Ethylaluminum dichloride catalyzed ene reactions of aldehydes with nonnucleophilic alkenes was written by Snider, Barry B.;Phillips, Gary B.. And the article was included in Journal of Organic Chemistry in 1983.Category: esters-buliding-blocks The following contents are mentioned in the article:
EtAlCl2, which is a strong Lewis acid and a proton scavenger, catalyzes the ene reactions of aliphatic aldehydes with nonnucleophilic alkenes. Higher aldehydes give good yields of ene adducts with terminal alkenes. CH2O gives good yields of adducts with electron-deficient alkenes. This reaction has been used for the synthesis of recifeiolide, ricinelaidic acid, and the insect pheromones (E,E)-8,10-dodecadienyl acetate and (E)-9,11-dodecadienyl acetate. This study involved multiple reactions and reactants, such as (E)-Dodeca-9,11-dien-1-yl acetate (cas: 50767-78-7Category: esters-buliding-blocks).
(E)-Dodeca-9,11-dien-1-yl acetate (cas: 50767-78-7) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Esterification is the general name for a chemical reaction in which two reactants (typically an alcohol and an acid) form an ester as the reaction product. Esters are common in organic chemistry and biological materials.Category: esters-buliding-blocks
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics