Recently I am researching about DECARBOXYLATIVE ALLYLIC ETHERIFICATION; OXIDATIVE DECARBOXYLATION; CARBOXYLIC-ACIDS; ANODIC-OXIDATION; ELECTROCHEMICAL SYNTHESIS; ALIPHATIC-ACIDS; MALONIC-ACID; ARYL; COMPLEXES; ELECTROLYSIS, Saw an article supported by the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) under Germany’s Excellence StrategyGerman Research Foundation (DFG) [EXC 2033-390677874-RESOLV, FOR 2982/1-UNODE, GO863/12-1]; BMBFFederal Ministry of Education & Research (BMBF); state of NRW (Center of Solvation Science ZEMOS). Published in NATURE RESEARCH in BERLIN ,Authors: Martinez, AM; Hayrapetyan, D; van Lingen, T; Dyga, M; Goossen, LJ. The CAS is 103-25-3. Through research, I have a further understanding and discovery of Methyl 3-phenylpropionate. Computed Properties of C10H12O2
Established electrodecarboxylative etherification protocols are based on Hofer-Moest-type reaction pathways. An oxidative decarboxylation gives rise to radicals, which are further oxidised to carbocations. This is possible only for benzylic or otherwise stabilised substrates. Here, we report the electrodecarboxylative radical-radical coupling of lithium alkylcarboxylates with 1-hydroxybenzotriazole at platinum electrodes in methanol/pyridine to afford alkyl benzotriazole ethers. The substrate scope of this electrochemical radical coupling extends to primary and secondary alkylcarboxylates. The benzotriazole products easily undergo reductive cleavage to the alcohols. They can also serve as synthetic hubs to access a wide variety of functional groups. This reaction prototype demonstrates that electrodecarboxylative C-O bond formation can be taken beyond the intrinsic substrate limitations of Hofer-Moest mechanisms.
Computed Properties of C10H12O2. Welcome to talk about 103-25-3, If you have any questions, you can contact Martinez, AM; Hayrapetyan, D; van Lingen, T; Dyga, M; Goossen, LJ or send Email.
Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
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