Tandem catalytic oxidative deacetylation of acetoacetic esters and heteroaromatic cyclizations was written by Ju, Yeming;Miao, Di;Yu, Ruiyang;Koo, Sangho. And the article was included in Organic & Biomolecular Chemistry in 2015.Synthetic Route of C10H13NO2 This article mentions the following:
One pot syntheses of furan, thiophene, and pyrrole were accomplished by oxidative deacetylation using Mn(III)/Co(II) catalysts and the Paal-Knorr reaction from 1,5-dicarbonyl compounds, which are prepared from the conjugate addition of Et acetoacetate to α,β-unsaturated carbonyl compounds The oxidative deacetylation and reductive cyclization of β-ketoesters derived from Et acetoacetate and o-nitrobenzyl bromides efficiently produced diversely substituted indoles. In the experiment, the researchers used many compounds, for example, Ethyl 3-amino-4-methylbenzoate (cas: 41191-92-8Synthetic Route of C10H13NO2).
Ethyl 3-amino-4-methylbenzoate (cas: 41191-92-8) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits. Liquid esters of low volatility serve as softening agents for resins and plastics. Esters also include many industrially important polymers. Polymethyl methacrylate is a glass substitute sold under the names Lucite and Plexiglas; polyethylene terephthalate is used as a film (Mylar) and as textile fibres sold as Terylene, Fortrel, and Dacron.Synthetic Route of C10H13NO2
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics