Golubeva, Maria A. published the artcileHydroprocessing of furfural over in situ generated nickel phosphide based catalysts in different solvents, SDS of cas: 539-88-8, the main research area is nickel phosphide catalyst furfural hydrodeoxygenation solvent.
The present work is dedicated to the nickel phosphide based catalysts, containing particles, generated in situ in the reaction medium from the different catalytic systems. The present catalytic systems exhibited high activity in the hydroprocessing of furfural. Full conversion of furfural depending on conditions was reached after 0.5-3 h of reaction at 250-350°C. 2-methylfuran was obtained as a main product in toluene with the highest selectivity of 77%. Et levulinate and 2-methylfuran with selectivity of 40% and 38% resp. were obtained as main products in ethanol under different conditions. Different reaction medium and nickel phosphide precursors had an influence on the obtained phases of catalysts. Ni12P5 and Ni2P were obtained in toluene from oil-soluble precursors and Ni12P5 was obtained in ethanol from water-soluble precursors.
Applied Catalysis, A: General published new progress about Deoxidation. 539-88-8 belongs to class esters-buliding-blocks, name is Ethyl 4-oxopentanoate, and the molecular formula is C7H12O3, SDS of cas: 539-88-8.
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