Wang, Peng-Zi; He, Bin-Qing; Cheng, Ying; Chen, Jia-Rong; Xiao, Wen-Jing published the artcile< Radical C-C Bond Cleavage/Addition Cascade of Benzyl Cycloketone Oxime Ethers Enabled by Photogenerated Cyclic Iminyl Radicals>, Safety of (9Z,12Z)-Methyl octadeca-9,12-dienoate, the main research area is radical carbon carbon bond cleavage addition cascade reaction; cascade reaction benzyl cycloketone oxime ether alkene; photogenerated cyclic iminyl radical oxo nitrile preparation.
A light-driven, metal-free, and iminyl radical-mediated ring-opening C-C bond cleavage/addition cascade of O-4-methoxybenzyl oxime ethers and alkenes is described for the first time. The reaction shows a broad substrate scope and high functional group compatibility with both components, giving the corresponding valuable oxo nitriles in generally good yields. Key to the success of this protocol is the generation of cyclic iminyl radicals from the O-4-methoxybenzyl oxime ethers via a photocatalytic hydrogen atom transfer (HAT) process. The proposed main pathway is also supported by the preliminary mechanistic studies.
Organic Letters published new progress about Addition reaction. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Safety of (9Z,12Z)-Methyl octadeca-9,12-dienoate.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics