Otsu, T. published the artcileLiving radical polymerization in homogeneous system by using iniferter: design of block copolymers, Synthetic Route of 3052-61-7, the publication is Journal of Macromolecular Science, Chemistry (1984), A21(8-9), 961-77, database is CAplus.
Benzyl N-ethyldithiocarbamate (I) [28249-01-6] and p-xylylene bis(N-ethyldithiocarbamate) (II) [93522-33-9] were prepared, and used as mono- and bifunctional photoiniferters, resp., of the polymerization of styrene and Me methacrylate. These photopolymerizations were performed via a living radical polymerization mechanism in a homogeneous system. The polymers obtained by I and II still contained 1 and 2 reactive N-ethyldithiocarbamate end groups, resp., bonded at their chain ends. When these polymers reacted with nucleophiles and Cu2+ the chain extension reactions occurring depended on their functionality. By using the polymers obtained by I and II as mono- and bifunctional polymeric photoiniferters, AB and ABA block copolymers were also obtained, resp. Similar results were obtained by using benzyl N,N-diethyldithiocarbamate [3052-61-7] and p-xylylene bis(N,N-diethyldithiocarbamate) [89964-93-2] as mono- and bifunctional photoiniferters, resp. These results were also compared and discussed.
Journal of Macromolecular Science, Chemistry published new progress about 3052-61-7. 3052-61-7 belongs to esters-buliding-blocks, auxiliary class Amine,Benzene,Amide, name is Benzyl diethylcarbamodithioate, and the molecular formula is C12H17NS2, Synthetic Route of 3052-61-7.
Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics