I found the field of Chemistry very interesting. Saw the article Selective oxidative esterification of alcohols over Au-Pd/graphene published in 2020.0. Safety of Methyl 3-phenyl-2-propenoate, Reprint Addresses Zheng, ZF (corresponding author), Chinese Acad Sci, State Key Lab Coal Convers, Inst Coal Chem, POB 165, Taiyuan 030001, Shanxi, Peoples R China.. The CAS is 103-26-4. Through research, I have a further understanding and discovery of Methyl 3-phenyl-2-propenoate
Direct selective oxidative esterification of readily available alcohols under mild conditions is an attractive approach to synthesis valuable esters. Developing high performance catalyst is the key factor to the efficient esters synthesis. We report graphene supported Au-Pd alloy catalyst exhibits excellent catalytic performance in the synthesis of methyl benzoate from benzyl alcohol and methanol, a turnover frequency (TOF) of 230 h(-1) and selectivity of 100% to methyl benzoate were achieved under 1 atm O-2 at 25 degrees C, which is superior to the majority of the state-of-the-art catalysts. Experimentally observed volcano-like reactivity trends and DFT calculations prove the outstanding performance was mainly ascribed to unique electronic structures of AuPd alloy catalyst for the adsorption and activation of reactant molecules. The catalytic reaction mechanism for interpretation of the structure-activity relationships of various catalysts at molecular level was investigated. The present study could help to unravel the synergistic effect of Au-Pd catalyst and provides a mild and efficient route for synthesis high-value esters in terms of green and sustainable chemistry.
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Reference:
Article; Weng, Shiue-Shien; Ke, Chih-Shueh; Chen, Fong-Kuang; Lyu, You-Fu; Lin, Guan-Ying; Tetrahedron; vol. 67; 9; (2011); p. 1640 – 1648;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics