Metal- and Additive-Free Intermolecular Aziridination of Olefins Using N-Boc-O-tosylhydroxylamine was written by Jat, Jawahar L.;Chandra, Dinesh;Kumar, Puneet;Singh, Vikram;Tiwari, Bhoopendra. And the article was included in Synthesis in 2022.Synthetic Route of C12H20O2 This article mentions the following:
A metal and additive-free stereospecific direct N-H and N-Me aziridination of inactivated olefins was disclosed using N-Boc- O-tosylhydroxylamine (TsONHBoc) as an aminating agent in hexafluoroisopropanol (HFIP) to gave aziridine derivatives such as I [R1 = H, Me; R2 = Et, Bz, octyl, etc.; R3 = H, Me; R4 = H, Me, Ph, etc.; R2R4 = (CH2)4, (CH2)6]. The use of TsONHBoc, which generates the free aminating agent in situ under the reaction conditions, had several inherent advantages over other similar agents, such as low cost, easy access, and stability (non-explosiveness) during storage over a longer time. In the experiment, the researchers used many compounds, for example, (E)-3,7-Dimethylocta-2,6-dien-1-yl acetate (cas: 105-87-3Synthetic Route of C12H20O2).
(E)-3,7-Dimethylocta-2,6-dien-1-yl acetate (cas: 105-87-3) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits. Cyclic esters are called lactones, regardless of whether they are derived from an organic or inorganic acid. One example of an organic lactone is γ-valerolactone.Synthetic Route of C12H20O2
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics