Category: 103-25-3

Computed Properties of C10H12O2. Recently I am researching about COUPLING REACTION; HYDROCARBONS; HALOGENATION; ACID; HALIDES; MILD; 9-MESITYL-10-METHYLACRIDINIUM; SUCCINIMIDYL; COMPLEXES; OXIDATION, Saw an article supported by the Ministry of Science and Technology of ChinaMinistry of Science and Technology, China [2017YFA0206903]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21861132004]; Strategic Priority Research Program of the Chinese Academy of ScienceChinese Academy of Sciences [XDB17000000]; Key Research Program of Frontier Sciences of the Chinese Academy of Science [QYZDY-SSW-JSC029]; K. C. Wong Education Foundation. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Xiang, M; Zhou, C; Yang, XL; Chen, B; Tung, CH; Wu, LZ. The CAS is 103-25-3. Through research, I have a further understanding and discovery of Methyl 3-phenylpropionate

By combining N-chlorosuccinimide (NCS)” as the safe chlorine source with Acr(+)-Mes as the photocatalyst, we successfully achieved benzylic C-H bond chlorination under visible light irradiation. Furthermore, benzylic chlorides could be converted to benzylic ethers smoothly in a one-pot manner by adding sodium methoxide. This mild and scalable chlorination method worked effectively for diverse toluene derivatives, especially for electron-deficient substrates. Careful mechanistic studies supported that NCS provided a hydrogen abstractor N-centered succinimidyl radical, which was responsible for the cleavage of the benzylic C-H bond, relying on the reducing ability of Acr(center dot)-Mes.

Computed Properties of C10H12O2. Welcome to talk about 103-25-3, If you have any questions, you can contact Xiang, M; Zhou, C; Yang, XL; Chen, B; Tung, CH; Wu, LZ or send Email.

Reference:
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Ester – Wikipedia,
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Recently I am researching about C-H ACTIVATION; GRIGNARD-REAGENTS; ELECTROCYCLIC REACTIONS; CONJUGATE ADDITION; SCALABLE SYNTHESIS; ATE COMPLEXES; REACTIVITY; ALKYL; SCOPE; CYCLOISOMERIZATION, Saw an article supported by the ICIQ International Ph.D. Mobility Program (Severo Ochoa Excellence Accreditation, Spanish Ministerio de Economia y Competitividad); MPGMax Planck Society. COA of Formula: C10H12O2. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Huang, L; Gu, YT; Furstner, A. The CAS is 103-25-3. Through research, I have a further understanding and discovery of Methyl 3-phenylpropionate

In the presence of simple iron salts, 2-pyridone derivatives react with Grignard reagents under mild conditions to give the corresponding 1,6-addition products; if the reaction medium is supplemented with an aprotic dipolar cosolvent after the actual addition step, the intermediates primarily formed succumb to ring opening, giving rise to non-thermodynamic Z,E-configured dienoic acid amide derivatives which are difficult to make otherwise. Control experiments as well as the isolation and crystallographic characterization of a (tricarbonyl)iron pyridone complex suggest that the active iron catalyst generated in situ exhibits high affinity to the polarized diene system embedded into the heterocyclic ring system of the substrates, which likely serves as the actual recognition element.

Welcome to talk about 103-25-3, If you have any questions, you can contact Huang, L; Gu, YT; Furstner, A or send Email.. COA of Formula: C10H12O2

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Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

An article Hydrosilane-Promoted Facile Deprotection of tert-Butyl Groups in Esters, Ethers, Carbonates, and Carbamates WOS:000459822800003 published article about SILANE-REDUCTION; HECK REACTIONS; PALLADIUM; CLEAVAGE; CLUSTER; POLYMERIZATION; ALDEHYDES; REMOVAL in [Ikeda, Takuya; Zhang, Zhenzhong; Motoyama, Yukihiro] Toyota Technol Inst, Dept Adv Sci & Technol, Nagoya, Aichi 4688511, Japan in 2019.0, Cited 22.0. Computed Properties of C10H12O2. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3

Combination of PdCl2 with 1,1,3,3-tetramethyldisiloxane in the presence of activated carbon was found to be an effective catalyst system for the cleavage reaction of C-O bond of O-t-Bu moieties. The present catalytic reaction offers a practical method for the deprotection of tert-butyl esters, tert-butyl ethers, O-Boc, and N-Boc derivatives under mild conditions. The addition of activated carbon in the reaction mixture was proved to be crucial for not only sustaining the catalytic activity but also trapping the palladium species after the reaction.

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Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

An article Aldehyde as a Traceless Directing Group for Regioselective C-H Alkylation Catalyzed by Rhodium(III) in Air WOS:000516667200008 published article about PARA-SELECTIVE ALKYLATION; ALIPHATIC-ALDEHYDES; BOND FUNCTIONALIZATION; CONJUGATE ADDITION; ACTIVATION; DECARBONYLATION; SALICYLALDEHYDES; HYDROACYLATION; ANNULATION; SECONDARY in [Chen, Si-Qi; Li, Xin-Ran; Fan, Juan; Liu, Zhong-Wen; Shi, Xian-Ying] Shaanxi Normal Univ, Sch Chem & Chem Engn, Key Lab Syngas Convers Shaanxi Prov,Minist Educ, Key Lab Macromol Sci Shaanxi Prov,Key Lab Appl Su, Xian 710062, Peoples R China; [Li, Chao-Jun] McGill Univ, Dept Chem, Montreal, PQ H3A 0B8, Canada in 2020.0, Cited 82.0. COA of Formula: C10H12O2. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3

The aromatic aldehyde as a traceless directing group for the regionselective C-H alkylation catalyzed by rhodium(III) under aerobic atmospheric conditions has been developed. The process involves an aldehyde assisted direct addition of C-H bond to unsaturated electrophiles of acrylates or acrylic acids, and the subsequent decarbonylation. A trace amount of water is found to favor the reaction.

Welcome to talk about 103-25-3, If you have any questions, you can contact Chen, SQ; Li, XR; Li, CJ; Fan, J; Liu, ZW; Shi, XY or send Email.. COA of Formula: C10H12O2

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Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

An article Celite-Polyaniline supported palladium catalyst for chemoselective hydrogenation reactions WOS:000464452800023 published article about SELECTIVE HYDROGENATION; HETEROGENEOUS CATALYST; PD NANOPARTICLES; FACILE SYNTHESIS; N-ALKYLATION; REDUCTION; ACID; EFFICIENT; SUZUKI; OXIDATION in [Patel, Heta A.; Rawat, Maitreyee; Patel, Arun L.; Bedekar, Ashutosh V.] Maharaja Sayajirao Univ Baroda, Fac Sci, Dept Chem, Vadodara 390002, India in 2019.0, Cited 110.0. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3. Safety of Methyl 3-phenylpropionate

Polyaniline coated on particles of celite is used as support to load palladium catalyst. This heterogenized Celite center dot PANI center dot Pd system, is used as an efficient catalyst for chemoselective hydrogenation reactions. The catalyst is characterized by usual spectral, analytical techniques and studied for hydrogenation reactions at ambient conditions. The mild reaction conditions allow the control over the reactions and excellent selectivity is achieved in number of conversions. Hydrogenation of a carbon-carbon double bond was favored over other polar pi-bond systems, while labile functional groups such as benzyl ether, benzyl esters, cyano, nitro and halogen remained unaffected. Primary amines were converted to N,N-dimethyl amines with formaldehyde, the double bond of coumarin was selectively hydrogenated without opening of the lactone functionality.

Safety of Methyl 3-phenylpropionate. Welcome to talk about 103-25-3, If you have any questions, you can contact Patel, HA; Rawat, M; Patel, AL; Bedekar, AV or send Email.

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Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

In 2020.0 CHEM-ASIAN J published article about TRANSITION-METAL-FREE; CARBON-DIOXIDE; MEDIATED CARBOXYLATION; CO2; PALLADIUM; CARBONYLATION; FUNCTIONALIZATION; ARYLPYRAZOLES; LACTONIZATION; ACTIVATION in [Saitou, Takanobu; Jin, Yushu; Isobe, Kotaro; Suga, Takuya; Takaya, Jun; Iwasawa, Nobuharu] Tokyo Inst Technol, Dept Chem, Meguro Ku, 2-12-1 O Okayama, Tokyo 1528551, Japan in 2020.0, Cited 83.0. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3. Quality Control of Methyl 3-phenylpropionate

The Rh-catalyzed direct carboxylation of alkenyl C-H bonds was achieved by using pyrazole as a removable directing group. In the presence of 5 mol% RhCl3 . 3H(2)O, 6 mol% P(Mes)(3), and 2 equiv. of AlMe2(OMe), the alkenyl C-H bond of various alkenylpyrazoles was directly carboxylated in good yields under CO2 atmosphere. Furthermore, several useful transformations of the pyrazole moiety of the product were achieved to afford synthetically useful carboxylic acid derivatives in good yields.

Welcome to talk about 103-25-3, If you have any questions, you can contact Saitou, T; Jin, YH; Isobe, K; Suga, T; Takaya, J; Iwasawa, N or send Email.. Quality Control of Methyl 3-phenylpropionate

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Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Product Details of 103-25-3. Bhattacharya, A; Shukla, PM; Kaushik, LK; Maji, B in [Bhattacharya, Aditya; Shukla, Pushpendra Mani; Kaushik, Lalit Kumar; Maji, Biswajit] Indira Gandhi Natl Tribal Univ, Dept Chem, Amarkantak 484886, Madhya Pradesh, India published Synthesis of chromans and kinetic resolution of 2-aryl-3-nitro-2H-chromenes via the NHC-bound azolium homoenolate pathway in 2019.0, Cited 60.0. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3.

Beyond the tandem oxa-Michael strategy, an N-heterocyclic carbene-catalyzed kinetic resolution approach to access highly diastereo- and enantioenriched 2-aryl-3-nitro-chromane derivatives has been developed. An efficient strategy for the kinetic resolution of racemic 2-aryl-3-nitro-2H-chromenes was also successfully achieved. This catalytic kinetic resolution method allows the synthetically valuable chiral scaffolds, chromane and 2H-chromene, to be accessed in a single catalytic and asymmetric transformation, through the NHC-bound azolium homoenolate pathway.

Welcome to talk about 103-25-3, If you have any questions, you can contact Bhattacharya, A; Shukla, PM; Kaushik, LK; Maji, B or send Email.. Product Details of 103-25-3

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Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

In 2020.0 ANGEW CHEM INT EDIT published article about BETA-KETO-ESTERS; CLICK CHEMISTRY; PHOSPHORYLATED NITRONE; ASYMMETRIC-SYNTHESIS; DICARBONYL COMPOUNDS; CATALYZED AZIDATION; HYDROGEN-PEROXIDE; ORGANIC AZIDES; ENOL ETHERS; IN-VITRO in [Uyanik, Muhammet; Sahara, Naoto; Tsukahara, Mayuko; Hattori, Yuhei; Ishihara, Kazuaki] Nagoya Univ, Grad Sch Engn, Chikusa Ku, Nagoya, Aichi 4648603, Japan in 2020.0, Cited 91.0. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3. SDS of cas: 103-25-3

We report high-performance I+/H(2)O(2)catalysis for the oxidative or decarboxylative oxidative alpha-azidation of carbonyl compounds by using sodium azide under biphasic neutral phase-transfer conditions. To induce higher reactivity especially for the alpha-azidation of 1,3-dicarbonyl compounds, we designed a structurally compact isoindoline-derived quaternary ammonium iodide catalyst bearing electron-withdrawing groups. The nonproductive decomposition pathways of I+/H(2)O(2)catalysis could be suppressed by the use of a catalytic amount of a radical-trapping agent. This oxidative coupling tolerates a variety of functional groups and could be readily applied to the late-stage alpha-azidation of structurally diverse complex molecules. Moreover, we achieved the enantioselective alpha-azidation of 1,3-dicarbonyl compounds as the first successful example of enantioselective intermolecular oxidative coupling with a chiral hypoiodite catalyst.

SDS of cas: 103-25-3. About Methyl 3-phenylpropionate, If you have any questions, you can contact Uyanik, M; Sahara, N; Tsukahara, M; Hattori, Y; Ishihara, K or concate me.

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Application In Synthesis of Methyl 3-phenylpropionate. Pattanaik, S; Chidambaram, G in [Pattanaik, Sandip; Chidambaram, Gunanathan] HBNI, Natl Inst Sci Educ & Res NISER, Sch Chem Sci, Bhubaneswar 752050, Khurda, India published Cobalt-catalysed selective synthesis of aldehydes and alcohols from esters in 2020.0, Cited 51.0. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3.

Efficient and selective reduction of esters to aldehydes and alcohols is reported in which a simple cobalt pincer catalyst catalyses both transformations using diethylsilane as a reductant. Remarkably, the reaction selectivity is controlled by the stoichiometry of diethylsilane.

Welcome to talk about 103-25-3, If you have any questions, you can contact Pattanaik, S; Chidambaram, G or send Email.. Application In Synthesis of Methyl 3-phenylpropionate

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Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Recommanded Product: Methyl 3-phenylpropionate. In 2019.0 RSC ADV published article about NATURAL-PRODUCTS; INVASION in [Li, Xiaojing; Wang, Na; Wang, Shuai; Wang, Hongmin] Liaocheng Univ, Sch Pharm, Lab Drug Discover & Design, Liaocheng 252000, Shandong, Peoples R China; [Li, Xiaojing] Shandong Univ, Sch Pharm, Minist Educ, Dept Med Chem,Key Lab Chem Biol, Jinan 250012, Shandong, Peoples R China; [Liu, Yihua; Ren, Shaoda] Liaocheng Peoples Hosp, Cent Lab, Liaocheng 252000, Shandong, Peoples R China; [Liu, Yuyu] Shandong Qidu Pharmaceut Co Ltd, Zibo 255400, Peoples R China; [Lie, Aihua] Liaocheng Peoples Hosp, Dept Obstet & Gynecol, Liaocheng 252000, Shandong, Peoples R China in 2019.0, Cited 23.0. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3.

Despite advances in ovarian cancer treatment, the five-year overall survival rate is less than 30% with the presence of cancer stem cells (CSCs). To develop CSC-targeting therapy, a series of 18 beta-glycyrrhetinic acid (GA) derivatives containing cinnamamide moiety have been designed, synthesized, and screened for their antiproliferative activity in SKOV3 and OVCAR3 cells. Most of the compounds exhibited stronger antiproliferative activity than GA, and compound 7c was the most active one. Further biological studies showed that compound 7c could induce apoptosis and suppress migration. In addition, compound 7c could not only observably decrease the colony formation and sphere formation ability, but also significantly reduce the CD44(+), CD133(+), and ALDH(+) subpopulation in SKOV3 and OVCAR3 cells. In conclusion, these results indicate that compound 7c is a promising anti-CSC agent for further anti-ovarian cancer studies.

Recommanded Product: Methyl 3-phenylpropionate. About Methyl 3-phenylpropionate, If you have any questions, you can contact Li, XJ; Liu, YH; Wang, N; Liu, YY; Wang, S; Wang, HM; Lie, AH; Ren, SD or concate me.

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics