Randriamahefa, S.’s team published research in Synthesis in | CAS: 5340-78-3

Synthesis published new progress about 5340-78-3. 5340-78-3 belongs to esters-buliding-blocks, auxiliary class Aliphatic Chain, name is Ethyltert-butylacetate, and the molecular formula is C8H16O2, SDS of cas: 5340-78-3.

Randriamahefa, S. published the artcileImproved synthesis of tertiary alkylacetic acids and esters, SDS of cas: 5340-78-3, the publication is Synthesis (1985), 493-5, database is CAplus.

RR1MeCCH2CO2H (R, R1 = Me, Et) were prepared in 13-90% yield by treating CH2:CCl2 with RR1MeCOH, H2SO4, and then H2O. Similar treatment of CH2:CCl2 with Me3COMe and Me3CCl gave 55 and 77% Me3CCH2CO2H resp. with some Me3CCH2CO2Me also being formed when the ether was used. Addition of R2OH (R2 = Me, Et, Pr, Me2CH, Bu, Me2CHCH2, pentyl) to the reaction-mixture prior to H2O yielded 13-76% RR1CMeCH2CO2R2.

Synthesis published new progress about 5340-78-3. 5340-78-3 belongs to esters-buliding-blocks, auxiliary class Aliphatic Chain, name is Ethyltert-butylacetate, and the molecular formula is C8H16O2, SDS of cas: 5340-78-3.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics