A new, modulated, oxidative ring-cleavage of α-nitro cycloalkanones by Oxone. Synthesis of α,ω-dicarboxylic acids and α,ω-dicarboxylic monomethyl esters was written by Ballini, Roberto;Curini, Massimo;Epifano, Francesco;Marcotullio, Maria Carla;Rosati, Ornelio. And the article was included in Synlett in 1998.COA of Formula: C13H24O4 This article mentions the following:
By the appropriate choice of the reaction conditions, Oxone produces the ring cleavage of α-nitro cycloalkanones affording good yields of α,ω-dicarboxylic acids and α,ω-dicarboxylic monomethyl esters, resp., regardless of the ring size and/or the presence of an alkyl group as substituent. In the experiment, the researchers used many compounds, for example, 12-Methoxy-12-oxododecanoic acid (cas: 3903-40-0COA of Formula: C13H24O4).
12-Methoxy-12-oxododecanoic acid (cas: 3903-40-0) belongs to esters. Esters are also usually derived from carboxylic acids. It may also be obtained by reaction of acid anhydride or acid halides with alcohols or by the reaction of salts of carboxylic acids with alkyl halides. Cyclic esters are called lactones, regardless of whether they are derived from an organic or inorganic acid. One example of an organic lactone is γ-valerolactone.COA of Formula: C13H24O4
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics