Exploring anomeric glycosylation of phosphoric acid: Optimization and scope for non-native substrates was written by Beswick, Laura;Ahmadipour, Sanaz;Hofman, Gert-Jan;Wootton, Hannah;Dimitriou, Eleni;Reynisson, Johannes;Field, Robert A.;Linclau, Bruno;Miller, Gavin J.. And the article was included in Carbohydrate Research in 2020.Quality Control of (2S,3R,4S,5S,6R)-6-(Acetoxymethyl)tetrahydro-2H-pyran-2,3,4,5-tetrayl tetraacetate This article mentions the following:
An improved access to glycosyl 1-phosphates has been developed,formed using a melt of an acetylated precursor with H3PO4 under high vacuum. Through preparation of the reaction components in a glove box and reducing the reaction temperature and equivalent of H3PO4, small scale access to the preparation of native and non-native glycosyl 1-phosphates in good yields and with facile purification is enabled. In the experiment, the researchers used many compounds, for example, (2S,3R,4S,5S,6R)-6-(Acetoxymethyl)tetrahydro-2H-pyran-2,3,4,5-tetrayl tetraacetate (cas: 4163-60-4Quality Control of (2S,3R,4S,5S,6R)-6-(Acetoxymethyl)tetrahydro-2H-pyran-2,3,4,5-tetrayl tetraacetate).
(2S,3R,4S,5S,6R)-6-(Acetoxymethyl)tetrahydro-2H-pyran-2,3,4,5-tetrayl tetraacetate (cas: 4163-60-4) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Polyesters are important plastics, with monomers linked by ester moieties. Acyl chlorides and acid anhydrides alcoholysis is another way to produce esters. Acyl chlorides and acid anhydrides react with alcohols to produce esters. Anydrous conditions are recommended since both acyl chlorides and acid anhydrides react with water.Quality Control of (2S,3R,4S,5S,6R)-6-(Acetoxymethyl)tetrahydro-2H-pyran-2,3,4,5-tetrayl tetraacetate
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics