Category: esters-buliding-blocks. I found the field of Chemistry very interesting. Saw the article A Bipyridine-Palladium Derivative as General Pre-Catalyst for Cross-Coupling Reactions in Deep Eutectic Solvents published in 2019.0, Reprint Addresses Ramn, DJ (corresponding author), Univ Alicante, Fac Ciencias, Dept Quim Organ, Apdo 99, Alicante 03080, Spain.; Ramn, DJ (corresponding author), Univ Alicante, Fac Ciencias, ISO, Apdo 99, E-03080 Alicante, Spain.. The CAS is 103-26-4. Through research, I have a further understanding and discovery of Methyl 3-phenyl-2-propenoate.
A versatile and DES-compatible bipyridine palladium complex has been developed as a general pre-catalyst for different cross-coupling reactions (Hiyama, Suzuki-Miyaura, Heck-Mizoroki and Sonogashira) in deep eutectic solvents. Hydrogen bond capacity of the ligand allows to keep the excellent level of results previously obtained in classical organic solvents. Palladium pre-catalyst showed a high catalytic activity for many cross-coupling reactions, demonstrating a great versatility and applicability. Also, this methodology employs sustainable solvents as a reaction medium and highlights the potential of DES as alternative solvents in organometallic catalysis. The catalyst and DES were easily and successfully recycled. The formation of PdNPs in DES has been confirmed by TEM and XPS analysis and their role as catalyst by mercury test. The dynamic coordination of bipyridine-type ligand in the palladium complex formation has been studied via UV/Vis.
Category: esters-buliding-blocks. Welcome to talk about 103-26-4, If you have any questions, you can contact Saavedra, B; Gonzlez-Gallardo, N; Meli, A; Ramn, DJ or send Email.
Reference:
Article; Weng, Shiue-Shien; Ke, Chih-Shueh; Chen, Fong-Kuang; Lyu, You-Fu; Lin, Guan-Ying; Tetrahedron; vol. 67; 9; (2011); p. 1640 – 1648;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics