Fatty Acid Derived Renewable Platform Chemicals via Selective Oxidation Processes was written by von Czapiewski, Marc;Rhein, Michael;Meier, Michael A. R.. And the article was included in ACS Sustainable Chemistry & Engineering in 2018.Application of 106-79-6 This article mentions the following:
Highly efficient synthesis processes for the selective catalytic oxidation of unsaturated fatty acid Me esters (FAMEs) are described, leading to valuable renewable platform chems. Here keto-FAMEs derived from Me oleate and Me erucate were synthesized via a cocatalyst-free Wacker oxidation process using a high pressure reactor system. The catalytic system of palladium(II) chloride in dimethylacetamide/water enabled the oxidation of monounsaturated FAMEs in the presence of mol. oxygen as sole reoxidant with reduced amounts of solvent in shorter reaction time compared to previous reports. The high product selectivity is confirmed by two different synthesis approaches and the characterization of thereof derived products using mass spectrometry measurements (GC-MS, ESI-MS-MS). The obtained keto-FAMEs are used in a subsequent Baeyer-Villiger oxidations with m-CPBA, enabling the synthesis of diesters, thus allowing access to various platform chems. (e.g., hydroxy-esters, fatty alcs.). Moreover, an enone derivative, which can be obtained through selective photo peroxidation of Me oleate, is studied in the cocatalyst-free Wacker oxidation process leading to a 1,3-diketone. Addnl., the same enone is used in the Baeyer-Villiger oxidation with Oxone and m-CPBA as oxidant, allowing the highly selective synthesis of a vinyl acetate and an epoxy diester derivative, resp. In the experiment, the researchers used many compounds, for example, Dimethyl decanedioate (cas: 106-79-6Application of 106-79-6).
Dimethyl decanedioate (cas: 106-79-6) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Esters are more polar than ethers but less polar than alcohols. They participate in hydrogen bonds as hydrogen-bond acceptors, but cannot act as hydrogen-bond donors, unlike their parent alcohols. This ability to participate in hydrogen bonding confers some water-solubility.Application of 106-79-6
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics