Hayashi, Tamio’s team published research in Journal of the American Chemical Society in 121 | CAS: 126613-06-7

Journal of the American Chemical Society published new progress about 126613-06-7. 126613-06-7 belongs to esters-buliding-blocks, auxiliary class Chiral Diphenols, name is (R)-[1,1′-Binaphthalene]-2,2′-diyl bis(trifluoromethanesulfonate), and the molecular formula is C22H12F6O6S2, Safety of (R)-[1,1′-Binaphthalene]-2,2′-diyl bis(trifluoromethanesulfonate).

Hayashi, Tamio published the artcileRhodium-Catalyzed Asymmetric 1,4-Addition to 1-Alkenylphosphonates, Safety of (R)-[1,1′-Binaphthalene]-2,2′-diyl bis(trifluoromethanesulfonate), the publication is Journal of the American Chemical Society (1999), 121(49), 11591-11592, database is CAplus.

Rhodium-catalyzed asym. 1,4-addition is successfully applied to α,β-unsaturated phosphonates by use of triarylcyclotriboroxanes as arylating reagents in place of arylboronic acids. Thus, reaction of (E)-MeCH:CHP(O)(OEt)2 with phenylboroxine and 1 equivalent (to boron) of water in dioxane at 100° for 3 h gave 94% (S)-di-Et 2-phenylpropylphosphonate.

Journal of the American Chemical Society published new progress about 126613-06-7. 126613-06-7 belongs to esters-buliding-blocks, auxiliary class Chiral Diphenols, name is (R)-[1,1′-Binaphthalene]-2,2′-diyl bis(trifluoromethanesulfonate), and the molecular formula is C22H12F6O6S2, Safety of (R)-[1,1′-Binaphthalene]-2,2′-diyl bis(trifluoromethanesulfonate).

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics