Electrochemical two-electron oxygen reduction reaction (ORR) induced aerobic oxidation of α-diazoesters was written by Ruan, Mengyao;Chen, Liang;Wen, Ziyang;Yang, Fan;Ma, Chao;Lu, Cuifen;Yang, Guichun;Gao, Meng. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2022.Recommanded Product: 587-88-2 This article mentions the following:
The recent progress in the oxidation of α-diazoesters R1C(=N2)C(O)OR2 (R1 = Ph, 2-naphthyl, benzo[d][1,3]dioxol-5-yl, etc.; R2 = Me, cyclohexyl, (tetrahydrofuran-2-yl)methyl, etc.) to α-ketoesters R1C(O)C(O)OR2 by in situ generated hydrogen peroxide via a two-electron oxygen reduction approach was described. A diverse collection of valuable α-ketoester products was obtained with moderate to high yields under an exogenous-oxidant-free and metal catalyst-free electrochem. conditions. In the experiment, the researchers used many compounds, for example, Ethyl 2-(4-fluorophenyl)acetate (cas: 587-88-2Recommanded Product: 587-88-2).
Ethyl 2-(4-fluorophenyl)acetate (cas: 587-88-2) belongs to esters. Carboxylic acid esters of low molecular weight are colourless, volatile liquids with pleasant odours, slightly soluble in water. Liquid esters of low volatility serve as softening agents for resins and plastics. Esters also include many industrially important polymers. Polymethyl methacrylate is a glass substitute sold under the names Lucite and Plexiglas; polyethylene terephthalate is used as a film (Mylar) and as textile fibres sold as Terylene, Fortrel, and Dacron.Recommanded Product: 587-88-2
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics