Awesome Chemistry Experiments For Methyl 3-phenyl-2-propenoate

Application In Synthesis of Methyl 3-phenyl-2-propenoate. Welcome to talk about 103-26-4, If you have any questions, you can contact Ham, JS; Park, B; Son, M; Roque, JB; Jurczyk, J; Yeung, CS; Baik, MH; Sarpong, R or send Email.

I found the field of Chemistry very interesting. Saw the article C-H/C-C Functionalization Approach to N-Fused Heterocycles from Saturated Azacycles published in 2020.0. Application In Synthesis of Methyl 3-phenyl-2-propenoate, Reprint Addresses Yeung, CS (corresponding author), Merck & Co Inc, Dept Discovery Chem, Boston, MA 02115 USA.; Baik, MH (corresponding author), Inst Basic Sci IBS, Ctr Catalyt Hydrocarbon Functionalizat, Daejeon 34141, South Korea.; Baik, MH (corresponding author), Korea Adv Inst Sci & Technol KAIST, Dept Chem, Daejeon 34141, South Korea.; Sarpong, R (corresponding author), Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA.. The CAS is 103-26-4. Through research, I have a further understanding and discovery of Methyl 3-phenyl-2-propenoate

Herein we report the synthesis of substituted indolizidines and related N-fused bicycles from simple saturated cyclic amines through sequential C-H and C-C bond functionalizations. Inspired by the Norrish-Yang Type II reaction, C-H functionalization of azacycles is achieved by forming alpha-hydroxy-beta-lactams from precursor alpha-ketoamide derivatives under mild, visible light conditions. Selective cleavage of the distal C(sp(2))-C(sp(3)) bond in alpha-hydroxy-beta-lactams using a Rh-complex leads to alpha-acyl intermediates which undergo sequential Rh-catalyzed decarbonylation, 1,4-addition to an electrophile, and aldol cyclization, to afford N-fused bicycles including indolizidines. Computational studies provide mechanistic insight into the observed positional selectivity of C-C cleavage, which depends strongly on the groups bound to Rh trans to the phosphine ligand.

Application In Synthesis of Methyl 3-phenyl-2-propenoate. Welcome to talk about 103-26-4, If you have any questions, you can contact Ham, JS; Park, B; Son, M; Roque, JB; Jurczyk, J; Yeung, CS; Baik, MH; Sarpong, R or send Email.

Reference:
Article; Weng, Shiue-Shien; Ke, Chih-Shueh; Chen, Fong-Kuang; Lyu, You-Fu; Lin, Guan-Ying; Tetrahedron; vol. 67; 9; (2011); p. 1640 – 1648;,
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