Fiandanese, Vito published the artcileA general approach to the synthesis of monoolefinic insect sex pheromones of Z- or E-configuration, Application In Synthesis of 16974-11-1, the publication is Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999) (1985), 1115-19, database is CAplus.
Several insect sex pheromones and structurally related alkenes were prepared by 2 sequential cross-coupling reactions starting from (Z)- or (E)-BrCH:CHSPh [(Z)- or (E)-I]. Z-Isomers were prepared by sequential cross-coupling of (Z)-I with 2 Grignard reagents in the presence of [PdCl2(PPh3)2] (II) and [NiCl2(dppe)] [III; dppe = (Ph2PCH2)2], resp., whereas E-isomers were prepared by sequential cross-coupling of (E)-I with Grignard reagents in the presence of III. E.g., sequential treatment of (Z)-I with Me(CH2)12MgBr in the presence of II and Me(CH2)7MgBr in the presence of III in Et2O at room temperature gave 75% (Z)-Me(CH2)12CH:CH(CH2)7Me, the sex pheromone of the housefly.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999) published new progress about 16974-11-1. 16974-11-1 belongs to esters-buliding-blocks, auxiliary class Aliphatic Chain, name is (Z)-Dodec-9-en-1-yl acetate, and the molecular formula is C14H26O2, Application In Synthesis of 16974-11-1.
Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics