Sn-Catalyzed Criegee-Type Rearrangement of Peroxyoxindoles Enabled by Catalytic Dual Activation of Esters and Peroxides was written by Chaudhari, Moreshwar B.;Jayan, Krishna;Gnanaprakasam, Boopathy. And the article was included in Journal of Organic Chemistry in 2020.Name: Octyl acetate The following contents are mentioned in the article:
Sn-catalyzed mild protocol was reported for ring expansion of peroxyoxindoles to afford a series of substituted 2H-benzo[b][1,4]oxazin-3(4H)-one derivatives In this protocol, authors showed the in-situ conversion of tert-Bu peroxy compounds into peresters with the aid of external esters, which then underwent the ring-expansion process and the incipient carbocation was trapped with the alc. residue generated from the esters. The reaction was also demonstrated in a continuous flow process. This study involved multiple reactions and reactants, such as Octyl acetate (cas: 112-14-1Name: Octyl acetate).
Octyl acetate (cas: 112-14-1) belongs to esters. Volatile esters with characteristic odours are used in synthetic flavours, perfumes, and cosmetics. Certain volatile esters are used as solvents for lacquers, paints, and varnishes. Because of their lack of hydrogen-bond-donating ability, esters do not self-associate. Consequently, esters are more volatile than carboxylic acids of similar molecular weight.Name: Octyl acetate
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics