Rheological properties of UHMWPE/HDPE blend gels and morphology and mechanical properties of gel-spun fibers was written by Yang, Wenxiao;Bin, Yuezhen;Wang, Hai;Ge, Zhonghui. And the article was included in Polymer Engineering & Science in 2021.Application In Synthesis of 2,2-Bis(((3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoyl)oxy)methyl)propane-1,3-diyl bis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoate) This article mentions the following:
To produce polyethylene (PE) fibers with relatively high tensile strength but low cost, ultra-high-mol.-weight polyethylene (UHMWPE)/high-d. polyethylene (HDPE) (UH) blend gels were prepared from paraffin oil and further fabricated into UH blend fibers by gel spinning. This research focused on the rheol. properties of UH blend gels with high solid contents (SCs) ranging from 25 to 100 g/L, as well as morphol. and mech. properties of resultant gel-spun UH blend fibers. The rheol. measurements indicated that the apparent viscosity, shear storage, and loss moduli of the UH blend gels were not markedly increased compared with those of the UHMWPE gel with much less SC. No obvious solid-liquid phase separation occurred in UH blend gels at a temperature above the sol-gel transition temperature UH blend fibers were prepared by drawing as-spun fibers (draw ratio [λ] = 3) at 110°C to λ = 15, 45, 60, and 80, resp. The orientation degree of fibril structure in UH blend fibers increased with increasing λ but the length of fibrils (Lfibril) showed a complex change. The Lfibril of UH blend fibers became larger due to chain arrangement in company with the transformation of the kebab structure to the extended shish structure when the λ was less than 45 but decreased during further elongation (λ = 60 and 80) because of fibril breakage and recrystallization The change in morphol. behavior led to the corresponding change in mech. properties of resultant gel-spun UH blend fibers. The tensile strength of gel-spun UH55-45 blend fiber (UHMWPE/HDPE = 5/5 and λ = 45) reached 15.6 cN/dtex, which could fulfill the requirement of mech. properties in common application. In the experiment, the researchers used many compounds, for example, 2,2-Bis(((3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoyl)oxy)methyl)propane-1,3-diyl bis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoate) (cas: 6683-19-8Application In Synthesis of 2,2-Bis(((3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoyl)oxy)methyl)propane-1,3-diyl bis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoate)).
2,2-Bis(((3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoyl)oxy)methyl)propane-1,3-diyl bis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoate) (cas: 6683-19-8) belongs to esters. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Cyclic esters are called lactones, regardless of whether they are derived from an organic or inorganic acid. One example of an organic lactone is γ-valerolactone.Application In Synthesis of 2,2-Bis(((3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoyl)oxy)methyl)propane-1,3-diyl bis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoate)
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics