood, J; McElroy, CR; Hunt, AJ or concate me.

An article Direct comparison of safer or sustainable alternative dipolar aprotic solvents for use in carbon-carbon bond formation WOS:000562311200016 published article about BAYLIS-HILLMAN REACTION; BIO-BASED SOLVENTS; GAMMA-VALEROLACTONE; PROPYLENE CARBONATE; HECK REACTION; DIHYDROLEVOGLUCOSENONE CYRENE; MECHANISM; CHALLENGES; REACTIVITY; CATALYST in [Sangon, Suwiwat; Supanchaiyamat, Nontipa; Hunt, Andrew J.] Khon Kaen Univ, Fac Sci, Mat Chem Res Ctr, Dept Chem, Khon Kaen 40002, Thailand; [Sherwood, James; McElroy, Con R.] Univ York, Green Chem Ctr Excellence, Dept Chem, York YO10 5DD, N Yorkshire, England in 2020.0, Cited 44.0. Category: esters-buliding-blocks. The Name is Methyl 3-phenyl-2-propenoate. Through research, I have a further understanding and discovery of 103-26-4

There is a lot of interest in the development of new, safer and more sustainable polar aprotic solvents due to their importance in industrial applications and significant safety issues with the most commonly used examples. One such area of application is in pharmaceutically relevant C-C coupling reactions, where polar aprotic solvents are commonly used for solubility and to stabilise reaction intermediates. Although there are now a number of excellent alternatives in the literature, to date they have not been compared in a single study. This study demonstrates the effectiveness of the green solventsN-butylpyrrolidinone (NBP), gamma-valerolactone (GVL), propylene carbonate (PC) and dihydrolevoglucosenone (Cyrene) in Heck and Baylis-Hillman reactions. Good conversions and initial rates were observed in GVL and NBP in Heck reactions. Cyrene exhibited high initial rates of reaction and high yields in the Baylis-Hillman reaction. This demonstrates Cyrene to be a promising alternative polar aprotic solvent for this reaction.

Category: esters-buliding-blocks. About Methyl 3-phenyl-2-propenoate, If you have any questions, you can contact Sangon, S; Supanchaiyamat, N; Sherwood, J; McElroy, CR; Hunt, AJ or concate me.

Reference:
Article; Weng, Shiue-Shien; Ke, Chih-Shueh; Chen, Fong-Kuang; Lyu, You-Fu; Lin, Guan-Ying; Tetrahedron; vol. 67; 9; (2011); p. 1640 – 1648;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

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SDS of cas: 103-26-4. About Methyl 3-phenyl-2-propenoate, If you have any questions, you can contact Kong, DY; Moon, PJ; Lui, EKJ; Bsharat, O; Lundgren, RJ or concate me.

An article Direct reversible decarboxylation from stable organic acids in dimethylformamide solution WOS:000556568100044 published article about PYROLYSIS; CATALYSIS; ESTERS; CO2 in [Kong, Duanyang; Moon, Patrick J.; Lui, Erica K. J.; Bsharat, Odey; Lundgren, Rylan J.] Univ Alberta, Dept Chem, Edmonton, AB T6G 2G2, Canada in 2020.0, Cited 50.0. The Name is Methyl 3-phenyl-2-propenoate. Through research, I have a further understanding and discovery of 103-26-4. SDS of cas: 103-26-4

Many classical and emerging methodologies in organic chemistry rely on carbon dioxide (CO2) extrusion to generate reactive intermediates for bond-forming events. Synthetic reactions that involve the microscopic reverse-the carboxylation of reactive intermediates-have conventionally been undertaken using very different conditions. We report that chemically stable C(sp(3)) carboxylates, such as arylacetic acids and malonate half-esters, undergo uncatalyzed reversible decarboxylation in dimethylformamide solution. Decarboxylation-carboxylation occurs with substrates resistant to protodecarboxylation by Bronsted acids under otherwise identical conditions. Isotopically labeled carboxylic acids can be prepared in high chemical and isotopic yield by simply supplying an atmosphere of (CO2)-C-13 to carboxylate salts in polar aprotic solvents. An understanding of carboxylate reactivity in solution enables conditions for the trapping of aldehydes, ketones, and alpha,beta-unsaturated esters.

SDS of cas: 103-26-4. About Methyl 3-phenyl-2-propenoate, If you have any questions, you can contact Kong, DY; Moon, PJ; Lui, EKJ; Bsharat, O; Lundgren, RJ or concate me.

Reference:
Article; Weng, Shiue-Shien; Ke, Chih-Shueh; Chen, Fong-Kuang; Lyu, You-Fu; Lin, Guan-Ying; Tetrahedron; vol. 67; 9; (2011); p. 1640 – 1648;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

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About Methyl 3-phenyl-2-propenoate, If you have any questions, you can contact Terao, Y; Sugihara, S; Satoh, K; Kamigaito, M or concate me.. Category: esters-buliding-blocks

I found the field of Polymer Science very interesting. Saw the article 1:3 ABAA sequence-regulated substituted polymethylenes via alternating radical copolymerization of methyl cinnamate and maleic anhydride followed by post-polymerization reactions published in 2019.0. Category: esters-buliding-blocks, Reprint Addresses Satoh, K; Kamigaito, M (corresponding author), Nagoya Univ, Grad Sch Engn, Dept Mol & Macromol Chem, Chikusa Ku, Furo Cho, Nagoya, Aichi 4648603, Japan.; Satoh, K (corresponding author), Tokyo Inst Technol, Sch Mat & Chem Technol, Dept Chem Sci & Engn, Meguro Ku, 2-12-1 Ookayama, Tokyo 1528550, Japan.. The CAS is 103-26-4. Through research, I have a further understanding and discovery of Methyl 3-phenyl-2-propenoate

Methyl cinnamate (M-1) and maleic anhydride (M-2), which are both non-homopolymerizable 1,2-disubtituted vinyl monomers, were radically copolymerized in toluene to result in 1:1 alternating copolymers. The 1:1 alternating sequence was confirmed by not only the monomer reactivity ratios obtained by using the terminal model fitted by the Kelen-Tiidos method (r(1) = 0.0035, r(2) = 0.069) but also MALDI-TOF-MS analysis of the copolymers with controlled molecular weights and relatively narrow molecular weight distributions (M-w/M-n = 1.20), which were prepared by RAFT copolymerization using 2-cyano-2-propyl ethyl trithiocarbonate (CPETC) as the RAFT agent. The maleic anhydride unit was transformed into two methyl ester groups by hydrolysis followed by methylation. Since the propagation of methyl cinnamate occurred regioselectively via a styrenic radical, the methyl esterified copolymers possessed ABAA sequence-controlled substituted polymethylene structures (A: methyl ester, B: phenyl). The sequence-controlled substituted polymethylene showed good thermal properties (T-d5 = 323 degrees C, T-g >= 192 degrees C) due to the rigid main-chain structures, which possessed a phenyl group on every fourth main-chain carbon in the repeating units in addition to three methyl ester groups on the other main-chain carbons. Block copolymers consisting of the rigid substituted polymethylene and soft poly(methyl acrylate) were also synthesized by RAFT polymerization.

About Methyl 3-phenyl-2-propenoate, If you have any questions, you can contact Terao, Y; Sugihara, S; Satoh, K; Kamigaito, M or concate me.. Category: esters-buliding-blocks

Reference:
Article; Weng, Shiue-Shien; Ke, Chih-Shueh; Chen, Fong-Kuang; Lyu, You-Fu; Lin, Guan-Ying; Tetrahedron; vol. 67; 9; (2011); p. 1640 – 1648;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics