Samatov, Aizat A. et al. published their research in Thermochimica Acta in 2020 | CAS: 112-14-1

Octyl acetate (cas: 112-14-1) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits. Many esters have the potential for conformational isomerism, but they tend to adopt an s-cis (or Z) conformation rather than the s-trans (or E) alternative, due to a combination of hyperconjugation and dipole minimization effects. The preference for the Z conformation is influenced by the nature of the substituents and solvent, if present. Lactones with small rings are restricted to the s-trans (i.e. E) conformation due to their cyclic structure.Electric Literature of C10H20O2

Vaporization/sublimation enthalpies of mono- and dimethyl-esters estimated by solution calorimetry method was written by Samatov, Aizat A.;Nagrimanov, Ruslan N.;Miroshnichenko, Evgeniy A.;Solomonov, Boris N.. And the article was included in Thermochimica Acta in 2020.Electric Literature of C10H20O2 The following contents are mentioned in the article:

The additive scheme for calculating the solvation enthalpies of aliphatic compounds has been developed for linear mono- and dimethyl-esters. Ester group contribution to the enthalpy of solvation in n-heptane was obtained. Accuracy of the proposed approach for determination of solvation enthalpies of linear mono- and dimethyl-esters was tested by comparison with exptl. solvation enthalpies. In most cases, deviations do not exceed 1 kJ·mol-1. It was found that the dependence of the solution enthalpies of mono- and dimethyl-esters on the number of carbon atoms in the mol. can be fitted by power function. This dependence and a group-additivity scheme for solvation enthalpy were used for estimation of the enthalpies of phase transitions of mono- and dimethyl-esters. Evaluated values of sublimation, vaporization, and fusion enthalpies at 298.15 K are in good agreement with exptl. data obtained by conventional methods. This study involved multiple reactions and reactants, such as Octyl acetate (cas: 112-14-1Electric Literature of C10H20O2).

Octyl acetate (cas: 112-14-1) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits. Many esters have the potential for conformational isomerism, but they tend to adopt an s-cis (or Z) conformation rather than the s-trans (or E) alternative, due to a combination of hyperconjugation and dipole minimization effects. The preference for the Z conformation is influenced by the nature of the substituents and solvent, if present. Lactones with small rings are restricted to the s-trans (i.e. E) conformation due to their cyclic structure.Electric Literature of C10H20O2

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics