Category: 102-09-0

Direct synthesis of a high-density aviation fuel using a polycarbonate was written by Wang, Lulin;Han, Fengan;Li, Guangyi;Zheng, Min;Wang, Aiqin;Wang, Xiaodong;Zhang, Tao;Cong, Yu;Li, Ning. And the article was included in Green Chemistry in 2021.Quality Control of Diphenyl carbonate The following contents are mentioned in the article:

High-d. cyclic hydrocarbons were first synthesized with high carbon yields by a one-pot transfer hydrodeoxygenation of a polycarbonate (PC) using isopropanol as the solvent and hydrogen donor at the same time. RANEY nickel was found to be an effective catalyst for the conversion of the PC in isopropanol. Over it, the pure PC pellet was completely converted to a mixture of C₆-C₁₅ oxygenates, aromatics and cycloalkanes after the reaction was carried out at 463 K for 1 h. The catalytic performance of RANEY Ni was further improved after the introduction of solid acids as co-catalysts. Among the investigated solid acids, ultrastable Y (USY), a com. acidic zeolite, demonstrated the best promotion effect, which can be explained by its larger pore size and suitable acidity. Under the optimized conditions, an ∼75% carbon yield of C₆-C₁₅ cyclic hydrocarbons was achieved from the one-pot transfer hydrodeoxygenation of a chopped DVD disk under the co-catalysis of RANEY Ni and USY. According to our measurement, the C₆-C₁₅ cyclic hydrocarbon mixture as obtained has a high d. (0.94 g mL^-1), good volumetric net heat of combustion (NHOC) (41.5 MJ L^-1) and low f.p. (202 K-188 K). In real applications, it can be used as a potential substitute for currently used high-d. aviation fuels. This study involved multiple reactions and reactants, such as Diphenyl carbonate (cas: 102-09-0Quality Control of Diphenyl carbonate).

Diphenyl carbonate (cas: 102-09-0) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits, including apples, durians, pears, bananas, pineapples, and strawberries. Acyl chlorides and acid anhydrides alcoholysis is another way to produce esters. Acyl chlorides and acid anhydrides react with alcohols to produce esters. Anydrous conditions are recommended since both acyl chlorides and acid anhydrides react with water.Quality Control of Diphenyl carbonate

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Balancing the transesterification reactivity of isosorbide with diphenyl carbonate: preferential activation of exo-OH was written by Zhang, Ming;Tu, Yifei;Zhou, Zibo;Wu, Guozhang. And the article was included in Polymer Chemistry in 2020.Synthetic Route of C13H10O3 The following contents are mentioned in the article:

The exo-hydroxyl group (exo-OH) on isosorbide (ISB) has long been asserted as a highly reactive moiety compared with the endo-hydroxyl group (endo-OH). In this study, calculations based on d. functional theory and experiments without adding catalysts reveal that endo-OH has strong nucleophilic ability, and in the case of transesterification with di-Ph carbonate, the nucleophilic attack surmounts steric hindrance in rendering endo-OH more reactive than exo-OH. The kinetics of transesterification with different catalysts is investigated to determine the catalytic reactivity and mol. structure evolution. The results show that preferential activation of exo-OH moieties can be achieved either by reducing the coordination ability of catalytic cations (lg β1) or by enhancing the alkalinity of catalytic anions. Despite the low reactivity of exo-OH on ISB monomers, terminal exo-OH on carbonate oligomers exhibits higher reactivity than terminal endo-OH, justifying the exptl. fact that ISB-based polycarbonates (ISB-PCs) are mostly terminated by endo-OH. Balancing the reactivity between endo-OH and exo-OH can be promoted by increasing the reaction temperature, thus accelerating transesterification to a high equilibrium constant These findings help to clarify the mechanism of ISB transesterification and provide new strategies for the synthesis of high-mol.-weight ISB-PCs. This study involved multiple reactions and reactants, such as Diphenyl carbonate (cas: 102-09-0Synthetic Route of C13H10O3).

Diphenyl carbonate (cas: 102-09-0) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits, including apples, durians, pears, bananas, pineapples, and strawberries. Liquid esters of low volatility serve as softening agents for resins and plastics. Esters also include many industrially important polymers. Polymethyl methacrylate is a glass substitute sold under the names Lucite and Plexiglas; polyethylene terephthalate is used as a film (Mylar) and as textile fibres sold as Terylene, Fortrel, and Dacron.Synthetic Route of C13H10O3

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Effect of polymer molecular weight on structure and performance of PVDF hollow fiber membranes prepared via TIPS process with co-extrusion of solvent using triple orifice spinneret was written by Zhang, Pengfei;Fang, Chuanjie;Rajabzadeh, Saeid;Liu, Wenyi;Jia, Yuandong;Shen, Qin;Zhang, Lei;Wang, Shengyao;Kato, Noriaki;Matsuyama, Hideto. And the article was included in Journal of Membrane Science in 2021.Category: esters-buliding-blocks The following contents are mentioned in the article:

The co-extrusion of solvent at the outer layer of a dope solution in a thermally induced phase separation (TIPS) process has led to significant improvements in membrane characteristics, especially pure water permeability stability. This work investigates the effects of the poly(vinylidene fluoride) (PVDF) mol. weight and concentration on the characteristics of hollow fiber membranes prepared using this method. The PVDF mol. weight had little effect on the phase diagram of the PVDF/diphenyl carbonate (DPC) system, and effectively controlled the penetration depth and quantity of the extruded solvent (propylene carbonate (PC)) inside the polymer dope solution as well as the overall performance of the hollow fiber membranes. When the PVDF concentration was low, the PVDF mol. weight was crucial in controlling the penetration of the extruded solvent. For a PVDF/DPC system that led to the mainly bicontinuous structure which resulted from L-L phase separation, the penetration of the PC inside the membrane considerably changed the surface and sublayer structure from a bicontinuous structure with spherulite to a composite spherulite embedded in the bicontinuous structure and isolated spherulite structure. To obtain an appropriate membrane with considerable water permeability stability, it is necessary to choose an appropriate polymer mol. weight and concentration This study involved multiple reactions and reactants, such as Diphenyl carbonate (cas: 102-09-0Category: esters-buliding-blocks).

Diphenyl carbonate (cas: 102-09-0) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits. Liquid esters of low volatility serve as softening agents for resins and plastics. Esters also include many industrially important polymers. Polymethyl methacrylate is a glass substitute sold under the names Lucite and Plexiglas; polyethylene terephthalate is used as a film (Mylar) and as textile fibres sold as Terylene, Fortrel, and Dacron.Category: esters-buliding-blocks

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Backbone-Degradable (Co-)Polymers for Light-Triggered Drug Delivery was written by Rust, Tarik;Jung, Dimitri;Hoppe, Axel;Schoppa, Timo;Langer, Klaus;Kuckling, Dirk. And the article was included in ACS Applied Polymer Materials in 2021.Electric Literature of C13H10O3 The following contents are mentioned in the article:

In modern therapy, cutting side effects caused by the administration of drugs is one of the core challenges. One possible strategy is the delivery of a drug to the disease site by encapsulation into a polymeric matrix. Especially, light-responsive polymers are regarded as promising materials due to, e.g., the capability of tailored on-demand release in illuminated areas. In this work, a series of light-responsive backbone-degradable (co-)polymers were synthesized by polycondensation and polyaddition All obtained polymers showed rapid degradation in solution upon exposure to UV light as observed by size-exclusion chromatog. (SEC) and UV-visible (UV-vis) spectroscopy. Light-induced decomposition of films prepared from the polycarbonate was confirmed by UV-vis, surface plasmon resonance (SPR), and profilometry measurements. Depending on the incorporated comonomers, the functional co-polyurethanes exhibited either enhanced hydrophilicity or dual-responsiveness to light and redox environments, which was detected by SEC after treatment with a reducing agent. The formulation of nanoparticles from light-responsive polyurethanes proved the processability of the synthesized polymers, and dynamic light scattering (DLS) measurements confirmed the photo-induced degradation of the prepared particles. Water-soluble tetrazolium salt (WST-1) assays were carried out to evaluate the cytotoxic potential before and after irradiation This study involved multiple reactions and reactants, such as Diphenyl carbonate (cas: 102-09-0Electric Literature of C13H10O3).

Diphenyl carbonate (cas: 102-09-0) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Liquid esters of low volatility serve as softening agents for resins and plastics. Esters also include many industrially important polymers. Polymethyl methacrylate is a glass substitute sold under the names Lucite and Plexiglas; polyethylene terephthalate is used as a film (Mylar) and as textile fibres sold as Terylene, Fortrel, and Dacron.Electric Literature of C13H10O3

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Solvent-free, efficient synthesis of methyl phenyl carbonate over an SBA-15 loaded Pb-Bi bimetallic catalyst was written by Wang, Songlin;Jiang, Nan;Zhang, Qiying;Li, Huabo;Niu, Hongying;Chen, Tong;Wang, Gongying. And the article was included in Microporous and Mesoporous Materials in 2022.Computed Properties of C13H10O3 The following contents are mentioned in the article:

Me Ph carbonate (MPC) is one of the versatile carbonates; in particular, it is an important component in lithium-ion batteries. In recent years, the catalytic synthesis of MPC has become an important topic, but the development of highly active catalysts is still challenging. In this study, SBA-15-loaded nano-sized Pb-Bi catalysts with different Pb/Bi molar ratios were prepared by deposition-precipitation to improve the efficiency and selectivity. To investigate the relationship between the structure and performance of the catalysts, XRD, BET, SEM-EDS, HRTEM, H₂-TPR, and XPS characterization, as well as catalytic activity and stability tests, were conducted. Results revealed that Pb-Bi/SBA-15 can efficiently catalyze the synthesis of MPC under solvent-free conditions, with the highest catalytic activity obtained over 6 Pb-1Bi/SBA-15. SBA-15 with a large pore size and a high sp. surface area was suitable as catalyst carrier, and the average diameter of Pb-Bi oxide particles was ∼3.57 nm. The addition of Bi led to the improved dispersion of active components, which were highly and evenly dispersed on the SBA-15 surface. Furthermore, an appropriate proportion of Pb and Bi on SBA-15 was conducive to the considerable enhancement of the catalytic activity. Besides, Pb-Bi/SBA-15 also exhibited good durability and recyclability, making it a promising catalytic material for the synthesis of various carbonates. This study involved multiple reactions and reactants, such as Diphenyl carbonate (cas: 102-09-0Computed Properties of C13H10O3).

Diphenyl carbonate (cas: 102-09-0) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits. Esterification is the general name for a chemical reaction in which two reactants (typically an alcohol and an acid) form an ester as the reaction product. Esters are common in organic chemistry and biological materials.Computed Properties of C13H10O3

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Enhancing efficacy and safety of azelaic acid via encapsulation in cyclodextrin nanosponges: development, characterization and evaluation was written by Kumar, Anil;Rao, Rekha. And the article was included in Polymer Bulletin (Heidelberg, Germany) in 2021.Reference of 102-09-0 The following contents are mentioned in the article:

Abstract: Azelaic acid (AA), a promising agent for acne and hyperpigmentation disorders, is associated with side effects viz. rashes, skin irritation, dryness, burning and stinging. Its poor solubility also pose challenge in the development of suitable formulation. Therefore, this research was aimed to design cyclodextrin nanosponges (CDNS) of AA to address above-mentioned challenges. Herein, the fabrication of CDNS by melt method was demonstrated employing β-cyclodextrin (β-CD) as polymer and di-Ph carbonate (DPC) as a cross-linker. AA was loaded in CDNS via lyophilization and appropriately characterized by Fourier transform IR spectroscopy, thermogravimetric anal., X-ray powder diffraction and NMR. For morphol. evaluation, field emission scanning electron and transmission electron microscopy were also performed. The particle size of AANS was in nanorange, with acceptable zeta potential, low polydispersity index and delayed release. The safety of the nanoformulation was assessed using Human Epidermal Keratinocyte cell lines. Further, mol. docking studies for AA was carried out. In vitro antibacterial, antioxidant and antityrosinase assay were also conducted for prepared nanoformulation. The results of all the studies performed revealed that encapsulation of AA in nanosponges led to improvement in efficacy of drug in terms of solubility, release and safety, with adequate antimicrobial, antioxidant and antityrosinase activity. This study involved multiple reactions and reactants, such as Diphenyl carbonate (cas: 102-09-0Reference of 102-09-0).

Diphenyl carbonate (cas: 102-09-0) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Polyesters are important plastics, with monomers linked by ester moieties. Esterification is the general name for a chemical reaction in which two reactants (typically an alcohol and an acid) form an ester as the reaction product. Esters are common in organic chemistry and biological materials.Reference of 102-09-0

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

A smart porous wood-supported flower-like NiS/Ni conjunction with vitrimer co-effect as a multifunctional material with reshaping, shape-memory, and self-healing properties for applications in high-performance supercapacitors, catalysts, and sensors was written by Xiong, Chuanyin;Li, Bingbing;Liu, Heguang;Zhao, Wei;Duan, Chao;Wu, Haiwei;Ni, Yonghao. And the article was included in Journal of Materials Chemistry A in 2020.Application In Synthesis of Diphenyl carbonate The following contents are mentioned in the article:

Wood-based materials are attracting extensive attention for applications in energy storage due to their environmental friendliness and the presence of numerous channels in their structure. However, the poor conductivity and flexibility of wood restrict its application. Although some researchers have made several efforts to improve the conductivity of wood by carbonization, the wood-based materials become brittle instead of flexible. Moreover, the cycling stability of carbonized wood-based materials becomes very poor due to their falling off during the process of electrochem. energy storage. Herein, for the first time, a smart carbonized lignin-free wood (CLFW)@Ni-NiS/vitrimer(V) composite multifunctional material with good reshaping, shape-memory, and self-healing properties was designed and fabricated. When assembled to a sym. supercapacitor, the resultant CLFW@Ni-NiS/V hybrid showed not only the high gravimetric, areal, and volumetric energy densities of 38 W h kg-1, 687μW h cm-2, and 58 W h L-1 and simultaneously maintained the high power densities of 56 kW kg-1, 202 mW cm-2, and 39 kW L-1, but also significantly enhanced cycling stability, resp. In addition, CLFW@Ni-NiS/V presented good ORR and strain sensor properties. These outstanding advantages highlight the huge potential of smart wood-based materials with variable, shape-memory, and self-healing properties for applications in supercapacitors, catalysts, and sensors. This study involved multiple reactions and reactants, such as Diphenyl carbonate (cas: 102-09-0Application In Synthesis of Diphenyl carbonate).

Diphenyl carbonate (cas: 102-09-0) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits. Acyl chlorides and acid anhydrides alcoholysis is another way to produce esters. Acyl chlorides and acid anhydrides react with alcohols to produce esters. Anydrous conditions are recommended since both acyl chlorides and acid anhydrides react with water.Application In Synthesis of Diphenyl carbonate

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Microwave assisted synthesis and spectroscopic characterisation of diphenyl carbonate functionalised nanoporous starch was written by Swain, Yajnadutta;Badamali, Sushanta Kumar. And the article was included in Journal of Polymer Research in 2020.Application of 102-09-0 The following contents are mentioned in the article:

The functionalisation of potato starch using a greener and biol. important mol., i.e., di-Ph carbonate under microwave irradiation to obtain nanoporous di-Ph carbonate/starch composites is demonstrated. A series of spectroscopic techniques were used to investigate the bonding between di-Ph carbonate and starch, along with morphol. and nature of modified starch. The regular surface of pristine starch was noticeably modified to a porous structure as evidenced by FESEM and TEM. Both ¹H and ¹³C NMR studies revealed that the features of di-Ph carbonate were retained in modified starch. The line widths of ¹³C NMR signals were enhanced by 190 – 360 Hz referring to the crystalline nature of the modified form. FT IR studies showed bands at 1641 and 1774 cm^-1 which confirms the linkage of di-Ph carbonate with starch. FT IR studies supported a substantial removal of hydrogen bonding from the native starch surface after phenylation, referring to hydrophobic nature of modified starch. The shift of band position from 867 to 854 cm ^– 1 in Raman studies is attributed to the C-C-H or C-O-C bending linkage of carbon to di-Ph carbonate. The X-ray diffraction and thermogravimetric studies further supported the rigid and porous structure of modified starch. These modified starch possessing open structures is envisaged to act as a host materials for adsorption of hydropbobic mols. This study involved multiple reactions and reactants, such as Diphenyl carbonate (cas: 102-09-0Application of 102-09-0).

Diphenyl carbonate (cas: 102-09-0) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits. Esterification is the general name for a chemical reaction in which two reactants (typically an alcohol and an acid) form an ester as the reaction product. Esters are common in organic chemistry and biological materials.Application of 102-09-0

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Electrochemical study of functional additives for Li-ion batteries was written by Khodr, Zaynab;Mallet, Charlotte;Daigle, Jean-Christophe;Feng, Zimin;Amouzegar, Kamyab;Claverie, Jerome;Zaghib, Karim. And the article was included in Journal of the Electrochemical Society in 2020.Category: esters-buliding-blocks The following contents are mentioned in the article:

In the battery industry, the performance of lithium-ion batteries operating at a high voltage is enhanced by utilizing functional additives in electrolytes to achieve higher energy densities and longer lifetimes. These additives chem. stabilize the electrolyte and aid in the formation of a stable cathode electrolyte interphase (CEI). In this paper, the investigation of oxidative potentials of more than 100 additives, using d. functional theory calculations to determine the best candidates for CEI formation, is reported. The method was validated by comparing the calculated oxidation potentials and the exptl. data obtained using linear sweep voltammetry based on the evaluation of 18 candidates. Further electrochem. studies (AC impedance and cycling stability) on six selected additives were conducted. Among the tested additives, the addition of quinacridone at 0.03% weight concentration resulted in the formation of a less resistive surface film on the cathode in Li/Ni_0.5Mn_0.3Co_0.2O₂ coin cells. Moreover, the capacity retention in Gr/Ni_0.5Mn_0.3Co_0.2O coin cells increased from 62% to 77% after 200 cycles at 1C and approx. 4.4 V. The derived results suggest that the combination of the oxidation potential prediction with impedance study could be used as a powerful tool to properly and efficiently select CEI-forming additive candidates for improved battery performance. This study involved multiple reactions and reactants, such as Diphenyl carbonate (cas: 102-09-0Category: esters-buliding-blocks).

Diphenyl carbonate (cas: 102-09-0) belongs to esters. Carboxylic acid esters of low molecular weight are colourless, volatile liquids with pleasant odours, slightly soluble in water. Esterification is the general name for a chemical reaction in which two reactants (typically an alcohol and an acid) form an ester as the reaction product. Esters are common in organic chemistry and biological materials.Category: esters-buliding-blocks

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Stir bar sorptive extraction and automatic two-stage thermal desorption-gas chromatography-mass spectrometry for trace analysis of the byproducts from diphenyl carbonate synthesis was written by Liu, Tao;Yuan, Xiaoxue;Zhang, Gang;Hu, Jing;An, Jing;Chen, Tong;Wang, Gongying. And the article was included in Microchemical Journal in 2020.Recommanded Product: 102-09-0 The following contents are mentioned in the article:

In this study, a fast and sensitive method based on stir bar sorptive extraction (SBSE) and two-step thermal desorption coupled with online gas chromatog.-mass spectrometry was established to simultaneously analyze six trace byproducts [phenyl salicylate (PS), xanthone (XA), Me o-hydroxybenzoate (MS), 2-Me di-Ph carbonate (PTC), Me o-methoxybenzoate (MSME) and Ph o-methoxybenzoate (PSME)] generated in the process of di-Ph carbonate (DPC) synthesis. Under the optimal conditions, the six byproducts generated in the synthesis of DPC via transesterification were quant. analyzed by external standard method. The results showed that, within the range of 1.0-100 ng/L for all of the six transesterification byproducts, this method revealed good linearity with correlation coefficients (r) ≥0.997. The limits of detection (LODs) were between 0.054 ng/L and 0.253 ng/L, the relative standard deviations (RSD) were from 5.2% to 11.5%, and the recoveries were 81.6%-102.6% (n = 3). The method is simple, rapid and has a wide linear range, high accuracy, and sensitivity, as well as good stability. It is suitable for simultaneous, rapid and selective anal. of six trace byproducts in the process of DPC synthesis. It can also provide vigorous data support and industrialization guidance for the selection of transesterification conditions and research on the formation mechanisms, distribution regularity, and even control of transesterification byproducts. This study involved multiple reactions and reactants, such as Diphenyl carbonate (cas: 102-09-0Recommanded Product: 102-09-0).

Diphenyl carbonate (cas: 102-09-0) belongs to esters. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Liquid esters of low volatility serve as softening agents for resins and plastics. Esters also include many industrially important polymers. Polymethyl methacrylate is a glass substitute sold under the names Lucite and Plexiglas; polyethylene terephthalate is used as a film (Mylar) and as textile fibres sold as Terylene, Fortrel, and Dacron.Recommanded Product: 102-09-0

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics