The Use of Chiral BINAM NHC-Rh(III) Complexes in Enantioselective Hydrosilylation of 3-Oxo-3-arylpropionic Acid Methyl or Ethyl Esters was written by Xu, Qin;Gu, Xingxing;Liu, Sijia;Dou, Qinyu;Shi, Min. And the article was included in Journal of Organic Chemistry in 2007.Formula: C12H14O3 This article mentions the following:
Axially chiral BINAM N-heterocyclic carbene (NHC)-Rh(III) complexes were applied in the enantioselective hydrosilylation of 3-oxo-3-arylpropionic acid Me or Et esters. The reduction products 3-hydroxy-3-arylpropionic acid Me or Et esters could be obtained in good yields with good to excellent enantioselectivities under mild conditions. In the experiment, the researchers used many compounds, for example, Ethyl 3-oxo-3-(m-tolyl)propanoate (cas: 33166-79-9Formula: C12H14O3).
Ethyl 3-oxo-3-(m-tolyl)propanoate (cas: 33166-79-9) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits, including apples, durians, pears, bananas, pineapples, and strawberries. Esters contain a carbonyl center, which gives rise to 120° C–C–O and O–C–O angles. Unlike amides, esters are structurally flexible functional groups because rotation about the C–O–C bonds has a low barrier. Their flexibility and low polarity is manifested in their physical properties; they tend to be less rigid (lower melting point) and more volatile (lower boiling point) than the corresponding amides. Formula: C12H14O3
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics