Qiao, Xin-Chao published the artcileHalf-sandwich ruthenium-based versatile catalyst for both alcohol oxidation and catalytic hydrogenation of carbonyl compounds in aqueous media, Product Details of C6H12O3, the main research area is carbonyl compound preparation; alc preparation oxidation ruthenium catalyst; hydrogenation carbonyl compound ruthenium catalyst.
A series of half-sandwich ruthenium-based catalysts I (R = H, OCH3, CF3, Cl) for both alc., e.g., 1,2,3,4-tetrahydronaphthalen-1-ol oxidation and carbonyl compounds R1C(O)R2 (R1 = C6H5, 3-BrC6H4, 2-pyridyl, etc.; R2 = H, Me, Ph; R1R2 = -(CH2)5-) hydrogenation have been synthesized through metal-induced C-H bond activation based on benzothiazole ligands II. Mol. structures of complexes I (R = H, CF3) were further confirmed by X-ray diffraction anal. All complexes I exhibited high activity for the catalytic oxidation of a variety of alcs. with tBuOOH as oxidants to give carbonyl compounds, e.g., 1,2,3,4-tetrahydronaphthalen-1-one with high yields in water. Moreover, these half-sandwich complexes also showed high efficiency for the catalytic hydrogenation of carbonyl compounds in a methanol-water mixture The catalyst could be reused for at least five cycles without any loss of activity. The catalytic system also worked well for various kinds of substrates with either electron-donating or electron-withdrawing groups.
Applied Organometallic Chemistry published new progress about Carbonyl compounds (organic) Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 5405-41-4 belongs to class esters-buliding-blocks, name is Ethyl 3-hydroxybutanoate, and the molecular formula is C6H12O3, Product Details of C6H12O3.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics