Category: 103-25-3

Category: esters-buliding-blocks. In 2020.0 ANGEW CHEM INT EDIT published article about BETA-KETO-ESTERS; CLICK CHEMISTRY; PHOSPHORYLATED NITRONE; ASYMMETRIC-SYNTHESIS; DICARBONYL COMPOUNDS; CATALYZED AZIDATION; HYDROGEN-PEROXIDE; ORGANIC AZIDES; ENOL ETHERS; IN-VITRO in [Uyanik, Muhammet; Sahara, Naoto; Tsukahara, Mayuko; Hattori, Yuhei; Ishihara, Kazuaki] Nagoya Univ, Grad Sch Engn, Chikusa Ku, Nagoya, Aichi 4648603, Japan in 2020.0, Cited 91.0. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3.

We report high-performance I+/H(2)O(2)catalysis for the oxidative or decarboxylative oxidative alpha-azidation of carbonyl compounds by using sodium azide under biphasic neutral phase-transfer conditions. To induce higher reactivity especially for the alpha-azidation of 1,3-dicarbonyl compounds, we designed a structurally compact isoindoline-derived quaternary ammonium iodide catalyst bearing electron-withdrawing groups. The nonproductive decomposition pathways of I+/H(2)O(2)catalysis could be suppressed by the use of a catalytic amount of a radical-trapping agent. This oxidative coupling tolerates a variety of functional groups and could be readily applied to the late-stage alpha-azidation of structurally diverse complex molecules. Moreover, we achieved the enantioselective alpha-azidation of 1,3-dicarbonyl compounds as the first successful example of enantioselective intermolecular oxidative coupling with a chiral hypoiodite catalyst.

Welcome to talk about 103-25-3, If you have any questions, you can contact Uyanik, M; Sahara, N; Tsukahara, M; Hattori, Y; Ishihara, K or send Email.. Category: esters-buliding-blocks

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

An article Cobalt-Catalyzed Enantioselective and Chemodivergent Addition of Cyclopropanols to Oxabicyclic Alkenes WOS:000471212600095 published article about RING-OPENING REACTIONS; BICYCLIC HYDRAZINES; BORONIC ACIDS; RHODIUM; ALKYNES; DESYMMETRIZATION; ANNULATION; ACCESS; SCOPE in [Yang, Junfeng; Sekiguchi, Yoshiya; Yoshikai, Naohiko] Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, Singapore 637371, Singapore; [Yang, Junfeng] Fudan Univ, Dept Chem, 2005 Songhu Rd, Shanghai 2000438, Peoples R China in 2019.0, Cited 71.0. Safety of Methyl 3-phenylpropionate. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3

We report herein cobalt-catalyzed enantioselective and chemodivergent reactions between a cyclopropanol and an oxabicyclic alkene via a cobalt homoenolate, which afford either an alkylative ring-opening product or a hydroalkylation product, with the counterion of the cobalt catalyst being a major chemoselectivity-controlling factor. A catalyst generated from cobalt(II) chloride and a chiral diphosphine promotes alkylative ring opening to afford 1,2-dihydronaphthalen-1-ol derivatives in good yields with high enantioselectivity. By contrast, a catalyst generated from cobalt(II) acetate and the same diphosphine ligand, with the assistance of methanol, selectively affords hydroalkylation products with retention of the bicyclic structure at a comparable level of enantioselectivity.

Safety of Methyl 3-phenylpropionate. Bye, fridends, I hope you can learn more about C10H12O2, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Recommanded Product: 103-25-3. In 2019.0 ORG BIOMOL CHEM published article about STEREOSELECTIVE REACTIONS; ALKYNES; ACID; CYCLOPROPENATION; CYCLOADDITION; AMPLIFICATION; ALDEHYDES; STRATEGY; RH in [Shi, Taoda; Teng, Shenghan] East China Normal Univ, Shanghai Engn Res Ctr Mol Therapeut & New Drug De, Sch Chem & Chem Engn, Shanghai 200062, Peoples R China; [Shi, Taoda; Zhang, Yueteng; Moore, Kohlson T.; Buckley, Thomas; Mason, Damian J.; Wang, Wei; Chapman, Eli] Univ Arizona, Coll Pharm, Dept Pharmacol & Toxicol, Tucson, AZ 85721 USA; [Reddy, Alavala Gopi Krishna; Hu, Wenhao] Sun Yat Sen Univ, Sch Pharmaceut Sci, Guangzhou, Guangdong, Peoples R China; [Guo, Xin] Wenzhou Med Univ, Sch Pharmaceut Sci, Wenzhou, Zhejiang, Peoples R China in 2019.0, Cited 46.0. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3.

We report a bifunctional Ag catalyst promoted intramolecular capture of oxonium ylides with alkynes for the enantioselective synthesis of 2,5-dihydrofurans. This represents unprecedented synergistic catalysis of a bifunctional Ag catalyst. Mechanistic studies revealed that [(R)-3,5-DM-BINAP](AgSbF6)(2) (9) is likely to be the active catalytic species and that the reaction involves second order kinetics with respect to 9, suggesting that two molecules of 9 are involved in the intramolecular trapping of a Ag-associated oxonium ylide with a Ag-activated alkyne. Based on our mechanistic hypothesis, we further optimized the reaction, rendering a facile approach to 2,5-dihydrofurans in good to excellent yields in a highly chemo- and enantioselective fashion.

Recommanded Product: 103-25-3. About Methyl 3-phenylpropionate, If you have any questions, you can contact Shi, TD; Teng, SH; Reddy, AGK; Guo, X; Zhang, YT; Moore, KT; Buckley, T; Mason, DJ; Wang, W; Chapman, E; Hu, WH or concate me.

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

In 2021.0 J CHEM RES published article about HIGHLY EFFICIENT; DIRECT AMIDATION; ESTERIFICATION; DERIVATIVES; OXIDATION; CATALYSIS; AMIDES; AMINES; GREEN; CONVERSION in [Wu, Xiaofang; Zhou, Lei; Li, Fangshao; Xiao, Jing] Hunan Univ Sci & Technol, Key Lab Theoret Organ Chem & Funct Mol, Minist Educ, Sch Chem & Chem Engn, Hunan Xiangtan Taoyuan Rd, Xiangtan 411201, Peoples R China in 2021.0, Cited 56.0. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3. COA of Formula: C10H12O2

A PCl3-mediated conversion of tert-butyl esters into esters and amides in one-pot under air is developed. This novel protocol is highlighted by the synthesis of skeletons of bioactive molecules and gram-scale reactions. Mechanistic studies revealed that this transformation involves the formation of an acid chloride in situ, which is followed by reactions with alcohols or amines to afford the desired products.

COA of Formula: C10H12O2. Welcome to talk about 103-25-3, If you have any questions, you can contact Wu, XF; Zhou, L; Li, FS; Xiao, J or send Email.

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

An article Trizaine-based dehydrative condensation reagents bearing carbon-substituents WOS:000518870900002 published article about TRIAZINES; AMINES in [Kitamura, Masanori; Komine, Sayaka; Yamada, Kohei; Kunishima, Munetaka] Kanazawa Univ, Fac Pharmaceut Sci, Inst Med Pharmaceut & Hlth Sci, Kakuma Machi, Kanazawa, Ishikawa 9201192, Japan in 2020.0, Cited 24.0. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3. HPLC of Formula: C10H12O2

Herein, we report on the synthesis of alkyl-, aryl-, and alkynyl-substituted chlorotriazines and their ammonium salts, and demonstrate their utility in dehydrative condensation reactions. Although the electrophilicity of these reagents is mainly dependent on the hybridization of the carbon-substituents, it was found that bulky 2,6-dimethylphenyl group-substituted reagents resulted in the highest product yields because of a slight increase in reagent electrophilicity and/or steric hindrance favorable for desired dehydrative condensation reactions. (C) 2019 Elsevier Ltd. All rights reserved.

Welcome to talk about 103-25-3, If you have any questions, you can contact Kitamura, M; Komine, S; Yamada, K; Kunishima, M or send Email.. HPLC of Formula: C10H12O2

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

SDS of cas: 103-25-3. In 2019.0 RSC ADV published article about NATURAL-PRODUCTS; INVASION in [Li, Xiaojing; Wang, Na; Wang, Shuai; Wang, Hongmin] Liaocheng Univ, Sch Pharm, Lab Drug Discover & Design, Liaocheng 252000, Shandong, Peoples R China; [Li, Xiaojing] Shandong Univ, Sch Pharm, Minist Educ, Dept Med Chem,Key Lab Chem Biol, Jinan 250012, Shandong, Peoples R China; [Liu, Yihua; Ren, Shaoda] Liaocheng Peoples Hosp, Cent Lab, Liaocheng 252000, Shandong, Peoples R China; [Liu, Yuyu] Shandong Qidu Pharmaceut Co Ltd, Zibo 255400, Peoples R China; [Lie, Aihua] Liaocheng Peoples Hosp, Dept Obstet & Gynecol, Liaocheng 252000, Shandong, Peoples R China in 2019.0, Cited 23.0. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3.

Despite advances in ovarian cancer treatment, the five-year overall survival rate is less than 30% with the presence of cancer stem cells (CSCs). To develop CSC-targeting therapy, a series of 18 beta-glycyrrhetinic acid (GA) derivatives containing cinnamamide moiety have been designed, synthesized, and screened for their antiproliferative activity in SKOV3 and OVCAR3 cells. Most of the compounds exhibited stronger antiproliferative activity than GA, and compound 7c was the most active one. Further biological studies showed that compound 7c could induce apoptosis and suppress migration. In addition, compound 7c could not only observably decrease the colony formation and sphere formation ability, but also significantly reduce the CD44(+), CD133(+), and ALDH(+) subpopulation in SKOV3 and OVCAR3 cells. In conclusion, these results indicate that compound 7c is a promising anti-CSC agent for further anti-ovarian cancer studies.

SDS of cas: 103-25-3. Bye, fridends, I hope you can learn more about C10H12O2, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

An article Cobalt-catalysed selective synthesis of aldehydes and alcohols from esters WOS:000544773800026 published article about CARBOXYLIC-ACIDS; REDUCTION; EFFICIENT; CARBONYL; HYDROSILYLATION; HYDROGENATION; HYDROBORATION; COMPLEXES; LIGAND; MILD in [Pattanaik, Sandip; Chidambaram, Gunanathan] HBNI, Natl Inst Sci Educ & Res NISER, Sch Chem Sci, Bhubaneswar 752050, Khurda, India in 2020.0, Cited 51.0. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3. Application In Synthesis of Methyl 3-phenylpropionate

Efficient and selective reduction of esters to aldehydes and alcohols is reported in which a simple cobalt pincer catalyst catalyses both transformations using diethylsilane as a reductant. Remarkably, the reaction selectivity is controlled by the stoichiometry of diethylsilane.

About Methyl 3-phenylpropionate, If you have any questions, you can contact Pattanaik, S; Chidambaram, G or concate me.. Application In Synthesis of Methyl 3-phenylpropionate

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Recently I am researching about DONOR-ACCEPTOR CYCLOPROPANES; DIELS-ALDER REACTIONS; DIASTEREOSELECTIVE SYNTHESIS; THIOCARBONYL COMPOUNDS; DERIVATIVES; CYCLIZATION; RING, Saw an article supported by the JSPS KAKENHIMinistry of Education, Culture, Sports, Science and Technology, Japan (MEXT)Japan Society for the Promotion of ScienceGrants-in-Aid for Scientific Research (KAKENHI) [JP15H05846, JP18H04263]; Platform Project for Supporting Drug Discovery and Life Science Research (Basis for Supporting Innovative Drug Discovery and Life Science Research (BINDS)) from AMED [JP17am0101091]; JSPSMinistry of Education, Culture, Sports, Science and Technology, Japan (MEXT)Japan Society for the Promotion of Science; [17H03972]; [16 K08166]. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Matsumoto, Y; Tsuji, T; Nakatake, D; Yazaki, R; Ohshima, T. The CAS is 103-25-3. Through research, I have a further understanding and discovery of Methyl 3-phenylpropionate. Recommanded Product: Methyl 3-phenylpropionate

The utility of thionoester as a 1,2-dipolarophile for [4+2] cycloaddition with cyclobutanones is described. The [4+2] cycloaddition reaction provided tetrahydrothiopyran, which is found in biologically active natural products, in high yield with high diastereoselectivity by using readily available TiCl4. This synthetic method was applicable to a wide range of thionoesters and cyclobutanones. The ketone and S,O-ketal functionalities of the product could be reduced with excellent diastereoselectivity. Furthermore, the C-O bond was transformed into a C-C bond, affording contiguous tetrasubstituted carbon centers.

Recommanded Product: Methyl 3-phenylpropionate. Bye, fridends, I hope you can learn more about C10H12O2, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

An article Aldehydes as potential acylating reagents for oxidative esterification by inorganic ligand-supported iron catalysis WOS:000480643800027 published article about AEROBIC OXIDATION; BUILDING-BLOCKS; ALCOHOLS; ESTERS; TRANSFORMATION; CONVERSION; COMPLEXES; HEME in [Yu, Han; Wei, Yongge] Tsinghua Univ, Dept Chem, Key Lab Organ Optoelect & Mol Engn, Minist Educ, Beijing 100084, Peoples R China; [Yu, Han; Wang, Jingjing; Wu, Zhikang; Zhao, Qixin; Dan, Demin; Han, Sheng] Shanghai Inst Technol, Sch Chem & Environm Engn, 100 Haiquan Rd, Shanghai 201418, Peoples R China; [Tang, Jiangjiang] Northwest A&F Univ, Coll Sci, Shaanxi Engn Ctr Bioresource Chem & Sustainable U, Yangling 712100, Shaanxi, Peoples R China; [Wei, Yongge] Peking Univ, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China in 2019.0, Cited 48.0. Recommanded Product: 103-25-3. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3

The oxidative esterification of various aldehydes with alcohols could be achieved by a heterogeneous iron(iii) catalyst supported on a ring-like POM inorganic ligand under mild conditions, affording the corresponding esters, including several drug molecules and natural products, in high yields. ESI-MS and control experiments demonstrated that POM-Fe-V(O) was the active catalytic species and the plausible mechanism was presented. More importantly, the 6th run of the iron catalyst recycles shows only a slight decrease in the yield.

Recommanded Product: 103-25-3. Bye, fridends, I hope you can learn more about C10H12O2, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

An article Reusable Heterogeneous Tungstophosphoric Acid-Derived Catalyst for Green Esterification of Carboxylic Acids WOS:000489986400007 published article about HETEROPOLY ACID; OXIDATIVE ESTERIFICATION; CARBON NITRIDE; FATTY-ACIDS; OLEIC-ACID; ALCOHOLS; NANOPARTICLES; DEHYDRATION; PERFORMANCE; ALDEHYDES in [Fiorio, Jhonatan Luiz; Braga, Adriano Henrique; Rossi, Liane Marcia] Univ Sao Paulo, Inst Quim, Dept Quim Fundamental, Av Prof Lineu Prestes 748, BR-05508000 Sao Paulo, SP, Brazil; [Fiorio, Jhonatan Luiz; Barbosa Guedes, Carmen Luisa] Univ Estadual Londrina, Dept Quim, Ctr Ciencias Exatas, BR-86057970 Londrina, PR, Brazil in 2019.0, Cited 69.0. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3. Safety of Methyl 3-phenylpropionate

Solid acid catalysts are environmentally friendly alternatives to the use of mineral acids in a range of applications, including the esterification of carboxylic acids. Here, a phosphorus- and nitrogen-doped, carbon-modified, fully heterogeneous solid acid catalyst was prepared by pyrolysis of a mixture of melamine and tungstophosphoric acid at 250, 500, and 750 degrees C under a nitrogen atmosphere provided. The structure of the different catalysts was evaluated by surface area measurements, XRD, XPS, Raman spectroscopy, elemental analysis, and electron microscopies. Pyrolysis at 500 degrees C created complex solid materials with larger surface area and significantly higher acidity, which can be attributed to WO3 formation on a heteroatomic (N,P)-carbon structure. The 500 degrees C-treated heterogeneous catalysts showed remarkably better activity for esterification of palmitic acid and were thus applied in the esterification of a broad range of carboxylic acids with good overall yields. Furthermore, the solid acid catalyst can be easily recovered and recycled up to eight times without significant loss of activity with no leaching of species to the reaction mixture.

Safety of Methyl 3-phenylpropionate. Welcome to talk about 103-25-3, If you have any questions, you can contact Fiorio, JL; Braga, AH; Guedes, CLB; Rossi, LM or send Email.

Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics