Tu, Hai-Yong published the artcileEnantioselective Three-Component Fluoroalkylarylation of Unactivated Olefins through Nickel-Catalyzed Cross-Electrophile Coupling, Quality Control of 583-04-0, the main research area is nickel catalyzed enantioselective three component fluoroalkylarylation olefin.
A nickel-catalyzed, enantioselective, three-component fluoroalkylarylation of unactivated alkenes with aryl halides and perfluoroalkyl iodides has been described. This cross-electrophile coupling protocol utilizes a chiral nickel/BiOx system as well as a pendant chelating group to facilitate the challenging three-component, asym. difunctionalization of unactivated alkenes, providing direct access to valuable chiral β-fluoroalkyl arylalkanes with high efficiency and excellent enantioselectivity. The mild conditions allow for a broad substrate scope as well as good functional group toleration. Thus, e.g., allylic ester I + 5-bromo-2-(trifluoromethyl)pyrimidine + IC4F9 → II (87%, 94:6 er).
Journal of the American Chemical Society published new progress about Aryl bromides Role: RCT (Reactant), RACT (Reactant or Reagent). 583-04-0 belongs to class esters-buliding-blocks, name is Allyl benzoate, and the molecular formula is C10H10O2, Quality Control of 583-04-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics