Huang, Zhiyan’s team published research in Journal of the American Chemical Society in 133 | CAS: 126613-06-7

Journal of the American Chemical Society published new progress about 126613-06-7. 126613-06-7 belongs to esters-buliding-blocks, auxiliary class Chiral Diphenols, name is (R)-[1,1′-Binaphthalene]-2,2′-diyl bis(trifluoromethanesulfonate), and the molecular formula is C22H12F6O6S2, Application In Synthesis of 126613-06-7.

Huang, Zhiyan published the artcileAn Enantioselective, Intermolecular α-Arylation of Ester Enolates To Form Tertiary Stereocenters, Application In Synthesis of 126613-06-7, the publication is Journal of the American Chemical Society (2011), 133(40), 15882-15885, database is CAplus and MEDLINE.

Some examples of enantioselective, intermol. α-arylation of ester enolates with aryl triflates to form tertiary stereocenters using a palladium catalyst supported by a new, (R)-H8-BINOL-derived monophosphine is presented . The usefulness of the reaction was demonstrated in a gram-scale synthesis of (S)-Naproxen in 92% ee.

Journal of the American Chemical Society published new progress about 126613-06-7. 126613-06-7 belongs to esters-buliding-blocks, auxiliary class Chiral Diphenols, name is (R)-[1,1′-Binaphthalene]-2,2′-diyl bis(trifluoromethanesulfonate), and the molecular formula is C22H12F6O6S2, Application In Synthesis of 126613-06-7.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics