Olmos, Andrea published the artcileMeasuring the Relative Reactivity of the Carbon-Hydrogen Bonds of Alkanes as Nucleophiles, Recommanded Product: Ethyltert-butylacetate, the publication is Angewandte Chemie, International Edition (2018), 57(42), 13848-13852, database is CAplus and MEDLINE.
We report quant. measurements of the relative reactivities of a series of C-H bonds of gaseous or liquid CnH2n+2 alkanes (n = 1-8, 29 different C-H bonds) towards in situ generated electrophiles (copper, silver, and rhodium carbenes), with methane as the reference This strategy surpasses the drawback of previous model reactions of alkanes with strong electrophiles suffering from C-C cleavage processes, which precluded direct comparison of the relative reactivities of alkane C-H bonds.
Angewandte Chemie, International Edition published new progress about 5340-78-3. 5340-78-3 belongs to esters-buliding-blocks, auxiliary class Aliphatic Chain, name is Ethyltert-butylacetate, and the molecular formula is C8H16O2, Recommanded Product: Ethyltert-butylacetate.
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