Lunn, Richard D. J. published the artcileEncapsulation of Aromatic Compounds and a Non-Aromatic Herbicide into a Gadolinium-Based Metal-Organic Framework via the Crystalline Sponge Method, SDS of cas: 140-11-4, the main research area is encapsulation aromatic compound herbicide gadolinium MOF RUM2 crystalline sponge.
The crystalline sponge method (CSM) is a procedure that has the potential to remove the need to have good-quality single crystals of the target compound by soaking said compound into a crystalline metal-organic framework (MOF). To increase the range of compounds that can be employed with the CSM, a range of different MOFs must be investigated. In this study we have explored the use of a lanthanide-based MOF, RUM-2, recently shown to have potential as a CSM host. Specifically, we have successfully formed five novel inclusion complexes with the four aromatic guests: 2-phenylethanol, benzyl acetate, benzyl benzoate, and vanillin and the non-aromatic herbicide molinate. A detailed anal. of the effect of size on the positions guest mols. sit within the pores of the MOF was performed. The π···π, CH···π, hydrogen-bonding, and coordination host-guest and guest-guest interactions utilized in guest ordering were also investigated, and the disorder experienced by guest mols. was documented. Here we report five novel inclusion complexes within the crystalline sponge RUM-2, including the first com. herbicide to have its structure elucidated by the crystalline sponge method, molinate. A detailed investigation was performed into the effect of guest size on the position the guests sit within the MOF pores and the different intermol. interactions used for guest ordering.
Crystal Growth & Design published new progress about Crystal structure. 140-11-4 belongs to class esters-buliding-blocks, name is Benzyl acetate, and the molecular formula is C9H10O2, SDS of cas: 140-11-4.
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