One-pot ozonolytic synthesis of acyclic α,ω-bifunctional compounds from methyl 10-undecenoate and 10-undecen-1-ol was written by Legostaeva, Yu. V.;Botsman, L. P.;Nazarov, I. S.;Yakovleva, M. P.;Garifullina, L. R.;Khalikov, R. M.;Ishmuratov, G. Yu.. And the article was included in Russian Journal of Applied Chemistry in 2015.Category: esters-buliding-blocks This article mentions the following:
Transformations of peroxy products formed by ozonolysis of undecylenic acid derivatives (Me ester and hydride reduction product, 10-undecen-1-ol) in various protic and aprotic solvents (MeOH, PriOH, THF, 1: 5 AcOH-CH2Cl2 mixture), occurring under the action of such reductants as hydroxylamine and semicarbazide hydrochlorides, were studied. These reductants exhibit high performance and in some cases high chemoselectivity, which allowed the development of a number of one-pot procedures for the synthesis of acyclic α,ω-bifunctional compounds, the majority of which are widely used in medicine, perfumery, cosmetics, engineering, and chem. industry, e.g., as block synthons in targeted organic synthesis. In the experiment, the researchers used many compounds, for example, Dimethyl decanedioate (cas: 106-79-6Category: esters-buliding-blocks).
Dimethyl decanedioate (cas: 106-79-6) belongs to esters. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Esters contain a carbonyl center, which gives rise to 120° C–C–O and O–C–O angles. Unlike amides, esters are structurally flexible functional groups because rotation about the C–O–C bonds has a low barrier. Their flexibility and low polarity is manifested in their physical properties; they tend to be less rigid (lower melting point) and more volatile (lower boiling point) than the corresponding amides. Category: esters-buliding-blocks
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics