Bazyar, Zahra published the artcileOn/Off O2 Switchable Photocatalytic Oxidative and Protodecarboxylation of Carboxylic Acids, Product Details of C9H10O2, the main research area is photocatalytic oxidative protodecarboxylation carboxylic acid.
Photoredox catalysis in recent years has manifested a powerful branch of science in organic synthesis. Although merging photoredox and metal catalysts has been a widely used method, switchable heterogeneous photoredox catalysis has rarely been considered. Herein, we open a new window to use a switchable heterogeneous photoredox catalyst which could be turned on/off by changing a simple stimulus (O2) for two opponent reactions, namely, oxidative and protodecarboxylation. Using this strategy, we demonstrate that Au@ZnO core-shell nanoparticles could be used as a switchable photocatalyst which has good catalytic activity to absorb visible light due to the localized surface plasmon resonance effect of gold, can decarboxylate a wide range of aromatic and aliphatic carboxylic acids, have multiple reusability, and are a reasonable candidate for synthesizing both aldehydes/ketones and alkane/arenes in a large-scale set up. Some biol. active mols. are also shown via examples of the direct oxidative and protodecarboxylation which widely provided pharmaceutical agents.
Journal of Organic Chemistry published new progress about Aldehydes Role: SPN (Synthetic Preparation), PREP (Preparation). 140-11-4 belongs to class esters-buliding-blocks, name is Benzyl acetate, and the molecular formula is C9H10O2, Product Details of C9H10O2.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics