Synthesis and Coordination Chemistry of 3,4-Ethylene-Bridged 1,1,2,5-Tetrasubstituted Biguanides was written by Dehmel, Maximilian;Vass, Valentin;Prock, Lukas;Goerls, Helmar;Kretschmer, Robert. And the article was included in Inorganic Chemistry in 2020.Name: Isopropylisothiocyanate The following contents are mentioned in the article:
The synthesis of 3,4-ethylene-bridged 1,1,2,5-tetrasubstituted biguanides is reported, which are accessible by three alternative routes. Exemplary mol. structures of the ligand and an observed side product have been elucidated by x-ray diffraction anal. Mono- and dinuclear complexes of the biguanide in both its neutral and monoanionic forms were obtained, including examples of aluminum, copper, magnesium, potassium, tin, and zinc, indicating a versatile coordination behavior, as evidenced by single-crystal x-ray diffraction anal. A new class of electron-rich N,N’-bidentate ligands is reported, and mono- and dinuclear complexes of the new ligand in both its neutral and monoanionic form were obtained. This study involved multiple reactions and reactants, such as Isopropylisothiocyanate (cas: 2253-73-8Name: Isopropylisothiocyanate).
Isopropylisothiocyanate (cas: 2253-73-8) belongs to esters. Carboxylic acid esters of low molecular weight are colourless, volatile liquids with pleasant odours, slightly soluble in water. Acyl chlorides and acid anhydrides alcoholysis is another way to produce esters. Acyl chlorides and acid anhydrides react with alcohols to produce esters. Anydrous conditions are recommended since both acyl chlorides and acid anhydrides react with water.Name: Isopropylisothiocyanate
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics